Citation: Xilong Lu, Liwen Mao, Yiming Liu, Zhenliang Dong, Tiange Gao, Libing Zheng, Peng Huang, Yueling Bai, Yiling Liu, Qingmin Hu, Jiaqiang Xu. Facet-dominant dual-selective sensing performance to HF and NO of Pt/TiO₂ film via phase transition[J]. Chinese Chemical Letters, ;2026, 37(3): 110668. doi: 10.1016/j.cclet.2024.110668 shu

Facet-dominant dual-selective sensing performance to HF and NO of Pt/TiO₂ film via phase transition

Xilong Lu ^{a, 1} ,
Liwen Mao ^{a, 1} ,
Yiming Liu ^a ,
Zhenliang Dong ^a ,
Tiange Gao ^a ,
Libing Zheng ^{b, d} ,
Peng Huang ^c ,
Yueling Bai ^a ,
Yiling Liu ^{c, *,} ,
Qingmin Hu ^{a, *,} ,
Jiaqiang Xu ^{a, *,}

a.
NEST Lab, Department of Physics, Department of Chemistry, Institute for Sustainable Energy, Collage of Sciences, Shanghai University, Shanghai 200444, China
b.
Institute of Electrical Engineering, Chinese Academy of Sciences (CAS), Beijing 100190, China
c.
National Institute of Metrology, Beijing 100029, China
d.
University of Chinese Academy of Science, Beijing 100083, China

liuyl@nim.ac.cn

huqingmin@shu.edu.cn

xujiaqiang@shu.edu.cn

Received Date: 14 September 2024
Revised Date: 7 November 2024
Accepted Date: 21 November 2024
Available Online: 26 November 2024

Figures(4)

The surficial inherent properties of TiO₂ like exposed facet and crystalline state are vital for their surface reactions. However, efficiently controlling the specific crystal structure and the exposed crystal surface still faces big challenge. Here, the controlled solid phase transition of amorphous TiO₂ to crystalline phase with exposed crystal facet (001) is achieved by photo-assisted atomic layer deposition (ALD) Pt process. Significantly, the obtained Pt/TiO₂ film via photo-assisted treatment exhibits high sensing performance to NO and HF, and shows a lower optimized working temperature. The enhanced sensing performance is attributed to the metal-support strong interaction under oxidative atmosphere (O-SMSI). The facet effects leading to the unique distribution of charges at the interface combined with the catalytic effects result in the high sensing performance. This work provides a novel phase transition engineering strategy for regulating TiO₂ from amorphous to crystalline phase, and the controllable synthesis of high Pt monatomic loading on TiO₂ via ALD, which are critical for the accurate synthesis of efficient sensing and catalytic nanomaterials.
- Amorphous and crystal TiO₂,
- Atomic layer deposition,
- Phase transition,
- Strong metal support,
- Interaction (SMSI),
- Precisely fabrication,
- HF and NO sensor
1. [1]
  J. Chen, Y. Kang, W. Zhang, et al., Angew. Chem. Int. Ed. 61 (2022) e202203022. doi: 10.1002/anie.202203022
2. [2]
  L.N. Appelhans, P.S. Finnegan, L.T. Massey, et al., Sens. Actuator. B 228 (2016) 117–123. doi: 10.1016/j.snb.2015.12.068
3. [3]
  X. Zhang, Z. Yuan, J. Chen, et al., Catal. Today 340 (2020) 204–208. doi: 10.1016/j.cattod.2018.09.025
4. [4]
  J. Zhou, Z. Gao, G. Xiang, et al., Nat. Commun. 13 (2022) 327.
5. [5]
  C. Liu, J. Qian, Y. Ye, et al., Nat. Catal. 4 (2020) 36–45. doi: 10.1038/s41929-020-00550-5
6. [6]
  X. Zhang, Z. Li, W. Pei, et al., ACS Catal. 12 (2022) 3634–3643. doi: 10.1021/acscatal.1c05695
7. [7]
  Y. Zhang, A. Jia, Z. Li, Z. Yuan, W. Huang, ACS Catal. 13 (2022) 392–399.
8. [8]
  X. Wang, W. Shi, S. Wang, et al., J. Am. Chem. Soc. 141 (2019) 5856–5862. doi: 10.1021/jacs.9b00029
9. [9]
  Z. Wang, C. Yang, T. Lin, et al., Energy Environ. Sci. 6 (2013) 3007. doi: 10.1039/c3ee41817k
10. [10]
  W. Lin, H. Zheng, P. Zhang, T. Xu, Appl. Catal. A: Gen. 521 (2016) 75–82. doi: 10.1016/j.apcata.2015.10.032
11. [11]
  F. Pan, K. Wu, H. Li, G. Xu, W. Chen, Chemistry 20 (2014) 15095–15101. doi: 10.1002/chem.201403866
12. [12]
  X.H. Yang, Z. Li, C. Sun, H.G. Yang, C. Li, Chem. Mater. 23 (2011) 3486–3494. doi: 10.1021/cm2008768
13. [13]
  B. Shao, W. Zhao, S. Miao, et al., Chin. J. Catal. 40 (2019) 1534–1539. doi: 10.1016/S1872-2067(19)63388-7
14. [14]
  H.G. Yang, C.H. Sun, S.Z. Qiao, et al., Nature 453 (2008) 638–641. doi: 10.1038/nature06964
15. [15]
  C. Zheng, R.E. Simpson, K. Tang, et al., Chem. Rev. 122 (2022) 15450–15500. doi: 10.1021/acs.chemrev.2c00171
16. [16]
  A. Beck, H. Frey, X. Huang, et al., Angew. Chem. Int. Ed. 62 (2023) e202301468. doi: 10.1002/anie.202301468
17. [17]
  Q. Hu, S. Wang, Z. Gao, et al., Appl. Catal. B: Environ. 218 (2017) 591–599. doi: 10.1016/j.apcatb.2017.06.087
18. [18]
  J.C. Matsubu, V.N. Yang, P. Christopher, J. Am. Chem. Soc. 137 (2015) 3076–3084. doi: 10.1021/ja5128133
19. [19]
  X. Lan, K. Xue, T. Wang, J. Catal. 372 (2019) 49–60. doi: 10.1016/j.jcat.2019.02.022
20. [20]
  Y. Xu, W. Zheng, X. Liu, et al., Mater. Horiz. 7 (2020) 1519–1527. doi: 10.1039/D0MH00495B
21. [21]
  S. Zhang, X. Chang, L. Zhou, X. Liu, J. Zhang, ACS Sens. 9 (2024) 2101–2109. doi: 10.1021/acssensors.4c00162
22. [22]
  Q. Hu, X. Lu, T. Gao, et al., Sens. Actuator. B 414 (2024) 135852. doi: 10.1016/j.snb.2024.135852
23. [23]
  M. Guo, N. Luo, Y. Bai, et al., Sens. Actuator. B 398 (2024) 134151. doi: 10.1016/j.snb.2023.134151
24. [24]
  Q. Hu, C. Wu, Z. Dong, et al., J Mater. Chem. A 10 (2022) 2786–2794. doi: 10.1039/D1TA08630H
25. [25]
  H. Cai, N. Luo, Q. Hu, et al., ACS Sens. 7 (2022) 1484–1494. doi: 10.1021/acssensors.2c00228
26. [26]
  S. Bernal, J.J. Calvino, M.A. Cauqui, et al., Catal. Today 77 (2003) 385–406. doi: 10.1016/S0920-5861(02)00382-6
27. [27]
  T.Y. Chang, A.K. Singh, J.H. Shao, et al., Appl. Surf. Sci. 637 (2023) 157929. doi: 10.1016/j.apsusc.2023.157929
28. [28]
  G.C. Lu, X.H. Liu, W. Zheng, et al., Rare Metals 41 (2022) 1520–1528. doi: 10.1007/s12598-021-01899-7
29. [29]
  Y. Zhang, B. Wang, S. Lv, et al., Sens. Actuator. B 361 (2022) 131736. doi: 10.1016/j.snb.2022.131736
1. [1]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
2. [2]
  Zhi-Yuan Yue , Hua-Kai Li , Na Wang , Shan-Shan Liu , Le-Ping Miao , Heng-Yun Ye , Chao Shi . Dehydration-triggered structural phase transition-associated ferroelectricity in a hybrid perovskite-type crystal. Chinese Chemical Letters, 2024, 35(10): 109355-. doi: 10.1016/j.cclet.2023.109355
3. [3]
  Yan-Ran Weng , Wen-Fu Tian , Wen-Jing Ding , Bi-He Ren , De-Hou Liu , Jia-Ying Tang , Feng Zhou , Xiao-Gang Chen , Xian-Jiang Song , Hui-Peng Lv , Yong Ai . Homochiral organic ferroelastics with plastic phase transition. Chinese Chemical Letters, 2025, 36(7): 110188-. doi: 10.1016/j.cclet.2024.110188
4. [4]
  Hongping Zhao , Hanzhaobing Wu , Baolong Shi , Jiayue Wang , Chunzheng Wu , Chaohai Wang , Xiaoyan Wang , Wei Liu , Chaoqing Dai , Dalei Wang . Fast and controllable anatase-to-rutile phase transition irradiated by NIR light. Chinese Chemical Letters, 2025, 36(11): 110815-. doi: 10.1016/j.cclet.2025.110815
5. [5]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
6. [6]
  Zhaohong Chen , Mengzhen Li , Jinfei Lan , Shengqian Hu , Xiaogang Chen . Organic ferroelastic enantiomers with high T_c and large dielectric switching ratio triggered by order-disorder and displacive phase transition. Chinese Chemical Letters, 2024, 35(10): 109548-. doi: 10.1016/j.cclet.2024.109548
7. [7]
  Ying-Yu Zhang , Jia-Qi Luo , Yan Han , Wan-Ying Zhang , Yi Zhang , Hai-Feng Lu , Da-Wei Fu . Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature. Chinese Chemical Letters, 2025, 36(1): 109530-. doi: 10.1016/j.cclet.2024.109530
8. [8]
  Mao-Fan Li , Ming‐Yu Guo , De-Xuan Liu , Xiao-Xian Chen , Wei-Jian Xu , Wei-Xiong Zhang . Multi-stimuli responsive behaviors in a new chiral hybrid nitroprusside salt (R-3-hydroxypyrrolidinium)₂[Fe(CN)₅(NO)]. Chinese Chemical Letters, 2024, 35(12): 109507-. doi: 10.1016/j.cclet.2024.109507
9. [9]
  Shifang Song , Chenyu Wu , Li Zhang , Dezhi Yang , Yang Lu , Zhengzheng Zhou . Unpacking phase transitions in multi-component drug systems: A case study. Chinese Chemical Letters, 2025, 36(7): 110911-. doi: 10.1016/j.cclet.2025.110911
10. [10]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
11. [11]
  Keke Han , Wenjun Rao , Xiuli You , Haina Zhang , Xing Ye , Zhenhong Wei , Hu Cai . Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO₄⁻, ReO₄⁻). Chinese Chemical Letters, 2024, 35(6): 108809-. doi: 10.1016/j.cclet.2023.108809
12. [12]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
13. [13]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
14. [14]
  Hao-Fei Ni , Jia-He Lin , Gele Teri , Qiang-Qiang Jia , Pei-Zhi Huang , Hai-Feng Lu , Chang-Feng Wang , Zhi-Xu Zhang , Da-Wei Fu , Yi Zhang . B-site ion regulation strategy enables performance optimization and multifunctional integration of hybrid perovskite ferroelectrics. Chinese Chemical Letters, 2025, 36(3): 109690-. doi: 10.1016/j.cclet.2024.109690
15. [15]
  Fan Wu , Shaoyang Wu , Xin Ye , Yurong Ren , Peng Wei . Research progress of high-entropy cathode materials for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(4): 109851-. doi: 10.1016/j.cclet.2024.109851
16. [16]
  Yan Zou , Yuting Xue , Chenxue Du , Wenyang Fu , Bin Xia , Yu He , Liang Ao , Xiaoshu Lv , Guangming Jiang . Anhydrous sodium sulfate microparticles for efficient water separation from surfactant-stabilized water-in-oil emulsions. Chinese Chemical Letters, 2025, 36(11): 110814-. doi: 10.1016/j.cclet.2025.110814
17. [17]
  Doudou Liu , Weiwei Guo , Guoliang Mei , Youpeng Dan , Rong Yang , Chao Huang , Yanling Zhai , Xiaoquan Lu . Application of catalyst Cu-t-ZrO₂ based on the electronic metal-support interaction in electrocatalytic nitrate reduction. Chinese Chemical Letters, 2025, 36(8): 110578-. doi: 10.1016/j.cclet.2024.110578
18. [18]
  Shan Zhao , Xu Liu , Haotian Guo , Zonglin Liu , Pengfei Wang , Jie Shu , Tingfeng Yi . Synergistic design of high-entropy P2/O3 biphasic cathodes for high-performance sodium-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(1): 100129-0. doi: 10.1016/j.actphy.2025.100129
19. [19]
  Bicheng Ji , Xicheng Li , Shuai Gao , Pengyuan Liu , Jiajie Bao , Lv Qian , Changzheng Wang , Qiang Wang , Chong-Chen Wang . In-situ Z-scheme hetero-phase homojunction significantly enhances the carrier separation efficiency of TiO₂ nanotube arrays: Key role of crystal phase engineering. Chinese Chemical Letters, 2026, 37(2): 111424-. doi: 10.1016/j.cclet.2025.111424
20. [20]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(24)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Facet-dominant dual-selective sensing performance to HF and NO of Pt/TiO2 film via phase transition

Metrics

通讯作者: 陈斌, bchen63@163.com

Facet-dominant dual-selective sensing performance to HF and NO of Pt/TiO₂ film via phase transition