Citation: Mengxiang Zhu, Tao Ding, Yunzhang Li, Yuanjie Peng, Ruiping Liu, Quan Zou, Leilei Yang, Shenglei Sun, Pin Zhou, Guosheng Shi, Dongting Yue. Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction[J]. Chinese Chemical Letters, ;2024, 35(12): 109833. doi: 10.1016/j.cclet.2024.109833 shu

Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction

Mengxiang Zhu ^{a, 1} ,
Tao Ding ^{a, 1} ,
Yunzhang Li ^a ,
Yuanjie Peng ^a ,
Ruiping Liu ^b ,
Quan Zou ^{a, b} ,
Leilei Yang ^c ,
Shenglei Sun ^{d, *,} ,
Pin Zhou ^{e, *,} ,
Guosheng Shi ^a ,
Dongting Yue ^{a, *,}

a.
Shanghai Applied Radiation Institute, State Key Lab. Advanced Special Steel, Shanghai University, Shanghai 200444, China
b.
Center for Soil Protection and land scape Design, Chinese Academy of Environmental Planning, Beijing 100041, China
c.
Zhejiang Grearth Ecological Co., Ltd., International Trade Center Office Building, Hangzhou 311400, China
d.
Institute of Balsalt Fiber in Eco-Application, School of Environmental Science and Engineering, Qingdao University, Qingdao 266071, China
e.
Research Center of secondary Resources and Environment, Changzhou Institute of Technology, Changzhou 213032, China

sunshenglei@qdu.edu.cn

zpnhs@163.com

yuedongting@shu.edu.cn

Received Date: 9 November 2023
Revised Date: 26 February 2024
Accepted Date: 25 March 2024
Available Online: 26 March 2024

Figures(3)

Fenton-like process based on metal oxide presents one of the most hoping strategies to generate reactive oxygen species to treat refractory pollutants. The introduction of oxygen vacancies (O_Vs) can enhance the catalytic performance of metal oxides in Fenton-like reaction. In this paper, a one-step all solid-state synthesis strategy is proposed to induce oxygen defects in V₂O₅, which uses graphene to engineer the crystallization process of V-based crystals. Such approach employs graphene as a solid-catalyst to promote growth of V-based crystals owing to the ions-π interactions between graphene and VCl₃. The electron-donor O_Vs in V₂O₅@graphene can not only active H₂O₂ for the ^•OH generation, but also accelerate the reduction of V⁵⁺ and V⁴⁺, thereby ensuring defective V₂O₅@graphene/H₂O₂ system is 14.3, 28.2, and 17.3 times higher than that of graphene/H₂O₂, pure V₂O₅/H₂O₂ and graphene+V₂O₅/H₂O₂ (mechanical mixed system), respectively. Our study provides a novel synthetic strategy to design and prepare O_Vs-riched transition metal catalysts for developing advanced oxidation technologies toward higher sustainability and practicality.
- Oxygen vacancies,
- Fenton-like,
- Catalysis,
- V₂O₅,
- Solid-state synthesis
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Graphene controlled solid-state growth of oxygen vacancies riched V2O5 catalyst to highly activate Fenton-like reaction

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Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction