Citation: Tao Long, Peng Chen, Bin Feng, Caili Yang, Kairong Wang, Yulei Wang, Can Chen, Yaping Wang, Ruotong Li, Meng Wu, Minhuan Lan, Wei Kong Pang, Jian-Fang Wu, Yuan-Li Ding. Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode[J]. Chinese Chemical Letters, ;2024, 35(4): 109267. doi: 10.1016/j.cclet.2023.109267 shu

Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode

Tao Long ^a ,
Peng Chen ^a ,
Bin Feng ^a ,
Caili Yang ^a ,
Kairong Wang ^a ,
Yulei Wang ^a ,
Can Chen ^a ,
Yaping Wang ^a ,
Ruotong Li ^a ,
Meng Wu ^{b, *,} ,
Minhuan Lan ^c ,
Wei Kong Pang ^d ,
Jian-Fang Wu ^a ,
Yuan-Li Ding ^{a, *,}

a.
College of Materials Science and Engineering, Hunan University, Changsha 410082, China
b.
Department of Physics, Xiamen University, Xiamen 361005, China
c.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
d.
Institute for Superconducting & Electronic Materials, Faculty of Engineering, University of Wollongong, Wollongong, NSW 2522, Australia

meng.wu@xmu.edu.cn

ylding@hnu.edu.cn

Received Date: 19 September 2023
Revised Date: 12 October 2023
Accepted Date: 31 October 2023
Available Online: 3 November 2023

Figures(4)

Realizing high-rate capability and high-efficiency utilization of polyanionic cathode materials is of great importance for practical sodium-ion batteries (SIBs) since they usually suffer from extremely low electronic conductivity and limited ionic diffusion kinetics. Herein, taking Na_3.5V_1.5Mn_0.5(PO₄)₃ (NVMP) as an example, a reinforced concrete-like hierarchical and porous hybrid (NVMP@C@3DPG) built from 3D graphene ("rebar") frameworks and in situ generated carbon coated NVMP ("concrete") has been developed by a facile polymer assisted self-assembly and subsequent solid-state method. Such hybrids deliver superior rate capability (73.9 mAh/g up to 20 C) and excellent cycling stability in a wide temperature range with a high specific capacity of 88.4 mAh/g after 5000 cycles at 15 C at room temperature, and a high capacity retention of 97.1% after 500 cycles at 1 C (−20 ℃), and maintaining a high reversible capacity of 110.3 mAh/g in full cell. This work offers a facile and efficient strategy to develop advanced polyanionic cathodes with high-efficiency utilization and 3D electron/ion transport systems.
- Sodium-ion battery,
- Polyanionic cathode,
- Hybrid structure,
- Interconnected structure,
- Energy storage
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沈阳化工大学材料科学与工程学院沈阳 110142

Reinforced concrete-like Na3.5V1.5Mn0.5(PO4)3@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode

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通讯作者: 陈斌, bchen63@163.com

Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode