Citation: Cangxu Feng, Jianwei Zhang, Chao Bian, Linyang Li, Rong Hu, Haixing Chang, Fei Peng, Xiaofeng Peng, Nianbing Zhong. Solid–liquid-core optical fiber biosensor for highly sensitive and selective detection of 4-chlorophenol in water[J]. Chinese Chemical Letters, ;2023, 34(12): 108457. doi: 10.1016/j.cclet.2023.108457 shu

Solid–liquid-core optical fiber biosensor for highly sensitive and selective detection of 4-chlorophenol in water

Cangxu Feng ^{a, b} ,
Jianwei Zhang ^a ,
Chao Bian ^{a, b, *,} ,
Linyang Li ^b ,
Rong Hu ^b ,
Haixing Chang ^c ,
Fei Peng ^b ,
Xiaofeng Peng ^{b, *,} ,
Nianbing Zhong ^{b, *,}

a.
Center for Hydrogeology and Environmental Geology Survey, China Geological Survey, Baoding 071051, China
b.
Intelligent Fiber Sensing Technology of Chongqing Municipal Engineering Research Center of Institutions of Higher Education, Chongqing Key Laboratory of Modern Photoelectric Detection Technology and Instrument, Chongqing Key Laboratory of Fiber Optic Sensor and Photodetector, Chongqing University of Technology, Chongqing 400054, China
c.
School of Chemistry and Chemical Engineering, Chongqing University of Technology, Chongqing 400054, China

chao_bian@126.com

pxf@cqut.edu.cn

pxlb08@cqut.edu.cn

Received Date: 23 November 2022
Revised Date: 8 March 2023
Accepted Date: 14 April 2023
Available Online: 15 April 2023

Figures(4)

A novel solid–liquid-core fiber-optic biosensor was fabricated for highly sensitive and selective detection of 4-chlorophenol in water. The sensor comprised horseradish peroxidase (HRP)-coated U-shaped liquid-core optical fiber (LCOF) and 4-chlorophenol permselective polymer membrane. The U-shaped LCOF was filled with ethanol suspension of SiO₂ particles and the polymer membrane was composed of molecularly imprinted polymer, sulfonated polyethersulfone, and polysulfone. The morphology, composition, and surface luminous properties of the sensing region were examined. The effects of the diameter and content of SiO₂ particles and temperature of 4-chlorophenol solutions on the sensitivity of the biosensors were investigated. Further, the sensitivity, selectivity, response time, and limit of detection (LOD) of the biosensors was investigated. In addition, the effects of fiber core materials on the light transmission in sensing region were investigated and a biosensor sensing model was established. The proposed sensor exhibited high selectivity for 4-chlorophenol with satisfactory sensitivity, LOD, and response time: -1.18 (µg/L)⁻¹, 30 µg/L, and 400 s, respectively. The results are expected to aid in the development of methods for enhancing sensitivity of fiber-optic sensors and surface luminous intensity of optical fibers.
- 4-Chlorophenol,
- Solid–liquid-core optical fiber,
- Horseradish peroxidase,
- Permselective polymer membrane,
- Sensitivity,
- Selectivity
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沈阳化工大学材料科学与工程学院沈阳 110142