Citation: Dun Ma, Xiujun He, Jingshan He, Huanxin Guo, Yongzhen Wu, Wenjun Wu, Weihong Zhu. Selective coordination of polyazin sapanisertib with halide vacancy for printable mesoscopic perovskite solar cells[J]. Chinese Chemical Letters, ;2023, 34(12): 108629. doi: 10.1016/j.cclet.2023.108629 shu

Selective coordination of polyazin sapanisertib with halide vacancy for printable mesoscopic perovskite solar cells

Dun Ma ^a ,
Xiujun He ^b ,
Jingshan He ^a ,
Huanxin Guo ^a ,
Yongzhen Wu ^a ,
Wenjun Wu ^{a, *,} ,
Weihong Zhu ^a

a.
Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, Shanghai Key Laboratory of Functional Materials Chemistry, East China University of Science and Technology, Shanghai 200237, China
b.
Yaopu (Shanghai) Pharmaceutical Technology Co., Ltd., Shanghai 201108, China

wjwu@ecust.edu.cn

Received Date: 17 December 2022
Revised Date: 27 May 2023
Accepted Date: 29 May 2023
Available Online: 3 June 2023

Figures(5)

The mitigation of under-coordinated Pb²⁺ (halide vacancy) defect remains an imperative challenge in the perovskite solar cells, especially printable mesoscopic perovskite solar cells (FP-PSCs). Here we report a commercial-available polyazin anticancer drug Sapanisertib as coordination passivator of halide vacancies in FP-PSCs, thereby achieving the photoelectric conversion efficiency (PCE) to 18.46%, along with a record certified PCE of 18.27%. In polazin Sapanisertib (Sap), there exists two kinds of nitrogen atoms: in-aromatic ring (in purine and oxazole rings, IAR-Ns) and out-aromatic ring (substituted amino groups, OAR-Ns). Through multiple characterizations, and DFT calculations show that substituted amino groups OAR-Ns hardly get interaction with the halide vacancy due to the distribution of charge density in Sapanisertib. Our work suggests that the selective coordination is of great significance for the design of high-performance passivators for printable mesoscopic perovskite solar cells.
- Sapanisertib,
- Lead vacancies,
- Coordination,
- Passivator,
- Perovskite
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