Citation: Rongliang Deng, Yihang Chen, Xiaotong Fan, Guolong Chen, Shuli Wang, Changzhi Yu, Xiao Yang, Tingzhu Wu, Zhong Chen, Yue Lin. Break of thermal equilibrium between optical and acoustic phonon branches of CsPbI₃ under continuous-wave light excitation and cryogenic temperature[J]. Chinese Chemical Letters, ;2024, 35(7): 109346. doi: 10.1016/j.cclet.2023.109346 shu

Break of thermal equilibrium between optical and acoustic phonon branches of CsPbI₃ under continuous-wave light excitation and cryogenic temperature

Rongliang Deng ^{a, 1} ,
Yihang Chen ^{a, 1} ,
Xiaotong Fan ^a ,
Guolong Chen ^a ,
Shuli Wang ^a ,
Changzhi Yu ^a ,
Xiao Yang ^{a, c} ,
Tingzhu Wu ^{a, b} ,
Zhong Chen ^{a, b} ,
Yue Lin ^{a, b, *,}

a.
Department of Electronic Science, Fujian Engineering Research Center for Solid-State Lighting, Xiamen University, Xiamen 361005, China
b.
Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen 361102, China
c.
Institute of Electromagnetics and Acoustics, School of Electronic Science and Engineering, Xiamen University, Xiamen 361005, China

yue.lin@xmu.edu.cn

Received Date: 10 October 2023
Revised Date: 13 November 2023
Accepted Date: 27 November 2023
Available Online: 7 December 2023

Figures(3)

The kinetic of low-temperature carrier and lattice of lead-halide perovskite is yet to be fully understood. In this work, we investigate the steady-state photoluminescences (PLs) of CsPbI₃ at the environmental temperature (T_e) ranging from 20 K to 300 K, and observed anomalous behaviors at cryogenic temperatures: The carrier temperature (T_c) of pure CsPbI₃ exhibits a negative correlation with T_e, accompanied by an expansion in Urbach tails of absorption spectra (Abs.) and excessive red-shifts at peak energy of PLs. These phenomena are also observed in those samples containing a certain amount of Cs₄PbI₆, but to a lesser extent and occurs at lower temperatures. It is attributed to the intensified hot phonon bottleneck effect (HPB) in CsPbI₃ at cryogenic T_e, which hinders the energy transfer from hot carriers, via longitudinal optics (LO) phonons to longitudinal acoustic (LA) phonons, to the ambient. For samples under continuous-wave laser excitation, in specific, the barrier induced by the enhanced HPB at low T_e prevents the effective thermalization among carriers, LO and LA phonons, which, therefore, form thermally isolated ensembles with different temperatures. At cryogenic T_e range, the elevated temperatures of carrier and LO phonon expand the high-energy side of PLs and the low-energy tail of Abs., respectively. For those samples in which the CsPbI₃ is mixed with Cs₄PbI₆, the interfacial LO-LO interaction across them provides a bypass for heat dissipation, mitigating the heat accumulation in LO-phonons of CsPbI₃. The results suggest that a strong HPB effect may break the thermal equilibrium among different branches of phonons in the lattice under certain extreme conditions.
- CsPbI₃,
- Cs₄PbI₆,
- Low-temperature carrier,
- Lattice kinetic,
- Hot phonon bottleneck effect,
- Interfacial LO-LO interaction
1. [1]
  J.Y. Kim, J.W. Lee, H.S. Jung, H. Shin, N.G. Park, Chem. Rev. 120 (2020) 7867–7918. doi: 10.1021/acs.chemrev.0c00107
2. [2]
  J. Yao, L. Xu, S. Wang, Z. Yang, J. Song, Nanoscale 14 (2022) 13990–14007. doi: 10.1039/d2nr03872b
3. [3]
  X. Fan, S. Wang, X. Yang, et al., Adv. Mater. 35 (2023) 2300834. doi: 10.1002/adma.202300834
4. [4]
  M. Li, P. Huang, H. Zhong, J. Phys. Chem. Lett. 14 (2023) 1592–1603. doi: 10.1021/acs.jpclett.2c03525
5. [5]
  S. Rudin, T.L. Reinecke, B. Segall, Phys. Rev. B: Condens. Matter Mater. Phys. 42 (1990) 11218–11231. doi: 10.1103/PhysRevB.42.11218
6. [6]
  J. Fu, Q. Xu, G. Han, et al., Nat. Commun. 8 (2017) 1300. doi: 10.1038/s41467-017-01360-3
7. [7]
  Y. Yang, D.P. Ostrowski, R.M. France, et al., Nat. Photonics 10 (2015) 53–59.
8. [8]
  Z. Nie, Z. Huang, M. Zhang, et al., ACS Photonics 9 (2022) 3457–3465. doi: 10.1021/acsphotonics.2c01394
9. [9]
  H. Shi, X. Zhang, X. Sun, X. Zhang, Appl. Phys. Lett. 116 (2020) 151902. doi: 10.1063/1.5145261
10. [10]
  F. Sekiguchi, H. Hirori, G. Yumoto, et al., Phys. Rev. Lett. 126 (2021) 077401. doi: 10.1103/PhysRevLett.126.077401
11. [11]
  Z. Nie, X. Gao, Y. Ren, et al., Nano Lett. 20 (2020) 4610–4617. doi: 10.1021/acs.nanolett.0c01452
12. [12]
  J. Yang, X. Wen, H. Xia, et al., Nat. Commun. 8 (2017) 14120. doi: 10.1038/ncomms14120
13. [13]
  J.W.M. Lim, Y. Wang, J. Fu, Q. Zhang, T.C. Sum, ACS Energy Lett. 7 (2022) 749–756. doi: 10.1021/acsenergylett.1c02581
14. [14]
  T.A. Go¨bel, M. Ruf, C.T. Cardona Lin, Phys. Rev. B 57 (1998) 15183. doi: 10.1103/PhysRevB.57.15183
15. [15]
  J. Lee, E.S. Koteles, M.O. Vassell, Phys. Rev. B: Condens. Matter Mater. Phys. 33 (1986) 5512–5516. doi: 10.1103/PhysRevB.33.5512
16. [16]
  J. Xu, S. Yu, X. Shang, X. Chen, Adv. Photonics Res. 4 (2022) 2200193.
17. [17]
  R. Saran, A. Heuer-Jungemann, A.G. Kanaras, R.J. Curry, Adv. Opt. Mater. (2017) 1700231.
18. [18]
  M. Ledinsky, T. Schonfeldova, J. Holovsky, et al., J. Phys. Chem. Lett. 10 (2019) 1368–1373. doi: 10.1021/acs.jpclett.9b00138
19. [19]
  Y. Xue, Y. Chen, G. Li, et al., Chin. Chem. Lett. 35 (2024) 108447. doi: 10.1016/j.cclet.2023.108447
20. [20]
  Z. Dai, J. Chen, B. Yang, J. Phys. Chem. Lett. 12 (2021) 10093–10098. doi: 10.1021/acs.jpclett.1c02798
21. [21]
  Z. Bao, C.Y. Hsiu, M.H. Fang, et al., ACS Appl. Mater. Interfaces 13 (2021) 34742–34751. doi: 10.1021/acsami.1c08920
22. [22]
  M.I. Saidaminov, J. Almutlaq, S. Sarmah, et al., ACS Energy Lett. 1 (2016) 840–845. doi: 10.1021/acsenergylett.6b00396
23. [23]
  J. Zhang, C. Liu, S. Wu, et al., J. Phys. Chem. C 126 (2022) 8777–8786. doi: 10.1021/acs.jpcc.2c02249
24. [24]
  G. Kaur, K.J. Babu, N. Ghorai, et al., J. Phys. Chem. Lett. 10 (2019) 5302–5311. doi: 10.1021/acs.jpclett.9b01552
25. [25]
  R. Deng, X. Fan, G. Chen, et al., J. Lumin. 257 (2023) 119701. doi: 10.1016/j.jlumin.2023.119701
26. [26]
  Y. Lin, X. Fan, X. Yang, et al., Small 17 (2021) 2103510. doi: 10.1002/smll.202103510
27. [27]
  R. Bhattacharya, B. Pal, B. Bansal, Appl. Phys. Lett. 100 (2012) 222103. doi: 10.1063/1.4721495
28. [28]
  G.D. Cody, T. Tiedje, B. Abeles, B. Brooks, Y. Goldstein, Phys. Rev. Lett. 47 (1981) 1480–1483. doi: 10.1103/PhysRevLett.47.1480
29. [29]
  C. Godet, Y. Bouizem, L. Chahed, et al., Phys. Rev. B: Condens. Matter Mater. Phys. 44 (1991) 5506–5509. doi: 10.1103/PhysRevB.44.5506
30. [30]
  M. Letz, A. Gottwald, M. Richter, L. Parthier, Phys. Rev. B 79 (2009) 195112. doi: 10.1103/PhysRevB.79.195112
1. [1]
  Yifan LIU , Zhan ZHANG , Rongmei ZHU , Ziming QIU , Huan PANG . A three-dimensional flower-like Cu-based composite and its low-temperature calcination derivatives for efficient oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 979-990. doi: 10.11862/CJIC.20240008
2. [2]
  Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NO_x reduction with improved N₂ selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132
3. [3]
  Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430
4. [4]
  Chenghao Ge , Peng Wang , Pei Yuan , Tai Wu , Rongjun Zhao , Rong Huang , Lin Xie , Yong Hua . Tuning hot carrier transfer dynamics by perovskite surface modification. Chinese Chemical Letters, 2024, 35(10): 109352-. doi: 10.1016/j.cclet.2023.109352
5. [5]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
6. [6]
  Hui Peng , Xiao Wang , Weiguo Huang , Shuiyue Yu , Linghang Kong , Qilin Wei , Jialong Zhao , Bingsuo Zou . Efficient tunable visible and near-infrared emission in Sb³⁺/Sm³⁺-codoped Cs₂NaLuCl₆ for near-infrared light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption. Chinese Chemical Letters, 2024, 35(11): 109462-. doi: 10.1016/j.cclet.2023.109462
7. [7]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2024.100416
8. [8]
  Zheyu Li , Huwei Li , Yao Li , Xinyu Fu , Hongxia Yue , Qingxing Yang , Jing Feng , Xinyu Wang , Hongjie Zhang . The effect of electron-phonon coupling on the photoluminescence properties of zinc-based halides. Chinese Chemical Letters, 2025, 36(4): 109800-. doi: 10.1016/j.cclet.2024.109800
9. [9]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
10. [10]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
11. [11]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
12. [12]
  Linjing Li , Wenlai Xu , Jianyong Ning , Yaping Zhong , Chuyue Zhang , Jiane Zuo , Zhicheng Pan . Revealing the intrinsic mechanisms for accelerating nitrogen removal efficiency in the Anammox reactor by adding Fe(II) at low temperature. Chinese Chemical Letters, 2024, 35(8): 109243-. doi: 10.1016/j.cclet.2023.109243
13. [13]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116
14. [14]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
15. [15]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
16. [16]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
17. [17]
  Meng Wang , Yan Zhang , Yunbo Yu , Wenpo Shan , Hong He . High-temperature calcination dramatically promotes the activity of Cs/Co/Ce-Sn catalyst for soot oxidation. Chinese Chemical Letters, 2025, 36(1): 109928-. doi: 10.1016/j.cclet.2024.109928
18. [18]
  Tong Tong , Lezong Chen , Siying Wu , Zhong Cao , Yuanbin Song , Jun Wu . Establishment of a leucine-based poly(ester amide)s library with self-anticancer effect as nano-drug carrier for colorectal cancer treatment. Chinese Chemical Letters, 2024, 35(12): 109689-. doi: 10.1016/j.cclet.2024.109689
19. [19]
  Dan-Ying Xing , Xiao-Dan Zhao , Chuan-Shu He , Bo Lai . Kinetic study and DFT calculation on the tetracycline abatement by peracetic acid. Chinese Chemical Letters, 2024, 35(9): 109436-. doi: 10.1016/j.cclet.2023.109436
20. [20]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(256)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Break of thermal equilibrium between optical and acoustic phonon branches of CsPbI3 under continuous-wave light excitation and cryogenic temperature

Metrics

通讯作者: 陈斌, bchen63@163.com

Break of thermal equilibrium between optical and acoustic phonon branches of CsPbI₃ under continuous-wave light excitation and cryogenic temperature