Citation: Shuaiwen Li, Zihui Chen, Feng Yang, Wanqing Yue. The age of vanadium-based nanozymes: Synthesis, catalytic mechanisms, regulation and biomedical applications[J]. Chinese Chemical Letters, ;2024, 35(4): 108793. doi: 10.1016/j.cclet.2023.108793 shu

The age of vanadium-based nanozymes: Synthesis, catalytic mechanisms, regulation and biomedical applications

Shuaiwen Li ^a ,
Zihui Chen ^a ,
Feng Yang ^a ,
Wanqing Yue ^{a, b, *,}

a.
Department of Chemistry, Key Laboratory of Biomedical Functional Materials, School of Science, China Pharmaceutical University, Nanjing 211198, China
b.
Key Laboratory of Drug Quality Control and Pharmacovigilance (China Pharmaceutical University), Ministry of Education, Nanjing 211198, China

yuewq@cpu.edu.cn

Received Date: 19 April 2023
Revised Date: 30 June 2023
Accepted Date: 7 July 2023
Available Online: 8 July 2023

Figures(2)

Nanomaterials with enzyme-mimic (nanozyme) activity have garnered considerable attention as a potential alternative to natural enzymes, thanks to their low preparation cost, high activity, ease of preservation, and unique physicochemical properties. Vanadium (V) is a transition metal that integrates the benefits of valence-richness, low cost, and non-toxicity, making it a desirable candidate for developing a range of emerging nanozymes. In this review, we provide the first systematic summary of recent research progress on V-based nanozymes. First, we summarize the preparation of V-based nanozymes using both top-down and bottom-up synthesis methods. Next, we review the mechanism of V-based nanozymes that mimic the activity of various enzymes. We then discuss methods for regulating V-based nanozyme activity, including morphology, size, valence engineering, defect engineering, external triggering, and surface engineering. Afterward, we outline various biomedical applications, including therapeutic, anti-inflammatory, antibacterial, and biosensing. Finally, we prospect the challenges and countermeasures for V-based nanozymes based on their development. By summarizing recent research progress on V-based nanozymes, we hope to provide useful insights for researchers to further explore their potential applications and overcome their existing challenges.
- Vanadium,
- Nanozymes,
- Catalytic mechanisms,
- Biomedical applications,
- Regulation
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沈阳化工大学材料科学与工程学院沈阳 110142