Citation: Jun-Ting Mo, Zheng Wang. Achieving tunable long persistent luminescence in metal organic halides based on pyridine solvent[J]. Chinese Chemical Letters, ;2024, 35(9): 109360. doi: 10.1016/j.cclet.2023.109360 shu

Achieving tunable long persistent luminescence in metal organic halides based on pyridine solvent

Jun-Ting Mo ^{a, b} ,
Zheng Wang ^{a, *,}

a.
College of Chemistry and Chemical Engineering, Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science and Technology, Xi'an 710021, China
b.
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

wangzhengnw@126.com

Received Date: 16 October 2023
Revised Date: 2 December 2023
Accepted Date: 4 December 2023
Available Online: 5 December 2023

Figures(4)

The research of long persistent luminescence (LPL) materials has yield brilliant results in many fields. However, the efforts are still needed for the regulation of the LPL performance. In this work, a series of LPL metal organic halides with rich halogen-bond interactions, Py-CdX₂ (X = Cl, Br, I) were synthesized through self-assembly by CdX₂ and pyridine solvent. The steady-state emission redshifted and phosphorescence lifetime declined as the halogen atoms are aggravated. Three halides exhibit adjustable emission from blue to green and multiple phosphorescence from green to yellow at room temperature by changing the excitation wavelengths. Surprisingly, Py-CdX₂ can emit the visible color-tunable LPL from green to yellow after removing different excitation sources at ambient conditions. Combing the results of theoretical calculation and experimental analysis, it is found that heavy atom effect and the rich intermolecular halogen bond help realize LPL and multiple triplet states originated from the pyridine ring and the halogens.
- Metal organic halide,
- Heavy atom effect,
- Halogen bond,
- Tunable long persistent luminescence,
- Anti-counterfeiting
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