Citation: Yifei Li, Yuechang Wei, Wenjie He, Zhiling Tang, Jing Xiong, Zhen Zhao. Ordered macroporous structured TiO₂-based photocatalysts for CO₂ reduction: A review[J]. Chinese Chemical Letters, ;2023, 34(12): 108417. doi: 10.1016/j.cclet.2023.108417 shu

Ordered macroporous structured TiO₂-based photocatalysts for CO₂ reduction: A review

Yifei Li ^a ,
Yuechang Wei ^{a, b, *,} ,
Wenjie He ^a ,
Zhiling Tang ^a ,
Jing Xiong ^{a, b} ,
Zhen Zhao ^a

a.
State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China
b.
Key Laboratory of Optical Detection Technology for Oil and Gas, China University of Petroleum, Beijing 102249, China

weiyc@cup.edu.cn

Received Date: 26 September 2022
Revised Date: 7 March 2023
Accepted Date: 31 March 2023
Available Online: 5 April 2023

Figures(23)

Herein, we review the significant of ordered macroporous (OM) TiO₂-based catalysts for boosting photocatalytic CO₂ reduction. Based on the need to improve the three key factors of photogenerated charge separation efficiency, solar energy utilization and CO₂ adsorption rate during the conversion of CO₂ to H₂O, we summarized five modification measures: including doping ions into OM TiO₂, introducing second semiconductor coupling and noble metal nanoparticles for fabricating multiple Z-scheme heterojunctions, constructing hierarchical pore and carbon-loaded OM TiO₂ materials, which effectively enhance the absorption rate of visible light, the separation rate of electrons-hole pairs and the selection of multiple active sites. The OM structured TiO₂-based photocatalysts solve the single or multiple key factors for enhancing photocatalytic performances during CO₂ conversion. The catalytic mechanism and pathways of OM structured TiO₂-based photocatalysts for CO₂ reduction are discussed and summarized. It provides new insights on the development of high-efficient catalyst for photocatalytic CO₂ conversion to solar fuels.
- TiO₂-based materials,
- Hierarchical pore,
- CO₂ reduction,
- Photocatalysts,
- Solar fuels
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沈阳化工大学材料科学与工程学院沈阳 110142

Ordered macroporous structured TiO2-based photocatalysts for CO2 reduction: A review

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通讯作者: 陈斌, bchen63@163.com

Ordered macroporous structured TiO₂-based photocatalysts for CO₂ reduction: A review