Citation: Guoping Yang, Zhoufu Lin, Xize Zhang, Jiawei Cao, Xuejiao Chen, Yufeng Liu, Xiaoling Lin, Ke Li. Assembly of Y(Ⅲ)-containing antimonotungstates induced by malic acid with catalytic activity for the synthesis of imidazoles[J]. Chinese Chemical Letters, ;2024, 35(12): 110274. doi: 10.1016/j.cclet.2024.110274 shu

Assembly of Y(Ⅲ)-containing antimonotungstates induced by malic acid with catalytic activity for the synthesis of imidazoles

Guoping Yang ^{a, b, 1,*,} ,
Zhoufu Lin ^{a, 1} ,
Xize Zhang ^a ,
Jiawei Cao ^a ,
Xuejiao Chen ^a ,
Yufeng Liu ^{a, b} ,
Xiaoling Lin ^{a, *,} ,
Ke Li ^{a, *,}

a.
School of Nuclear Science and Engineering, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, Jiangxi Province Key Laboratory of Functional Organic Polymers, East China University of Technology, Nanchang 330013, China
b.
College of Chemistry, Xinjiang University, Urumqi 830017, China

erick@ecut.edu.cn

xiaoling@ecut.edu.cn

like@ecut.edu.cn

Received Date: 10 July 2024
Revised Date: 15 July 2024
Accepted Date: 16 July 2024
Available Online: 16 July 2024

Figures(4)

A dimeric Y(Ⅲ)-containing antimonotungstate [Y₄(H₂O)₈(mal)₂(OAc)O(Sb₂W^Ⅴ₂W^Ⅵ₁₉O₇₂)₂]²¹⁻ (Y₄mal₂, H₃mal = DL-malic acid), resembling a “handshake” configuration, was synthesized and characterized. The polyanion of Y₄mal₂ consists of two Dawson-derived {Y₂Sb₂W₂₁} moieties that are further linked by two mal ligands and one μ₂-bridging acetate to form an asymmetric polyanion. Notably, the chiral configuration induced by the D- or L-configuration of the mal ligand results in both {Y₂Sb₂W₂₁} moieties within one polyanion exhibiting identical chirality, leading to the racemate crystallization of Y₄mal₂. Moreover, Y₄mal₂ exhibits excellent Lewis acid catalytic activity for environmentally friendly synthesis of imidazoles.
- Polyoxometalates,
- Yttrium,
- Antimonotungstate,
- Malic acid,
- Imidazoles
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