Citation: Rui Liu, Yue Yu, Lu Deng, Maoxia Xu, Haorong Ren, Wenjie Luo, Xudong Cai, Zhenyu Li, Jingyu Chen, Hua Yu. The synergistic effect of A-site cation engineering and phase regulation enables efficient and stable Ruddlesden-Popper perovskite solar cells[J]. Chinese Chemical Letters, ;2024, 35(12): 109545. doi: 10.1016/j.cclet.2024.109545 shu

The synergistic effect of A-site cation engineering and phase regulation enables efficient and stable Ruddlesden-Popper perovskite solar cells

Rui Liu ^a ,
Yue Yu ^a ,
Lu Deng ^a ,
Maoxia Xu ^a ,
Haorong Ren ^a ,
Wenjie Luo ^a ,
Xudong Cai ^a ,
Zhenyu Li ^{a, b, *,} ,
Jingyu Chen ^{a, b, *,} ,
Hua Yu ^{c, *,}

a.
The Center of Functional Materials for Working Fluids of Oil and Gas Field, School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China
b.
Sichuan Engineering Technology Research Center of Basalt Fiber Composites Development and Application, State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, China
c.
School of Physical Sciences, Great Bay University, Dongguan 510799, China

zhenyu.li@swpu.edu.cn

jingyu_chencn@hotmail.com

yuhua@gbu.edu.cn

Received Date: 20 December 2023
Revised Date: 15 January 2024
Accepted Date: 17 January 2024
Available Online: 23 January 2024

Figures(6)

BA₂(MA)_n-1Pb_nI_3n+1 series low-dimensional (2D) perovskites have been widely investigated for their remarkable environmental stability, but still suffer the poor light absorption and disordered phase distribution, hindering their practical applications. In this work, we combine the introduction of FA and the addition of PbCl₂ to optimize the film quality, strengthen the light absorption, regulate internal phase distribution, and promote carrier transport inside 2D perovskite films. The incorporation of FA promotes sufficient light absorption and improve the film crystallinity. Furthermore, the addition of PbCl₂ eliminates the low n phase (n = 1) and suppresses the forming of the low n phase of n = 2, enhancing the film conductivity and diminishing carrier recombination. The synergistic of A-site cation engineering and phase manipulation achieves a high efficiency of 16.48%. Importantly, the synergistic prepared perovskite film does not show any changes after 60 days in the air with an average humidity of 57% ± 3%, and the corresponding solar cell maintains 85% of the original efficiency after more than 800 h, demonstrating remarkable environmental stability. The results indicate that the synergistic of A-site cation engineering and phase manipulation is promising for producing superior efficiency, along with satisfying humidity stability.
- Phase control,
- Layered perovskite,
- Synergistic effect,
- Low n phase,
- Stability
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沈阳化工大学材料科学与工程学院沈阳 110142