Citation: Zhiyang Zhang, Yi Chen, Yingnan Zhang, Chuanlang Zhan. Deuterated chloroform replaces ultra-dry chloroform to achieve high-efficient organic solar cells[J]. Chinese Chemical Letters, ;2025, 36(1): 110083. doi: 10.1016/j.cclet.2024.110083 shu

Deuterated chloroform replaces ultra-dry chloroform to achieve high-efficient organic solar cells

Key Laboratory of Advanced Materials Chemistry and Devices (AMCDLab) of the Department of Education of Inner Mongolia Autonomous Region, College of Chemistry and Environment Science, Inner Mongolia Normal University, Huhehot 010022, China

clzhan@imnu.edu.cn

Received Date: 19 March 2024
Revised Date: 31 May 2024
Accepted Date: 2 June 2024
Available Online: 3 June 2024

Figures(3)

Chloroform is a common and excellent solvent for preparing high-efficient organic solar cells (OSCs), however, it is toxic and poisonable chemical. In comparisons, deuterated chloroform (DC) is less toxic and costly, and particularly, it is non-poisonable chemical. In this paper, we use DC to replace ultra-dry chloroform (UC) as the processing solvent for preparation of active layers of organic solar cells. First, we selected PM6:BTP-eC9 as the basic binary and counted 100 solar cells' data, from which comparable device performance were obtained with use of DC and UC. Interestingly, DC showed better reproducibility, superior storage under a nitrogen atmosphere and a little better performance than UC. Both DC and UC gave rise of comparable hole and electron mobilities and similar charge recombination losses. Second, we based PM6:Y6 and D18-Cl: Y6 as the binaries and similar effects were obtained from both UC and DC when counting 30 devices for each binary. Third, the universality of the use of DC for preparing high-efficient OSCs were again checked with several binary and ternary systems. In all, this study demonstrate that DC can replace UC for use in the field of OSCs.
- Organic solar cell,
- Processing solvent,
- Deuterated chloroform,
- Ultra-dry chloroform,
- Active layer
1. [1]
  H. Sun, P.Y. Zhang, Y.N. Zhang, C.L. Zhan, Chem. J. Chin. Univ. 44 (2023) 20230076.
2. [2]
  Y. Wang, Q. Chen, S. Liang, et al., Chin. Chem. Lett. 35 (2024) 109164. doi: 10.1016/j.cclet.2023.109164
3. [3]
  W. Feng, T. Chen, Y. Li, et al., Angew. Chem. Int. Ed. 63 (2024) e202316698. doi: 10.1002/anie.202316698
4. [4]
  C. He, Q. Shen, B. Wu, et al., Adv. Energy Mater. 13 (2023) 2204154. doi: 10.1002/aenm.202204154
5. [5]
  G. Cai, Z. Chen, T. Li, et al., J. Mater. Chem. A 10 (2022) 21061–21071. doi: 10.1039/D2TA05817K
6. [6]
  Y. Li, Y. Cai, Y. Xie, et al., Energy Environ. Sci. 14 (2021) 5009–5016. doi: 10.1039/D1EE01864G
7. [7]
  T. Huang, Z. Zhang, Q. Liao, et al., Small 19 (2023) 2303399. doi: 10.1002/smll.202303399
8. [8]
  B. Pang, C. Liao, X. Xu, et al., Adv. Mater. 35 (2023) 2300631. doi: 10.1002/adma.202300631
9. [9]
  L. Zhan, S. Li, Y. Li, et al., Adv. Energy Mater. 12 (2022) 2201076. doi: 10.1002/aenm.202201076
10. [10]
  M. Deng, X. Xu, Y. Duan, et al., Adv. Mater. 35 (2023) 2210760. doi: 10.1002/adma.202210760
11. [11]
  J. Gao, X. Zhu, H. Bao, et al., Chin. Chem. Lett. 34 (2023) 107968. doi: 10.1016/j.cclet.2022.107968
12. [12]
  J. Wang, Y. Wang, P. Bi, et al., Adv. Mater. 35 (2023) 2301583. doi: 10.1002/adma.202301583
13. [13]
  J. Song, C. Zhang, C. Li, et al., Angew. Chem. Int. Ed. 63 (2024) e202404297. doi: 10.1002/anie.202404297
14. [14]
  S. Luo, C. Li, J. Zhang, et al., Nat. Commun. 14 (2023) 6964. doi: 10.1038/s41467-023-41978-0
15. [15]
  T. Chen, S. Li, Y. Li, et al., Adv. Mater. 35 (2023) 2300400. doi: 10.1002/adma.202300400
16. [16]
  K. Chong, X. Xu, H. Meng, et al., Adv. Mater. 34 (2022) 2109516. doi: 10.1002/adma.202109516
17. [17]
  Z. Zheng, J. Wang, P. Bi, et al., Joule 6 (2022) 171–184. doi: 10.1016/j.joule.2021.12.017
18. [18]
  F. Zhao, C. Wang, X. Zhan, Adv. Energy Mater. 8 (2018) 1703147. doi: 10.1002/aenm.201703147
19. [19]
  G. Zhang, F.R. Lin, F. Qi, et al., Chem. Rev. 122 (2022) 14180–14274. doi: 10.1021/acs.chemrev.1c00955
20. [20]
  L. Zhu, M. Zhang, W. Zhong, et al., Energy Environ. Sci. 14 (2021) 4341–4357. doi: 10.1039/D1EE01220G
21. [21]
  W. Chen, T. Xu, F. He, et al., Nano Lett. 11 (2011) 3707–3713. doi: 10.1021/nl201715q
22. [22]
  S. Guo, E.M. Herzig, A. Naumann, et al., J. Phys. Chem. B 118 (2014) 344–350. doi: 10.1021/jp410075a
23. [23]
  I. Burgués-Ceballos, F. Machui, J. Min, et al., Adv. Funct. Mater. 24 (2014) 1449–1457. doi: 10.1002/adfm.201301509
24. [24]
  C. McDowell, M. Abdelsamie, M.F. Toney, G.C. Bazan, Adv. Mater. 30 (2018) 1707114. doi: 10.1002/adma.201707114
25. [25]
  J. Mao, J. Iocozzia, J. Huang, et al., Energy Environ. Sci. 11 (2018) 772–799. doi: 10.1039/C7EE03031B
26. [26]
  K. Yang, M. Lv, Y. Chang, K. Lu, Z. Wei, Chin. Chem. Lett. 35 (2024) 109018. doi: 10.1016/j.cclet.2023.109018
27. [27]
  W. Zhang, J. Huang, X. Lv, et al., Chin. Chem. Lett. 34 (2023) 107436. doi: 10.1016/j.cclet.2022.04.034
28. [28]
  S.H. Park, A. Roy, S. Beaupré, et al., Nature Photon 3 (2009) 297–302. doi: 10.1038/nphoton.2009.69
29. [29]
  H. Tan, W. Zhang, P. Zhang, et al., Solar RRL 6 (2022) 2200147. doi: 10.1002/solr.202200147
30. [30]
  P. Ding, D. Yang, S. Yang, Z. Ge, Chem. Soc. Rev. 53 (2024) 2350–2387. doi: 10.1039/D3CS00492A
31. [31]
  Y. Su, Z. Ding, R. Zhang, et al., Sci. China Chem. 66 (2023) 2380–2388. doi: 10.1007/s11426-023-1608-6
32. [32]
  Z. Zhang, J. Wang, Z. Hu, et al., Chin. Chem. Lett. 34 (2023) 108527. doi: 10.1016/j.cclet.2023.108527
33. [33]
  P. Zhang, Z. Zhang, H. Sun, et al., Chin. Chem. Lett. 35 (2024) 108802. doi: 10.1016/j.cclet.2023.108802
34. [34]
  C.C. Tong, K.C. Hwang, J. Phys. Chem. C 111 (2007) 3490–3494. doi: 10.1021/jp066116k
35. [35]
  M. Shao, J. Keum, J. Chen, et al., Nat. Commun. 5 (2014) 3180. doi: 10.1038/ncomms4180
36. [36]
  E.M. Russak, E.M. Bednarczyk, Ann. Pharmacother. 53 (2019) 211–216. doi: 10.1177/1060028018797110
37. [37]
  L.R. Pohl, G. Rriehna, Life Sci. 23 (1978) 1067–1072. doi: 10.1016/0024-3205(78)90668-9
38. [38]
  M. Ahmadizadeh, C.H. Kuo, J.B. Hook, J. Toxicol. Environ. Health 8 (1981) 105–111. doi: 10.1080/15287398109530054
39. [39]
  L. Li, J. Jakowski, C. Do, K. Hong, Macromolecules 54 (2021) 3555–3584. doi: 10.1021/acs.macromol.0c02284
40. [40]
  A. Wang, Y. Kang, C. Hou, et al., Sci. Bull. 68 (2023) 1153–1161. doi: 10.1016/j.scib.2023.05.005
41. [41]
  M. Deng, X. Xu, Y. Duan, et al., Adv. Funct. Mater. 33 (2023) 2212290. doi: 10.1002/adfm.202212290
42. [42]
  A. Lan, Y. Lv, J. Zhu, et al., ACS Energy Lett. 7 (2022) 2845–2855. doi: 10.1021/acsenergylett.2c01438
43. [43]
  K. Li, Y. Wu, Y. Tang, et al., Adv. Energy Mater. 9 (2019) 1901728. doi: 10.1002/aenm.201901728
44. [44]
  X. Li, M.A. Pan, T.K. Lau, et al., Chem. Mater. 32 (2020) 5182–5191. doi: 10.1021/acs.chemmater.0c01245
45. [45]
  L. Zhong, H. Bin, Y. Li, et al., J. Mater. Chem. A 6 (2018) 24814–24822. doi: 10.1039/C8TA08406H
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