Citation: Shengyu Zhao, Qinhao Shi, Wuliang Feng, Yang Liu, Xinxin Yang, Xingli Zou, Xionggang Lu, Yufeng Zhao. Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries[J]. Chinese Chemical Letters, ;2024, 35(5): 108606. doi: 10.1016/j.cclet.2023.108606 shu

Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries

Shengyu Zhao ^a ,
Qinhao Shi ^a ,
Wuliang Feng ^a ,
Yang Liu ^a ,
Xinxin Yang ^b ,
Xingli Zou ^b ,
Xionggang Lu ^b ,
Yufeng Zhao ^{a, *,}

a.
Institute for Sustainable Energy & College of Sciences, Shanghai University, Shanghai 200444, China
b.
State Key Laboratory of Advanced Special Steel & Shanghai Key Laboratory of Advanced Ferrometallurgy & School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China

yufengzhao@shu.edu.cn

Received Date: 1 April 2023
Revised Date: 7 May 2023
Accepted Date: 23 May 2023
Available Online: 25 May 2023

Figures(6)

O3-type layered oxide cathodes have been widely investigated due to their high reversible capacities and sufficient Na⁺ reservoirs. However, such materials usually suffer from complex multistep phase transitions along with drastic volume changes, leading to the unsatisfied cycle performance. Herein, we report a Mg/Ti co-doped O3-type NaNi_0.5Mn_0.5O₂, which can effectively suppress the complex multistep phase transition and realize a solid-solution reaction within a wide voltage range. It is confirmed that, the Mg/Ti co-doping is beneficial to enhance the structural stability and integrity by absorbing micro-strain and distortions. Thus, the as obtained sample delivers an outstanding cyclic performance (82.3% after 200 cycles at 1 C) in the voltage range of 2.0–4.0 V, and a high discharge capacity of 86.6 mAh/g after 100 cycles within the wide voltage range (2.0–4.5 V), which outperform the existing literatures. This co-doping strategy offers new insights into high performance O3-type cathode for sodium ion batteries.
- Sodium ion batteries,
- Mg/Ti co-doping,
- Phase transition,
- Cyclic performance,
- High voltage performance
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