Citation: Tianxia Chen, Yunhui Chen, Weiwei Li, Peipei Cen, Yan Guo, Jin Zhang, Cunding Kong, Xiangyu Liu. Fabricating AuAg-nanoparticles/ZIF-8 composites for selective detection and efficient extraction of dinitroaniline pesticides[J]. Chinese Chemical Letters, ;2025, 36(8): 110214. doi: 10.1016/j.cclet.2024.110214 shu

Fabricating AuAg-nanoparticles/ZIF-8 composites for selective detection and efficient extraction of dinitroaniline pesticides

Tianxia Chen ^{a, 1} ,
Yunhui Chen ^{a, 1} ,
Weiwei Li ^a ,
Peipei Cen ^{b, *,} ,
Yan Guo ^a ,
Jin Zhang ^c ,
Cunding Kong ^a ,
Xiangyu Liu ^{a, *,}

a.
State Key Laboratory of High-Efficiency Utilization of Coal and Green Chemical Engineering, College of Chemistry and Chemical Engineering, School of Civiland Hydraulic Engineering, Ningxia University, Yinchuan 750021, China
b.
College of Public Health, College of Basic Medical Science, Ningxia Medical University, Yinchuan 750021, China
c.
Analysis and Testing Center, Ningxia University, Yinchuan 750021, China

13895400691@163.com

xiangyuliu432@126.com

Received Date: 28 May 2024
Revised Date: 14 June 2024
Accepted Date: 4 July 2024
Available Online: 5 July 2024

Figures(10)

Developing candidate materials that are equipped with the ability of both selective detection and efficient removal of pesticides is greatly desirable for the environment and public health. However, most of reported materials usually possess single function, which considerably limits their applications as sensors or captures. Herein, two fluorescent composites, ZIF-8@AuAg NPs and ZIF-8-AuAg NPs, are prepared by the integration of Au/Ag nanoparticles (M NPs) and a zeolite imidazolate framework (ZIF-8), presenting a more stable fluorescent performance compared with pure AuAg NPs. The characterizations unravel that ZIF-8@AuAg NPs exhibits a core shell type structure, whereas ZIF-8-AuAg NPs are indicative of a dispersed loading type motif. ZIF-8-AuAg NPs features a significant fluorescent quenching effect for three commonly used dinitroaniline pesticides in aqueous matrices. Then, pendimethalin (PDA) is selected as a representative of dinitroaniline pesticides to thoroughly develop the potential applications in the fields of detection and extraction. Impressively, ZIF-8-AuAg NPs made of ZIF-8 shell embedded with AuAg NPs can achieve fluorescence sensing for PDA in a low concentration range with the limit of detection (LOD) of 4.2 nmol/L from aqueous solution and agricultural products, attributed to the combination of competition mechanism and electron transfer. Moreover, ZIF-8-AuAg NPs possesses high adsorption capacity of 125 mg/g for PDA at pH 6, depending on the synergistic effect of unique structural frameworks, coordinative interaction and hydrogen bond. The design for present hybrid composites provides a facile strategy to develop difunctional luminescent adsorbents with the merits of selective detection and effective absorption of dinitroaniline pesticides.
- MOF composites,
- Nanoparticles,
- Pesticides,
- Detection,
- Absorption
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