Citation: Yaping Gong, Xiaoxian Chen, Bingqing Zhao, Jun Wang, Weixiong Zhang, Xiaoming Chen. Ferroelastic phase transitions in three new layered perovskites: (3-XC₆H₅CH₂CH₂NH₃)₂[CdCl₄] (X = F, Cl, and Br)[J]. Chinese Chemical Letters, ;2023, 34(12): 108282. doi: 10.1016/j.cclet.2023.108282 shu

Ferroelastic phase transitions in three new layered perovskites: (3-XC₆H₅CH₂CH₂NH₃)₂[CdCl₄] (X = F, Cl, and Br)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China

zhangwx6@mail.sysu.edu.cn

Received Date: 10 November 2022
Revised Date: 19 February 2023
Accepted Date: 28 February 2023
Available Online: 6 March 2023

Figures(5)

Two-dimensional organic-inorganic hybrid ferroelastics with high-temperature reversible phase transitions are very rare and have become one of the research hotspots in the field of ferroelastic materials. Herein, we report three new layered organic-inorganic hybrid perovskites based on halogen-substituted phenethylaminium, (3-XC₆H₅CH₂CH₂NH₃)₂[CdCl₄] (X = F (1), Cl (2) and Br (3)). They undergo structural phase transitions at 376/371 K, 436/430 K, and 421/411 K, respectively, between the isomorphic high-temperature phases (space group I4/mmm, Z = 2) and different room-temperature phases with the reduced structural symmetries, i.e., P2₁/a (Z = 2) in 1, (Z = 4) in 2, and P2₁/a (Z = 4) in 3, respectively. These ferroelastic transitions arise from the order-disorder transition of organic cations together with the synchronous displacement of inorganic layers, accompanying with ferroelastic spontaneous strains of 0.16, 0.13 and 0.12 for 1−3, respectively. By enriching layered perovskite ferroelastics based on halogen-substituted cations, this work provides important clues for exploring new ferroic materials based on hybrid crystals.
- Layered perovskite,
- Phase transition,
- Halogen-substituted,
- Ferroelastic,
- Spontaneous strain
1. [1]
  U. Bismayer, E. Salje, A.M. Glazer, et al., Phase Transit. 6 (1986) 129–151. doi: 10.1080/01411598608221634
2. [2]
  S.A.T. Salje, E. Salje, J. Phys. C Solid State Phys. 21 (1988) 277–285. doi: 10.1088/0022-3719/21/2/011
3. [3]
  J. Sapriel, Phys. Rev. B 12 (1975) 5128–5140. doi: 10.1103/PhysRevB.12.5128
4. [4]
  E.G. Fesenko, V.G. Gavrilyatchenko, A.F. Semenchev, Ferroelectrics 100 (1989) 195–207. doi: 10.1080/00150198908007915
5. [5]
  J. Li, Y. Zhu, P.Z. Huang, et al., Chem. Eur. J. (2022) e202201005.
6. [6]
  D.X. Liu, Z.H. Yu, X.X. Chen, et al., Chin. Chem. Lett. 34 (2023) 107310. doi: 10.1016/j.cclet.2022.03.033
7. [7]
  H.Y. Zhang, C.L. Hu, Z.B. Hu, et al., J. Am. Chem. Soc. 142 (2020) 3240–3245. doi: 10.1021/jacs.9b13446
8. [8]
  E.K.H. Salje, G. Hoppmann, Mat. Res. Bull. 11 (1976) 1545–1550. doi: 10.1016/0025-5408(76)90107-0
9. [9]
  E.K.H. Salje, Ferroelectrics 104 (1990) 111–120. doi: 10.1080/00150199008223816
10. [10]
  P.J. Fillingham, J. Appl. Phys. 38 (1967) 4823–4829. doi: 10.1063/1.1709228
11. [11]
  K. Aizu, A. Kumada, H. Yumoto, et al., J. Phys. Soc. Jpn. 27 (1969) 511. doi: 10.1143/JPSJ.27.511
12. [12]
  Z. An, S. Xie, N. Zhang, et al., APL Mater. 9 (2021) 030702. doi: 10.1063/5.0038996
13. [13]
  V. Nagarajan, A. Roytburd, A. Stanishevsky, et al., Nat. Mater. 2 (2003) 43–47. doi: 10.1038/nmat800
14. [14]
  K. Dorr, Nat. Mater. 15 (2016) 497–498. doi: 10.1038/nmat4596
15. [15]
  T. Delgado, A. Tissot, L. Guenee, et al., J. Am. Chem. Soc. 140 (2018) 12870–12876. doi: 10.1021/jacs.8b06042
16. [16]
  C. Su, M. Lun, Y. Chen, et al., CCS Chem. 4 (2022) 2009–2019. doi: 10.31635/ccschem.021.202101073
17. [17]
  H.Y. Zhang, Y.Y. Tang, P.P. Shi, et al., Acc. Chem. Res. 52 (2019) 1928–1938. doi: 10.1021/acs.accounts.8b00677
18. [18]
  X.X. Chen, X.Y. Zhang, D.X. Liu, et al., Chem. Sci. 12 (2021) 8713–8721. doi: 10.1039/D1SC01345A
19. [19]
  D.W. Fu, H.L. Cai, Y. Liu, et al., Science 339 (2013) 425–428. doi: 10.1126/science.1229675
20. [20]
  J.X. Gao, X.N. Hua, P.F. Li, et al., J. Phys. Chem. C 122 (2018) 23111–23116. doi: 10.1021/acs.jpcc.8b07853
21. [21]
  X. Meng, Z.B. Liu, K. Xu, et al., Inorg. Chem. Front. 9 (2022) 1603–1608. doi: 10.1039/D1QI01533H
22. [22]
  X. Xiao, J. Zhou, K. Song, et al., Nat. Commun. 12 (2021) 1332. doi: 10.1038/s41467-021-21493-w
23. [23]
  Z.B. Liu, L. He, P.P. Shi, et al., J. Phys. Chem. Lett. 11 (2020) 7960–7965. doi: 10.1021/acs.jpclett.0c02235
24. [24]
  M. Rok, B. Zarychta, R. Janicki, et al., Inorg. Chem. 61 (2022) 5626–5636. doi: 10.1021/acs.inorgchem.2c00363
25. [25]
  X.Q. Xu, H. Zhang, X.Q. Huang, et al., Inorg. Chem. Front. 8 (2021) 1197–1204.
26. [26]
  Y.P. Gong, X.X. Chen, G.Z. Huang, et al., J. Mater. Chem. C 10 (2022) 5482–5488. doi: 10.1039/D2TC00335J
27. [27]
  B. Huang, L.Y. Sun, S.S. Wang, et al., Chem. Commun. 53 (2017) 5764–5766. doi: 10.1039/C7CC02408H
28. [28]
  B. Huang, J.Y. Zhang, R.K. Huang, et al., Chem. Sci. 9 (2018) 7413–7418. doi: 10.1039/C8SC02917B
29. [29]
  P.P. Shi, S.Q. Lu, X.J. Song, et al., J. Am. Chem. Soc. 141 (2019) 18334–18340. doi: 10.1021/jacs.9b10048
30. [30]
  J. Li, X. Liu, P. Cui, et al., Sci. China Chem. 62 (2019) 1257–1262.
31. [31]
  Y. Nakayama, S. Nishihara, K. Inoue, et al., Angew. Chem. Int. Ed. 56 (2017) 9367–9370. doi: 10.1002/anie.201703898
32. [32]
  B. Huang, B.Y. Wang, Z.Y. Du, et al., J. Mater. Chem. C 4 (2016) 8704–8710. doi: 10.1039/C6TC02715F
33. [33]
  Y.Y. Yu, P.Z. Huang, Y.Z. Wang, et al., Chin. Chem. Lett. 32 (2021) 3558–3561. doi: 10.1016/j.cclet.2021.02.040
34. [34]
  H. Ye, W.H. Hu, W.J. Xu, et al., APL Mater. 9 (2021) 031102. doi: 10.1063/5.0035793
35. [35]
  Y.J. Cao, L. Zhou, L. He, et al., Chem. Eur. J. 26 (2020) 14124–14129. doi: 10.1002/chem.202001266
36. [36]
  Y. Yu, P. Huang, Y. Wang, et al., Chin. Chem. Lett. 32 (2021) 3558–3561. doi: 10.1016/j.cclet.2021.02.040
37. [37]
  S. Liu, L. He, Y. Wang, et al., Chin. Chem. Lett. 33 (2022) 1032–1036. doi: 10.1016/j.cclet.2021.07.039
38. [38]
  X.K. Liu, F. Gao, J. Phys. Chem. Lett. 9 (2018) 2251–2258. doi: 10.1021/acs.jpclett.8b00755
39. [39]
  T. Schmitt, S. Bourelle, N. Tye, et al., J. Am. Chem. Soc. 142 (2020) 5060–5067. doi: 10.1021/jacs.9b11809
40. [40]
  M. Li, M.S. Molokeev, J. Zhao, et al., Adv. Opt. Mater. 8 (2020) 2000418. doi: 10.1002/adom.202000418
41. [41]
  H.Y. Liu, H.Y. Zhang, X.G. Chen, et al., J. Am. Chem. Soc. 142 (2020) 15205–15218. doi: 10.1021/jacs.0c07055
42. [42]
  W. Ning, F. Gao, Adv. Mater. 31 (2019) e1900326. doi: 10.1002/adma.201900326
43. [43]
  M. Groh, R. Spengler, H. Burzlaff, et al., Acta Crystallogr. Sect. C: Cryst. Struct. Commun. 53 (1997) 1199–1201. doi: 10.1107/S0108270197005726
44. [44]
  S. Kassou, A. Kaiba, P. Guionneau, et al., J. Struct. Chem. 57 (2016) 737–743. doi: 10.1134/S0022476616040168
45. [45]
  K. Aizu, J. Phys. Soc. Jpn. 27 (1969) 387–396. doi: 10.1143/JPSJ.27.387
46. [46]
  M.J. Cliffe, A.L. Goodwin, J. Appl. Crystallogr. 45 (2012) 1321–1329. doi: 10.1107/S0021889812043026
47. [47]
  S. Han, X. Liu, J. Zhang, et al., J. Mater. Chem. C 6 (2018) 10327–10331. doi: 10.1039/C8TC03517B
48. [48]
  Z.X. Wang, W.Q. Liao, H.Y. Ye, et al., Dalton Trans. 44 (2015) 20406–20412. doi: 10.1039/C5DT03277F
49. [49]
  X.N. Hua, C.R. Huang, J.X. Gao, et al., Dalton Trans. 47 (2018) 6218–6224. doi: 10.1039/C8DT00786A
50. [50]
  M.A. Spackman, D. Jayatilaka, CrystEngComm 11 (2009) 19–32. doi: 10.1039/B818330A
51. [51]
  Z.Y. Yue, W. Luo, N. Wang, et al., CrystEngComm 25 (2023) 1270–1275. doi: 10.1039/D2CE01390H
1. [1]
  Zhaohong Chen , Mengzhen Li , Jinfei Lan , Shengqian Hu , Xiaogang Chen . Organic ferroelastic enantiomers with high T_c and large dielectric switching ratio triggered by order-disorder and displacive phase transition. Chinese Chemical Letters, 2024, 35(10): 109548-. doi: 10.1016/j.cclet.2024.109548
2. [2]
  Rui Liu , Yue Yu , Lu Deng , Maoxia Xu , Haorong Ren , Wenjie Luo , Xudong Cai , Zhenyu Li , Jingyu Chen , Hua Yu . The synergistic effect of A-site cation engineering and phase regulation enables efficient and stable Ruddlesden-Popper perovskite solar cells. Chinese Chemical Letters, 2024, 35(12): 109545-. doi: 10.1016/j.cclet.2024.109545
3. [3]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
4. [4]
  Zhi-Yuan Yue , Hua-Kai Li , Na Wang , Shan-Shan Liu , Le-Ping Miao , Heng-Yun Ye , Chao Shi . Dehydration-triggered structural phase transition-associated ferroelectricity in a hybrid perovskite-type crystal. Chinese Chemical Letters, 2024, 35(10): 109355-. doi: 10.1016/j.cclet.2023.109355
5. [5]
  Ying-Yu Zhang , Jia-Qi Luo , Yan Han , Wan-Ying Zhang , Yi Zhang , Hai-Feng Lu , Da-Wei Fu . Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature. Chinese Chemical Letters, 2025, 36(1): 109530-. doi: 10.1016/j.cclet.2024.109530
6. [6]
  Hao-Fei Ni , Jia-He Lin , Gele Teri , Qiang-Qiang Jia , Pei-Zhi Huang , Hai-Feng Lu , Chang-Feng Wang , Zhi-Xu Zhang , Da-Wei Fu , Yi Zhang . B-site ion regulation strategy enables performance optimization and multifunctional integration of hybrid perovskite ferroelectrics. Chinese Chemical Letters, 2025, 36(3): 109690-. doi: 10.1016/j.cclet.2024.109690
7. [7]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
8. [8]
  Keke Han , Wenjun Rao , Xiuli You , Haina Zhang , Xing Ye , Zhenhong Wei , Hu Cai . Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO₄⁻, ReO₄⁻). Chinese Chemical Letters, 2024, 35(6): 108809-. doi: 10.1016/j.cclet.2023.108809
9. [9]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
10. [10]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
11. [11]
  Mao-Fan Li , Ming‐Yu Guo , De-Xuan Liu , Xiao-Xian Chen , Wei-Jian Xu , Wei-Xiong Zhang . Multi-stimuli responsive behaviors in a new chiral hybrid nitroprusside salt (R-3-hydroxypyrrolidinium)₂[Fe(CN)₅(NO)]. Chinese Chemical Letters, 2024, 35(12): 109507-. doi: 10.1016/j.cclet.2024.109507
12. [12]
  Fan Wu , Shaoyang Wu , Xin Ye , Yurong Ren , Peng Wei . Research progress of high-entropy cathode materials for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(4): 109851-. doi: 10.1016/j.cclet.2024.109851
13. [13]
  Zhuoer Cai , Yinan Zhang , Xiu-Ni Hua , Baiwang Sun . Phase transition arising from order-disorder motion in stable layered two-dimensional perovskite. Chinese Journal of Structural Chemistry, 2024, 43(11): 100426-100426. doi: 10.1016/j.cjsc.2024.100426
14. [14]
  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257
15. [15]
  Mengjia Luo , Yi Qiu , Zhengyang Zhou . Exploring temperature-driven phase dynamics of phosphate: The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO4. Chinese Journal of Structural Chemistry, 2025, 44(1): 100446-100446. doi: 10.1016/j.cjsc.2024.100446
16. [16]
  Xiao-Tong Sun , Hao-Fei Ni , Yi Zhang , Da-Wei Fu . Hybrid perovskite shows temperature-dependent photoluminescence and dielectric response triggered by halogen substitution. Chinese Journal of Structural Chemistry, 2024, 43(6): 100212-100212. doi: 10.1016/j.cjsc.2023.100212
17. [17]
  Xuan Zhu , Lin Zhou , Xiao-Yun Huang , Yan-Ling Luo , Xin Deng , Xin Yan , Yan-Juan Wang , Yan Qin , Yuan-Yuan Tang . (Benzimidazolium)2GeI4: A layered two-dimensional perovskite with dielectric switching and broadband near-infrared photoluminescence. Chinese Journal of Structural Chemistry, 2024, 43(6): 100272-100272. doi: 10.1016/j.cjsc.2024.100272
18. [18]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
19. [19]
  Chuan Li , Yangyang Han , Yanan Zhai , Ke Li , Xingzhong Liu , Zhuan Zhang , Cai Jia , Yongsheng Che . Phomaketals A and B, pentacyclic meroterpenoids from a eupC overexpressed mutant strain of Phoma sp.. Chinese Chemical Letters, 2024, 35(7): 109019-. doi: 10.1016/j.cclet.2023.109019
20. [20]
  Mengchen Liu , Yufei Zhang , Yi Xiao , Yang Wei , Meichen Bi , Huaide Jiang , Yan Yu , Shenghong Zhong . High stretchability and toughness of liquid metal reinforced conductive biocompatible hydrogels for flexible strain sensors. Chinese Journal of Structural Chemistry, 2025, 44(3): 100518-100518. doi: 10.1016/j.cjsc.2025.100518

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(444)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ferroelastic phase transitions in three new layered perovskites: (3-XC6H5CH2CH2NH3)2[CdCl4] (X = F, Cl, and Br)

Metrics

通讯作者: 陈斌, bchen63@163.com

Ferroelastic phase transitions in three new layered perovskites: (3-XC₆H₅CH₂CH₂NH₃)₂[CdCl₄] (X = F, Cl, and Br)