Citation: Linnan Jiang, Zhenkai Qian, Yong Chen, Xiaoyong Yu, Yugui Qiu, Wen-Wen Xu, Yonghui Sun, Xiufang Xu, Lihua Wang, Yu Liu. Double response reversible phosphorescence based on cyclodextrin supramolecular flexible elastic achieved multicolor delayed fluorescence[J]. Chinese Chemical Letters, ;2025, 36(8): 110676. doi: 10.1016/j.cclet.2024.110676 shu

Double response reversible phosphorescence based on cyclodextrin supramolecular flexible elastic achieved multicolor delayed fluorescence

Linnan Jiang ^{a, 1} ,
Zhenkai Qian ^{a, 1} ,
Yong Chen ^a ,
Xiaoyong Yu ^a ,
Yugui Qiu ^b ,
Wen-Wen Xu ^a ,
Yonghui Sun ^a ,
Xiufang Xu ^c ,
Lihua Wang ^a ,
Yu Liu ^{a, *,}

a.
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry Nankai University, Tianjin 300071, China
b.
Xinjiang Key Laboratory of Novel Functional Materials Chemistry, College of Chemistry and Environmental Science, Kashi University, Kashi 844000, China
c.
Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, China

yuliu@nankai.edu.cn

Received Date: 14 August 2024
Revised Date: 16 November 2024
Accepted Date: 25 November 2024
Available Online: 26 November 2024

Figures(6)

Purely organic room-temperature phosphorescence (RTP) is current hotspot in the research fields of chemistry, biology, materials etc. Herein, we report that photo-thermal double response reversible ultralong RTP flexible elastic material with multicolor delayed fluorescence, which is constructed by 4-biphenylboronic acid (BOH), polyethylene glycol, 2,2-bis(hydroxymethyl)propionic acid, isophorone diamine and isophorone diisocyanate copolymer. Importantly, the supramolecular phosphorescent elastomer not only exhibits extending RTP emission with a lifetime up to 1.21 s, but also gives a visible afterglow of 20 s via encapsulation of BOH unities by the deep cavities of hydroxypropyl-β-cyclodextrin (β-CD-HP) and in situ polymerization. Especially, after doping organic dyes (Fluorescein isothiocyanate, Sulforhodamine 101, Rhodamine B), supramolecular phosphorescent elastomer achieves multicolor delayed fluorescence realized by RTP energy transfer from phosphorescent donor to dye acceptors, which possesses reversible photo-thermal responsiveness and maintains high efficiency in delayed emission even after dozens of cycles. Present research provides a new approach for constructing multicolor delayed fluorescent supramolecular elastomers.
- Double response reversible,
- Cyclodextrin,
- RTP,
- Host-guest interaction,
- Flexible elastic
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