Citation: Yi Chen, Hua-Pan Wu, Zheng-Wei Guo, Xin-Xiong Li, Ping-Wei Cai, Shou-Tian Zheng. Construction of a diverting polyoxotungstate based on 3d-5p heterometallic cluster for high-performance single-crystal proton conduction[J]. Chinese Chemical Letters, ;2025, 36(11): 110552. doi: 10.1016/j.cclet.2024.110552 shu

Construction of a diverting polyoxotungstate based on 3d-5p heterometallic cluster for high-performance single-crystal proton conduction

Yi Chen ^{a, c} ,
Hua-Pan Wu ^a ,
Zheng-Wei Guo ^a ,
Xin-Xiong Li ^{a, b} ,
Ping-Wei Cai ^{a, b, *,} ,
Shou-Tian Zheng ^{a, *,}

a.
Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated-Materials, College of Chemistry, Fuzhou University, Fuzhou 350108, China
b.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China
c.
College of Chemical Engineering, Fuzhou University, Fuzhou 350108, China

cai2022@fzu.edu.cn

stzheng@fzu.edu.cn

Received Date: 30 August 2024
Revised Date: 28 September 2024
Accepted Date: 13 October 2024
Available Online: 15 October 2024

Figures(5)

Exploring the synthesis of novel structures is crucial for the development of functional materials. In this context, a novel and intriguing 3d-5p heterometallic cluster-substituted polyoxotungstate material, H₂₉Na₉(H₂O)₂₁{Ca(H₂O)₂@Sb₁₂O₁₈[Ni₂(OH)(A-α-SiW₁₀O₃₇)]₃}₂·40H₂O (1), was constructed using Keggin-type polyoxotungstate A-α-SiW₁₀O₃₇, along with Ni and Sb elements. The structure features a T_d-symmetric Sb₁₂O₁₈ ({Sb₁₂}) cage that encapsulates an 8-coordinate Ca²⁺ ion at its face. Additionally, the {Sb₁₂} cage forms an 18-nuclear 3d-5p heterometallic cluster by connecting with three di-nuclear nickel clusters through shared oxygen atoms. Electrochemical impedance spectra studies reveal that the single crystal of 1 achieves a proton conductivity of 1.11×10⁻¹ S/cm along the [110] direction and 1.04×10⁻¹ S/cm along the [100] direction at 85 ℃ and 98% relative humidity (RH). Furthermore, the powder form of 1 exhibits a proton conductivity of 3.00×10⁻² S/cm. These findings suggest that compound 1 holds promise as a practical proton conducting material.
- Polyoxotungstate,
- 3d-5p,
- Heterometallic cluster,
- Single-crystal,
- Proton conduction
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