Citation: Yongjian Li, Xinyu Zhu, Chenxi Wei, Youyou Fang, Xinyu Wang, Yizhi Zhai, Wenlong Kang, Lai Chen, Duanyun Cao, Meng Wang, Yun Lu, Qing Huang, Yuefeng Su, Hong Yuan, Ning Li, Feng Wu. Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries[J]. Chinese Chemical Letters, ;2024, 35(12): 109536. doi: 10.1016/j.cclet.2024.109536 shu

Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries

Yongjian Li ^{a, b} ,
Xinyu Zhu ^{a, b} ,
Chenxi Wei ^c ,
Youyou Fang ^{a, b} ,
Xinyu Wang ^{a, b} ,
Yizhi Zhai ^a ,
Wenlong Kang ^a ,
Lai Chen ^{a, b} ,
Duanyun Cao ^{a, b} ,
Meng Wang ^b ,
Yun Lu ^{a, b} ,
Qing Huang ^{a, b} ,
Yuefeng Su ^{a, b, *,} ,
Hong Yuan ^{a, d, *,} ,
Ning Li ^{a, b, *,} ,
Feng Wu ^{a, b}

a.
School of Materials Science and Engineering, Beijing Key Laboratory of Environmental Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
b.
Chongqing Innovation Center, Beijing Institute of Technology, Chongqing 401120, China
c.
Center for Transformative Science, ShanghaiTech University, Shanghai 201210, China
d.
Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China

suyuefeng@bit.edu.cn

yuanhong@bit.edu.cn

ningli@bit.edu.cn

Received Date: 8 December 2023
Revised Date: 27 December 2023
Accepted Date: 11 January 2024
Available Online: 19 January 2024

Figures(4)

The prototype material, Li_1.23Ru_0.41Ni_0.36O₂, is proposed to gain the deep and comprehensive understanding of chemical and structural changes of the novel layered/rocksalt intergrown cathodes. Synchrotron-based X-ray absorption spectra and resonant inelastic X-ray scattering reveal that both cationic and anionic redox evolves in the charge compensation process of the intergrown material, while synchrotron-based extended X-ray fine structure spectra and in situ X-ray diffraction measurements demonstrates that the intergrown material undergoes minimal local- and long-range structural variations at deep de/lithiation. This work highlights the great potential of the intergrown structure to inspire the design of advanced cathode materials for lithium-ion batteries.
- Cathode materials,
- Intergrown structure,
- Cationic-anionic redox,
- Low strain,
- Synchrotron characterizations
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