Citation: Xiaojin Wang, Yi Chang, Yuanyuan Zhang, Zhuohua Li, Haiqi Huang, Yansha Huang, Jiawei Hu, Kai Zhang, Xuemei Gong, Ruirui Zhao. In-situ construction and tuning of a poly(1,3-dioxolane) dual-interlayer electrolyte bolstering high performance of solid-state battery[J]. Chinese Chemical Letters, ;2026, 37(3): 110626. doi: 10.1016/j.cclet.2024.110626 shu

In-situ construction and tuning of a poly(1,3-dioxolane) dual-interlayer electrolyte bolstering high performance of solid-state battery

Xiaojin Wang ^{a, 1} ,
Yi Chang ^{c, 1} ,
Yuanyuan Zhang ^{b, *,} ,
Zhuohua Li ^a ,
Haiqi Huang ^a ,
Yansha Huang ^a ,
Jiawei Hu ^a ,
Kai Zhang ^{d, *,} ,
Xuemei Gong ^e ,
Ruirui Zhao ^{a, *,}

a.
School of Chemistry, National and Local Joint Engineering Research Center of MPTES in High Energy and Safety LIBs, Engineering Research Center of MTEES (Ministry of Education), and Key Lab. of ETESPG(GHEI), South China Normal University, Guangzhou 510006, China
b.
Analysis & Testing Center, Key Laboratory of Theoretical Chemistry of Environment Ministry of Education, South China Normal University, Guangzhou 510006, China
c.
GAC AION New Energy Automobile Co., Ltd., Guangzhou 511434, China
d.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China
e.
Guangzhou TianTie Technology Research Co., Ltd., Guangzhou 510710, China

yyzhang@m.scnu.edu.cn

zhangkai_nk@nankai.edu.cn

zhaoruirui@m.scnu.edu.cn

Received Date: 26 September 2024
Revised Date: 4 November 2024
Accepted Date: 7 November 2024
Available Online: 8 November 2024

Figures(4)

Garnet-type ceramic Li₇La₃Zr₂O₁₂ (LLZO) stands out as a potential solid-state electrolyte, offering a promising alternative to conventional flammable liquid electrolytes. However, its large interfacial resistance with electrodes remains a significant challenge. In this research, we have successfully in-situ fabricated polymeric interface layers on both cathode and anode sides with LLZO. By tuning the gel-polymer interphase via fluoroethylene carbonate (FEC), known as FGPE, we have established a rapid Li⁺ transport channel by enhancing the solid-solid interfacial contact. This FGPE layer exhibits exceptional ionic conductivity of 1.38 mS/cm and a high Li-ion transference number of 0.64. Furthermore, FGPE effectively mitigates concentration polarization under high currents, thereby enabling a higher capacity output. In comparison to gel-polymer interphases with dimethyl carbonate (DMC) as the solvent (referred to as GPE), the Li|FGPE|Li symmetrical cell has demonstrated superior stability in plating/strapping performance over 800 h at a current density of 0.1 mA/cm². Moreover, the Li|FGPE|LLZO|FGPE|LiFePO₄ cell has exhibited commendable rate capability and has maintained a high capacity retention of 98.94% at 0.5 C after 200 cycles. This study underscores an innovative approach in advancing in field of solid-state batteries, anticipated to be broadly applicable to other solid-state batteries by facilitating an abundance of robust solid-solid interfacial contacts.
- Solid-state battery,
- Interface modification strategy,
- In-situ polymerization,
- Garnet electrolyte,
- Poly(1,3-dioxolane)
1. [1]
  Z.F. Wang, J. Zhao, X.D. Zhang, et al., eScience 3 (2023) 100087. doi: 10.1016/j.esci.2022.100087
2. [2]
  R.J. Chen, W.J. Qu, X. Guo, et al., Mater. Horiz. 3 (2016) 487–516. doi: 10.1039/C6MH00218H
3. [3]
  Y. Li, X.X. Liu, T. Ji, et al., Chin. Chem. Lett. 35 (2024) 109551.
4. [4]
  M. Zhang, X.X. Liu, J.D. Gu, et al., Chin. Chem. Lett. 34 (2023) 108471. doi: 10.1016/j.cclet.2023.108471
5. [5]
  K.V. Kravchyk, M.V. Kovalenko, Sci. Technol. Adv. Mater. 23 (2022) 2018919.
6. [6]
  F. Aguesse, W. Manalastas, L. Buannic, et al., ACS Appl. Mater. Interfaces 9 (2017) 3808–3816. doi: 10.1021/acsami.6b13925
7. [7]
  S.N. Lauro, J.N. Burrow, C.B. Mullins, eScience 3 (2023) 100152. doi: 10.1016/j.esci.2023.100152
8. [8]
  Z.H. Li, X.J. Wang, X.Y. Lin, et al., ACS Appl. Mater. Interfaces 15 (2023) 35684–35691. doi: 10.1021/acsami.3c06095
9. [9]
  H.Y. Fan, F.X. Wei, J.C. Luo, et al., Sustain. Energy Fuels 5 (2021) 2077–2084. doi: 10.1039/d1se00061f
10. [10]
  J.C. Chai, Z.H. Liu, J. Ma, et al., Adv. Sci. 4 (2017) 1600377. doi: 10.1002/advs.201600377
11. [11]
  S.H. Zhang, F. Sun, X.F. Du, et al., Energy Environ. Sci. 16 (2023) 2591–2602. doi: 10.1039/d3ee00558e
12. [12]
  Q.Y. Wang, X.Q. Xu, B. Hong, et al., Energy Environ. Mater. 6 (2023) e12351. doi: 10.1002/eem2.12351
13. [13]
  L. Wang, S.G. Xu, Z. Wang, et al., eScience 3 (2023) 100090. doi: 10.1016/j.esci.2022.100090
14. [14]
  Y.X. Wang, T.Y. Li, X.F. Yang, et al., Adv. Energy Mater. 14 (2024) 2303189. doi: 10.1002/aenm.202303189
15. [15]
  H. Yang, M.X. Jing, L. Wang, et al., Nano-Micro Lett. 16 (2024) 127. doi: 10.1007/s40820-024-01354-z
16. [16]
  Q. Zhao, X.T. Liu, S. Stalin, et al., Nat. Energy 4 (2019) 365–373. doi: 10.1038/s41560-019-0349-7
17. [17]
  F.Q. Liu, W.P. Wang, Y.X. Yin, et al., Sci. Adv. 4 (2018) eaat5383. doi: 10.1126/sciadv.aat5383
18. [18]
  J.P. Zheng, W.D. Zhang, C.Y. Huang, et al., Mater. Today Energy 26 (2022) 100984. doi: 10.1016/j.mtener.2022.100984
19. [19]
  R. McMillan, H. Slegr, Z.X. Shu, et al., J. Power Sources 81 (1999) 20–26.
20. [20]
  X.Q. Zhang, X.B. Cheng, X. Chen, et al., Adv. Funct. Mater. 27 (2017) 1605989. doi: 10.1002/adfm.201605989
21. [21]
  D.Q. Liu, K. Qian, Y.B. He, et al., Electrochim. Acta 269 (2018) 378–387. doi: 10.1016/j.electacta.2018.02.151
22. [22]
  J.Q. Zhou, T. Qian, J. Liu, et al., Nano Lett. 19 (2019) 3066–3073. doi: 10.1021/acs.nanolett.9b00450
23. [23]
  W.H. Ren, Y.F. Zhang, R.X. Lv, et al., J. Power Sources 542 (2022) 231773. doi: 10.1016/j.jpowsour.2022.231773
24. [24]
  N. Chen, Y.J. Dai, Y. Xing, et al., Energy Environ. Sci. 10 (2017) 1660–1667. doi: 10.1039/C7EE00988G
25. [25]
  R. Rojaee, S. Cavallo, S. Mogurampelly, et al., Adv. Funct. Mater. 30 (2020) 1910749. doi: 10.1002/adfm.201910749
26. [26]
  K.R. Deng, Q.G. Zeng, D. Wang, et al., Energy Storage Mater. 32 (2020) 425–447. doi: 10.1016/j.ensm.2020.07.018
27. [27]
  X.Y. Zhang, C.K. Fu, S.C. Cheng, et al., Energy Storage Mater. 56 (2023) 121–131. doi: 10.1016/j.ensm.2022.12.048
28. [28]
  Y. Cui, J.Y. Wan, Y.S. Ye, et al., Nano Lett. 20 (2020) 1686–1692. doi: 10.1021/acs.nanolett.9b04815
29. [29]
  Q.S. Wang, L.H. Jiang, Y. Yu, et al., Nano Energy 55 (2019) 93–114. doi: 10.1016/j.nanoen.2018.10.035
30. [30]
  Y.L. Liu, Y.L. Xu, Chem. Eng. J. 433 (2022) 134471. doi: 10.1016/j.cej.2021.134471
31. [31]
  J. Tan, J. Matz, P. Dong, et al., Adv. Energy Mater. 11 (2021) 2100046. doi: 10.1002/aenm.202100046
32. [32]
  H.P. Zeng, K. Yu, J.W. Li, et al., ACS Nano 18 (2024) 1969–1981. doi: 10.1021/acsnano.3c07038
33. [33]
  I.A. Shkrob, J.F. Wishart, D.P. Abraham, J. Phys. Chem. C 119 (2015) 14954–14964. doi: 10.1021/acs.jpcc.5b03591
34. [34]
  Q.L. Zhang, J. Pan, P. Lu, et al., Nano Lett. 16 (2016) 2011–2016. doi: 10.1021/acs.nanolett.5b05283
35. [35]
  Z. Liu, Y. Qi, Y.X. Lin, et al., J. Electrochem. Soc. 163 (2016) A592–A598. doi: 10.1149/2.0151605jes
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6. [6]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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