Citation: Hongyi Zhang, Wenda Li, Hao Luo, Lingyan Huang, Facai Wei, Shanzhe Ke, Liguo Ma, Chengbin Jing, Jiangong Cheng, Shaohua Liu. Mesoporous N-rich carbon nanospheres regulating high dispersion of red phosphorus for sodium-ion batteries[J]. Chinese Chemical Letters, ;2026, 37(2): 110605. doi: 10.1016/j.cclet.2024.110605 shu

Mesoporous N-rich carbon nanospheres regulating high dispersion of red phosphorus for sodium-ion batteries

Hongyi Zhang ^a ,
Wenda Li ^a ,
Hao Luo ^a ,
Lingyan Huang ^a ,
Facai Wei ^a ,
Shanzhe Ke ^a ,
Liguo Ma ^b ,
Chengbin Jing ^a ,
Jiangong Cheng ^c ,
Shaohua Liu ^{a, *,}

a.
State Key Laboratory of Precision Spectroscopy, Engineering Research Center of Nanophotonics & Advanced Instrument, Ministry of Education, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China
b.
Nantong Qiangsheng Graphene Technology Co., Ltd., Nantong 226000, China
c.
State Key Lab of Transducer Technology Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China

shliu@phy.ecnu.edu.cn

Received Date: 19 September 2024
Accepted Date: 1 November 2024
Available Online: 2 November 2024

Figures(5)

The intrinsic insulation and drastic volume change of the red phosphorus during the 3-electron alloying process greatly limits its widespread applications in sodium-ion batteries. Here, we report a monomicelle-directed assembly approach for controllable synthesis of monodispersed mesoporous polypyrrole (PPy) nanospheres, which allows for the shape-preserving conversion into N-doped carbon with regular mesoscopic pore and high surface area, thus affording a high dispersion of red phosphorus during melt impregnation process due to the available diffusion apertures and strong molecular chemical anchoring. Moreover, the theoretical calculations further revealed that positively polarized pyridine N atoms in N-doped mesoporous carbon nanospheres can empower comprehensive regulation of red phosphorus adsorption by strong chemical binding. Benefitting from the above advantages, the resultant red phosphorus host for sodium-ion batteries delivered an outstanding reversible capacity of 856 mAh/g with a capacity fading rate of only 0.025% per cycle during 1000 cycles at 1.0 A/g. This work provides an effective approach based on monomicelle-directed assembly engineering of carbon-based phosphorus hosts for advanced energy conversion and storage systems.
- Mesoporous materials,
- N-doped carbon nanospheres,
- Monomicelle-directed assembly,
- Phosphorus hosts,
- Sodium-ion batteries
1. [1]
  P.K. Nayak, L.T. Yang, W. Brehm, P. Adelhelm, Angew. Chem. Int. Ed. 57 (2018) 102–120. doi: 10.1002/anie.201703772
2. [2]
  Y. Jin, P.M.L. Le, P. Gao, et al., Nat. Energy 7 (2022) 718–725. doi: 10.1038/s41560-022-01055-0
3. [3]
  R. Shi, L. Liu, Y. Lu, et al., Nat. Commun. 11 (2020) 178. doi: 10.1038/s41467-019-13739-5
4. [4]
  Z. Hao, X. Shi, Z. Yang, L. Li, S.L. Chou, Adv. Funct. Mater. 32 (2022) 2208093.
5. [5]
  D. Luo, C. Ma, J. Hou, et al., Adv. Energy Mater. 12 (2022) 2106716.
6. [6]
  Z. Cheng, B. Zhao, Y.J. Guo, et al., Adv. Energy Mater. 12 (2022) 2103461. doi: 10.1002/aenm.202103461
7. [7]
  W. Zhang, Y. Wu, Z. Xu, et al., Adv. Energy Mater. 12 (2022) 2201065. doi: 10.1002/aenm.202201065
8. [8]
  J. Song, Z. Yu, M.L. Gordin, et al., Nano Lett. 14 (2014) 6329–6335. doi: 10.1021/nl502759z
9. [9]
  S. Qiao, Q. Zhou, M. Ma, et al., ACS Nano 17 (2023) 11220–11252. doi: 10.1021/acsnano.3c02892
10. [10]
  J. Zhao, X.X. He, W.H. Lai, et al., Adv. Energy Mater. 13 (2023) 2300444. doi: 10.1002/aenm.202300444
11. [11]
  Z. Li, M. Han, Y. Zhang, et al., Adv. Sci. 10 (2023) 2207234. doi: 10.1002/advs.202207234
12. [12]
  Q. Jin, K. Wang, P. Feng, et al., Energy Stor. Mater. 27 (2020) 43–50.
13. [13]
  X. Jiao, Y. Liu, B. Li, et al., Carbon 148 (2019) 518–524. doi: 10.1016/j.carbon.2019.03.053
14. [14]
  W. Zhang, T. Liu, Y. Wang, et al., Nano Energy 90 (2021) 106475.
15. [15]
  Y. Jiang, M. Xie, F. Wu, et al., Chem. Eng. J. 438 (2022) 134279. doi: 10.1016/j.cej.2021.134279
16. [16]
  Y. Lu, P. Zhou, K. Lei, et al., Adv. Energy Mater. 7 (2017) 1601937.
17. [17]
  Z. Yan, Y. Liang, W. Hua, et al., ACS Nano 14 (2020) 10284–10293. doi: 10.1021/acsnano.0c03737
18. [18]
  B. Sun, S. Wang, S. Zhou, et al., Adv. Funct. Mater. 34 (2024) 2314058. doi: 10.1002/adfm.202314058
19. [19]
  R. Mogensen, J. Maibach, A.J. Naylor, R. Younesi, Dalton Trans. 47 (2018) 10752–10758. doi: 10.1039/c8dt01068d
20. [20]
  K. Fang, D. Liu, X. Xiang, et al., Nano Energy 69 (2020) 104451. doi: 10.1016/j.nanoen.2020.104451
21. [21]
  H. Kaur, B. Konkena, C. Gabbett, et al., Adv. Energy Mater. 13 (2022) 2203013.
22. [22]
  Y. Liu, Q. Liu, C. Jian, et al., Nat. Commun. 11 (2020) 2520. doi: 10.1038/s41467-020-16077-z
23. [23]
  X. Liu, B. Xiao, A. Daali, et al., ACS Energy Lett. 6 (2021) 547–556. doi: 10.1021/acsenergylett.0c02650
24. [24]
  W. Liu, L. Du, S. Ju, et al., ACS Nano 15 (2021) 5679–5688. doi: 10.1021/acsnano.1c00924
25. [25]
  S. Zhang, C. Liu, H. Wang, et al., ACS Nano 15 (2021) 3365–3375. doi: 10.1021/acsnano.0c10370
26. [26]
  S. Liu, P. Gordiichuk, Z.S. Wu, et al., Nat. Commun. 6 (2015) 8817. doi: 10.1038/ncomms9817
27. [27]
  F. Wei, H. Xu, T. Zhang, et al., ACS Nano 17 (2023) 20643–20653. doi: 10.1021/acsnano.3c07868
28. [28]
  L. Peng, C.T. Hung, S.W. Wang, et al., J. Am. Chem. Soc. 141 (2019) 7073–7080. doi: 10.1021/jacs.9b02091
29. [29]
  F. Wei, T. Zhang, R. Dong, et al., Nat. Protoc. 18 (2023) 2459–2484. doi: 10.1038/s41596-023-00845-4
30. [30]
  W. Li, L. Shi, Y. Wu, et al., Energy Stor. Mater. 53 (2022) 183–191. doi: 10.3390/antiox11020183
31. [31]
  P. Huang, T. Xiong, S. Zhou, et al., ACS Appl. Mater. Interfaces 13 (2021) 16516–16527. doi: 10.1021/acsami.1c02645
32. [32]
  U. Sreevidya, V. Shalini, S. Kavirajan, et al., J. Colloid Interface Sci. 630 (2023) 46–60. doi: 10.1016/j.jcis.2022.09.056
33. [33]
  L. Xiang, S. Yuan, F. Wang, et al., J. Am. Chem. Soc. 144 (2022) 15497–15508. doi: 10.1021/jacs.2c02881
34. [34]
  J. Liu, H. Li, J. Wang, et al., Adv. Energy Mater. 11 (2021) 2101926. doi: 10.1002/aenm.202101926
35. [35]
  J. Xu, F. Yu, J. Hua, et al., Chem. Eng. J. 392 (2020) 123694. doi: 10.1016/j.cej.2019.123694
36. [36]
  G.L. Chai, K. Qiu, M. Qiao, et al., Energy Environ. Sci. 10 (2017) 1186–1195. doi: 10.1039/C6EE03446B
1. [1]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
2. [2]
  Jiaojiao Liang , Youming Peng , Zhichao Xu , Yufei Wang , Menglong Liu , Xin Liu , Di Huang , Yuehua Wei , Zengxi Wei . Boron/phosphorus co-doped nitrogen-rich carbon nanofiber with flexible anode for robust sodium-ion battery. Chinese Chemical Letters, 2025, 36(1): 110452-. doi: 10.1016/j.cclet.2024.110452
3. [3]
  Yu Deng , Yan Liu , Yonghui Deng , Jinsheng Cheng , Yidong Zou , Wei Luo . In situ sulfur-doped mesoporous tungsten oxides for gas sensing toward benzene series. Chinese Chemical Letters, 2024, 35(7): 108898-. doi: 10.1016/j.cclet.2023.108898
4. [4]
  Liangju Zhao , Shiyu Qin , Fei Wu , Limin Zhu , Qing Han , Lingling Xie , Xuejing Qiu , Hongliang Wei , Lanhua Yi , Xiaoyu Cao . Polycarbonyl conjugated porous polyimide as anode materials for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(8): 110246-. doi: 10.1016/j.cclet.2024.110246
5. [5]
  Zheng Li , Fangkun Li , Xijun Xu , Jun Zeng , Hangyu Zhang , Lei Xi , Yiwen Wu , Linwei Zhao , Jiahe Chen , Jun Liu , Yanping Huo , Shaomin Ji . A scalable approach to Na₄Fe₃(PO₄)₂P₂O₇@carbon/expanded graphite as cathode for ultralong-lifespan and low-temperature sodium-ion batteries. Chinese Chemical Letters, 2025, 36(10): 110390-. doi: 10.1016/j.cclet.2024.110390
6. [6]
  Yining Li , Shimei Wu , Lantao Chen , Haosen Fan , Yufei Zhang , Lingxing Zeng . Multiple yolks-shell cobalt phosphosulfide nanocrystals encapsulating into rich heteroatoms co-doped carbon frameworks for advanced sodium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(9): 110371-. doi: 10.1016/j.cclet.2024.110371
7. [7]
  Shimei Wu , Yining Li , Lantao Chen , Yufei Zhang , Lingxing Zeng , Haosen Fan . Hexapod cobalt phosphosulfide nanorods encapsulating into multiple hetero-atom doped carbon frameworks for advanced sodium/potassium ion battery anodes. Chinese Chemical Letters, 2025, 36(4): 109796-. doi: 10.1016/j.cclet.2024.109796
8. [8]
  Qiong Su , Chao Hu , Sichan Li , Wenjun Huang , Jianyu Dong , Ren Song , Lan Xu , Guozhao Fang . Sodium-ion batteries at low temperature: Storage mechanism and modification strategies. Chinese Chemical Letters, 2025, 36(12): 111267-. doi: 10.1016/j.cclet.2025.111267
9. [9]
  Guang Zeng , Yue Zeng , Huamin Hu , Yaqing Bai , Fangjie Nie , Junfei Duan , Zhaoyong Chen , Qi-Long Zhu . Regulating pore structure and pseudo-graphitic phase of hard carbon anode towards enhanced sodium storage performance. Chinese Chemical Letters, 2025, 36(7): 110122-. doi: 10.1016/j.cclet.2024.110122
10. [10]
  Yao Wang , Jun Ouyang , Huadong Yuan , Jianmin Luo , Shihui Zou , Jianwei Nai , Xinyong Tao , Yujing Liu . Impact of local amorphous environment on the diffusion of sodium ions at the solid electrolyte interface in sodium-ion batteries. Chinese Chemical Letters, 2025, 36(10): 110412-. doi: 10.1016/j.cclet.2024.110412
11. [11]
  Jichun Li , Zhengren Wang , Yu Deng , Hongxiu Yu , Yonghui Deng , Xiaowei Cheng , Kaiping Yuan . Construction of mesoporous silica-implanted tungsten oxides for selective acetone gas sensing. Chinese Chemical Letters, 2024, 35(11): 110111-. doi: 10.1016/j.cclet.2024.110111
12. [12]
  Xuan Wang , Peng Sun , Siteng Yuan , Lu Yue , Yufeng Zhao . P2-type low-cost and moisture-stable cathode for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(5): 110015-. doi: 10.1016/j.cclet.2024.110015
13. [13]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
14. [14]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
15. [15]
  Fanjun Kong , Jing Zhang , Yuting Tang , Chencheng Sun , Chunfu Lin , Tao Zhang , Wangsheng Chu , Li Song , Liang Zhang , Shi Tao . Introducing high-valence element into P2-type layered cathode material for high-rate sodium-ion batteries. Chinese Chemical Letters, 2025, 36(8): 110993-. doi: 10.1016/j.cclet.2025.110993
16. [16]
  Wenya Li , Yuanqi Yang , Yuqing Yang , Min Liang , Huizi Li , Xi Ke , Liying Liu , Yan Sun , Chunsheng Li , Zhicong Shi , Su Ma . Insights into magnesium and titanium co-doping to stabilize the O3-type NaCrO₂ cathode material for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(10): 110388-. doi: 10.1016/j.cclet.2024.110388
17. [17]
  Yanxue Wu , Xijun Xu , Shanshan Shi , Fangkun Li , Shaomin Ji , Jingwei Zhao , Jun Liu , Yanping Huo . Facile construction of Cu_2-xSe@C nanobelts as anode for superior sodium-ion storage. Chinese Chemical Letters, 2025, 36(6): 110062-. doi: 10.1016/j.cclet.2024.110062
18. [18]
  Hong Yin , Danyang Han , Wei Wang , Zhaohui Hou , Miao Zhou , Ye Han , İhsan Çaha , João Cunha , Maryam Karimi , Zhixin Tai , Xinxin Cao . Bimetallic sulfide anodes based on heterojunction structures for high-performance sodium-ion battery anodes. Chinese Chemical Letters, 2025, 36(12): 110537-. doi: 10.1016/j.cclet.2024.110537
19. [19]
  Mingxin Song , Lijing Xie , Fangyuan Su , Zonglin Yi , Quangui Guo , Cheng-Meng Chen . New insights into the effect of hard carbons microstructure on the diffusion of sodium ions into closed pores. Chinese Chemical Letters, 2024, 35(6): 109266-. doi: 10.1016/j.cclet.2023.109266
20. [20]
  Hui Qi , Chaozheng He , Chenfei Song , Juncui Gao , Qing Gao , Weipeng Luo , Ze Zhang , Haoyu Liu , Xiaojing Yuan , Wenfeng Wu , Bohang Zhao , Lina Kong , Yayi Cheng , Ling Guo . Tailoring the exposure of active facets of FeNCN towards enhanced pseudocapacitive behavior for sodium storage. Chinese Chemical Letters, 2025, 36(11): 111591-. doi: 10.1016/j.cclet.2025.111591

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(10)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142