Citation: Feng-Fan Yang, Yin-Kang Ding, Lin-Kai Wu, Jiayue Tian, Shuai Dou, Wenjing Wang, Linfeng Liang. A 1,3,5-triazine μ₃-bridged neutral Cu(Ⅰ) framework with enhanced stability and CO₂ capture selectivity[J]. Chinese Chemical Letters, ;2025, 36(12): 110550. doi: 10.1016/j.cclet.2024.110550 shu

A 1,3,5-triazine μ₃-bridged neutral Cu(Ⅰ) framework with enhanced stability and CO₂ capture selectivity

Feng-Fan Yang ^a ,
Yin-Kang Ding ^a ,
Lin-Kai Wu ^a ,
Jiayue Tian ^b ,
Shuai Dou ^b ,
Wenjing Wang ^c ,
Linfeng Liang ^{a, d, *,}

a.
Institute of Crystalline Materials, Shanxi University, Taiyuan 030006, China
b.
School of Materials and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450000, China
c.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
d.
Key Laboratory of Materials for Energy Conversion and Storage of Shanxi Province, Taiyuan 030006, China

jtcl@sxu.edu.cn

Received Date: 14 August 2024
Revised Date: 8 October 2024
Accepted Date: 13 October 2024
Available Online: 15 October 2024

Figures(4)

Compounds with 1,3,5-triazine ring such as melamine derivatives, known for their low cost and high stability, offer potential for affordable, stable metal organic framework (MOF) synthesis. However, reported such frameworks are facing issues like low stability and reduced porosity. To overcome such problems, we explored organic ligands with protonated nitrogen atoms on the 1,3,5-triazine ring, facilitated by introducing hydroxyl groups on carbon atoms of the triazine ring to construct MOFs. By using 5-azacytosine, we have successfully synthesized SXU-121, a neutral ultramicroporous MOF with eta-topology and high density of open Cu(Ⅰ) sites. SXU-121 features robust structural stability and significant CO₂ adsorption capacity with high selectivity over N₂ under ambient conditions. We believe SXU-121's development opens new avenues for creating a class of stable and low cost metal-triazine frameworks with potential diverse functionalities.
- 5-Azacytosine,
- Metal organic framework,
- Carbon dioxide capture,
- Crystal engineering,
- Gas adsorption and separation
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沈阳化工大学材料科学与工程学院沈阳 110142

A 1,3,5-triazine μ3-bridged neutral Cu(Ⅰ) framework with enhanced stability and CO2 capture selectivity

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通讯作者: 陈斌, bchen63@163.com

A 1,3,5-triazine μ₃-bridged neutral Cu(Ⅰ) framework with enhanced stability and CO₂ capture selectivity