Citation: Juan Guo, Mingyuan Fang, Qingsong Liu, Xiao Ren, Yongqiang Qiao, Mingju Chao, Erjun Liang, Qilong Gao. Zero thermal expansion in Cs₂W₃O₁₀[J]. Chinese Chemical Letters, ;2024, 35(7): 108957. doi: 10.1016/j.cclet.2023.108957 shu

Zero thermal expansion in Cs₂W₃O₁₀

School of Physics & Microelectronics, Key Laboratory of Materials Physics of Ministry of Education of China, Zhengzhou University, Zhengzhou 450052, China

qilonggao@zzu.edu.cn

Received Date: 20 June 2023
Revised Date: 22 July 2023
Accepted Date: 21 August 2023
Available Online: 23 August 2023

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Zero thermal expansion materials are important for the practical applications due to their shape stability as changing temperature. The reported concept of average atomic volume is an available method to hunt new zero thermal expansion materials. Here, according to this concept, a tetragonal tungstate Cs₂W₃O₁₀ with zero expansion has been found. There is no structure phase transition as increasing temperature from 150 K to 573 K. The coefficient of thermal expansion of axes and volume are α_a = 0.0074 × 10⁻⁶ K⁻¹, α_c = 1.63 × 10⁻⁶ K⁻¹, and α_V = 1.60 × 10⁻⁶ K⁻¹, respectively, in the temperature range of 150 ~ 573 K. The temperature- and pressure-dependent Raman spectra reveal that the vibrations of WO₆ octahedra libration modes with positive total anharmonicity and W-O-W bending mode with negative Grüneisen parameter are possibly the origin of zero thermal expansion in Cs₂W₃O₁₀.
- Zero thermal expansion,
- Cesium tungstate,
- Raman spectra,
- Average atomic volume,
- Temperature-dependent X-ray diffraction
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Zero thermal expansion in Cs₂W₃O₁₀