Citation: Lu Liu, Xiao-Li Chen, Miao Cai, Rui-Kui Yan, Hua-Li Cui, Hua Yang, Ji-Jiang Wang. Dye@MOF composites (RhB@1): Highly sensitive dual emission sensor for the detection of pesticides, Fe³⁺ and ascorbate acid[J]. Chinese Chemical Letters, ;2023, 34(10): 108411. doi: 10.1016/j.cclet.2023.108411 shu

Dye@MOF composites (RhB@1): Highly sensitive dual emission sensor for the detection of pesticides, Fe³⁺ and ascorbate acid

School of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Laboratory of New Energy and New Function Materials, Yan’an University, Yan’an 716000, China

chenxiaoli003@163.com

Received Date: 1 November 2022
Revised Date: 11 February 2023
Accepted Date: 30 March 2023
Available Online: 31 March 2023

Figures(4)

With the rapid development of economy, industrial and agricultural pollutants have caused great damage to the ecological environment and the normal development of organisms, posing a serious threat to global public health. Therefore, rapid and sensitive detection of pollutants is very important for environmental safety and people’s health. A stable multi-response fluorescence sensor (RhB@1) with dual emission characteristics was constructed by embedding RhB guest molecules in Zn-MOF using a simple one-pot method. XRD, IR, XPS, Raman and other characterization methods were used to demonstrate the formation of composite materials. The sensor has two fluorescence emission peaks at 415 nm and 575 nm under the excitation of 316 nm. It has high sensitivity and low detection limit (7.94 and 7.82 nmol/L, respectively) in the detection of fluazinam (FLU) and Fe³⁺. The mechanism of fluorescence quenching may be due to the synergistic effect of IFE and PET. Outstandingly, when ascorbate acid (AA) was added to the quenching system of Fe³⁺ and RhB@1, its fluorescence gradually recovered, forming the unique “on-off-on” sensor. Therefore, RhB@1 has a fast fluorescence response and good stability, making it potentially useful in practical application and biosensors. More significantly, using Fe³⁺ and AA as chemical input signals, a binary intelligent logic gate device has been developed based on the “on-off-on” response mode of RhB@1, which extends the application of logic gate switching devices in the chemical field. In addition, a visual portable test paper with good selectivity and high sensitivity was developed, which can be used for rapid detection of FLU, showing its broad application prospect.
- Metal-organic framework,
- Rhodamine B,
- Pesticides,
- Fe³⁺,
- Ascorbate acid,
- Fluorescence sensing
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沈阳化工大学材料科学与工程学院沈阳 110142

Dye@MOF composites (RhB@1): Highly sensitive dual emission sensor for the detection of pesticides, Fe3+ and ascorbate acid

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通讯作者: 陈斌, bchen63@163.com

Dye@MOF composites (RhB@1): Highly sensitive dual emission sensor for the detection of pesticides, Fe³⁺ and ascorbate acid