Citation: Yu He, Hao Jiang, Shaoxuan Yuan, Jiayi Lu, Qiang Sun. On-surface photo-induced dechlorination[J]. Chinese Chemical Letters, ;2024, 35(9): 109807. doi: 10.1016/j.cclet.2024.109807 shu

On-surface photo-induced dechlorination

Materials Genome Institute, Shanghai University, Shanghai 200444, China

qiangsun@shu.edu.cn

Received Date: 18 January 2024
Revised Date: 14 March 2024
Accepted Date: 20 March 2024
Available Online: 22 March 2024

Figures(5)

On-surface Ullmann-type reaction, or the dehalogenated coupling, is arguably the most pivotal reaction in on-surface synthesis for the fabrications of carbon nanostructures. Hitherto, the vast majority of works rely on activating the C-Br bond of aryl bromide which has a moderate bond dissociation energy. The C-Cl bond of aryl chloride has a higher dissociation energy and requires much higher thermal energy to break the bond. In this study, we have explored the on-surface photo-induced dechlorination and achieved the activation of three distinct aryl chlorines on the Au(111) surface with mild temperatures. This work enriches our understanding of on-surface photo-induced reactions and highlights the potential of photochemistry in realizing unconventional reactions.
- On-surface synthesis,
- Scanning probe microscopy,
- On-surface photochemistry,
- Dechlorination reaction
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