Citation: Guangliang Zhang, Riran Zang, Man Mo, Zhijie Fang, Yangxian Huang, Kunsong Hu, Jiali Huang, Xinxiang Liu, Lingyun Huang, Guohui Kang, Weijian Li, Haiqing Zhan, Xianquan Ming, Guanhan Huang, Guiliang Li, Feng Zhan. 3D anchoring structured for LiFe_0.5Mn_0.5PO₄@cornstalk-C cathode materials[J]. Chinese Chemical Letters, ;2023, 34(8): 108164. doi: 10.1016/j.cclet.2023.108164 shu

3D anchoring structured for LiFe_0.5Mn_0.5PO₄@cornstalk-C cathode materials

a.
School of Resources Environment and Materials, Guangxi University, Nanning 530004, China
b.
School of Electronics Engineering, Guangxi University of Science and Technology, Liuzhou 545006, China
c.
State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China
d.
Guangxi Higher Education Key Laboratory of High Performance Structural Materials and Heat Treatment & Surface Processing, Guangxi University, Nanning 53004, China
e.
South Manganese Group Limited, Nanning 530029, China

phy_idea@outlook.com

Received Date: 16 December 2022
Revised Date: 10 January 2023
Accepted Date: 26 January 2023
Available Online: 28 January 2023

Figures(4)

The organic carbon source coating LiFe_xMn_1-xPO₄ suffers from the problem of non-uniform carbon cladding. Too thick carbon cladding layer instead hinders the de-embedding of lithium ions. In this paper, we choose cornstalk as the carbon source, then LiFe_0.5Mn_0.5PO₄@cornstalk-C (LFMP@C-C) with 3D anchoring structure is prepared by the solvothermal method. The results show that the LFMP with cornstalk as the carbon source has better performance compared to the sucrose-coated LFMP material (LFMP@C). The discharge capacity of LFMP@C-C is 116 mAh/g for the first cycle at 1 C and the capacity retention rate is 94.0% after 500 cycles, and the discharge capacity of LFMP@C-C is more than 17.17% higher than that of LFMP@C.
- LiFe_0.5Mn_0.5PO₄,
- Cornstalk,
- Solvothermal method,
- 3D anchoring structure,
- Cathode materials
1. [1]
  F. Jiang, K. Qu, M. Wang, et al., Sustain. Energy Fuels 4 (2020) 2741-2751. doi: 10.1039/D0SE00312C
2. [2]
  Y. Liu, Y.J. Gu, J.L. Deng, et al., J. Mater. Sci. Mater. Electron. 31 (2020) 2887-2894. doi: 10.1007/s10854-019-02833-5
3. [3]
  J. Ding, Z. Su, H.L. Tian, Ceram. Int. 42 (2016) 12435-12440. doi: 10.1016/j.ceramint.2016.04.184
4. [4]
  H. Yu, Z. Yang, H. Zhu, H. Jiang, C. Li, Chin. J. Chem. Eng. 28 (2020) 1935-1940. doi: 10.1016/j.cjche.2020.01.008
5. [5]
  J.L. Liu, W.J. Liao, A.S. Yu, J. Alloys Compd. 587 (2014) 133-137. doi: 10.1016/j.jallcom.2013.10.154
6. [6]
  Q. Deng, X. Liu, Z. Li, et al., J. Colloid Interface Sci. 633 (2023) 480-488. doi: 10.1016/j.jcis.2022.11.083
7. [7]
  X. Li, H. Liang, B. Qin, et al., J. Colloid Interface Sci. 625 (2022) 41-49. doi: 10.1016/j.jcis.2022.05.155
8. [8]
  G.N. Zhu, C.X. Wang, Y.Y. Xia, J. Electrochem. Soc. 158 (2011) A102-A109. doi: 10.1149/1.3519070
9. [9]
  H.Q. Zhao, Y. Cheng, W. Liu, et al., Nano Micro Lett. 11 (2019) 24. doi: 10.1007/s40820-019-0255-3
10. [10]
  J.C. Arrebola, A. Caballero, L. Hernan, et al., J. Electrochem. Soc. 157 (2010) A791-A797. doi: 10.1149/1.3425728
11. [11]
  J. Wang, P. Nie, B. Ding, et al., J Mater. Chem. A 5 (2017) 2411-2428. doi: 10.1039/C6TA08742F
12. [12]
  J. Liu, H. Yuan, X.Y. Tao, et al., EcoMat 2 (2020) e12019. doi: 10.1002/eom2.12019
13. [13]
  P. Liu, Y. Wang, J. Liu, J. Energy Chem. 34 (2019) 171-185. doi: 10.1016/j.jechem.2018.10.005
14. [14]
  Q. Deng, M. Wang, X. Liu, et al., J. Colloid Interface Sci. 626 (2022) 700-709. doi: 10.1016/j.jcis.2022.06.073
15. [15]
  R.R. Zhao, B.Y. Lan, H.Y. Chen, G.Z. Ma, Ionics 18 (2012) 873-879. doi: 10.1007/s11581-012-0700-5
16. [16]
  D. Choi, J. Xiao, Y.J. Choi, et al., Energy Environ. Sci. 4 (2011) 4560-4566. doi: 10.1039/c1ee01501j
17. [17]
  G.R. Du, X.Y. Guo, W.C. Yang, et al., J. Nanoparticle Res. 17 (2015) 272. doi: 10.1007/s11051-015-3077-3
18. [18]
  Z.W. Deng, Q. Wang, D.C. Peng, H.B. Liu, Y.X. Chen, J. Alloys Compd. 794 (2019) 178-185. doi: 10.1016/j.jallcom.2019.04.184
19. [19]
  Z.X. Chi, W. Zhang, X.S. Wang, et al., J Mater. Chem. A 2 (2014) 17359-17365. doi: 10.1039/C4TA03739A
20. [20]
  Y. Yang, X. Chen, Y. Gu, et al., Mater. Lett. 299 (2021) 130053. doi: 10.1016/j.matlet.2021.130053
21. [21]
  N.V. Kosova, O.A. Podgornova, A.K. Gutakovskii, J. Alloys Compd. 742 (2018) 454-465. doi: 10.1016/j.jallcom.2018.01.242
1. [1]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
2. [2]
  Fan Wu , Shaoyang Wu , Xin Ye , Yurong Ren , Peng Wei . Research progress of high-entropy cathode materials for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(4): 109851-. doi: 10.1016/j.cclet.2024.109851
3. [3]
  Yajun Hou , Chuanzheng Zhu , Qiang Wang , Xiaomeng Zhao , Kun Luo , Zongshuai Gong , Zhihao Yuan . ~2.5 nm pores in carbon-based cathode promise better zinc-iodine batteries. Chinese Chemical Letters, 2024, 35(5): 108697-. doi: 10.1016/j.cclet.2023.108697
4. [4]
  Xiaoxing Ji , Xiaojuan Li , Chenggang Wang , Gang Zhao , Hongxia Bu , Xijin Xu . Ni_xB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery. Chinese Chemical Letters, 2024, 35(10): 109388-. doi: 10.1016/j.cclet.2023.109388
5. [5]
  Yongjian Li , Xinyu Zhu , Chenxi Wei , Youyou Fang , Xinyu Wang , Yizhi Zhai , Wenlong Kang , Lai Chen , Duanyun Cao , Meng Wang , Yun Lu , Qing Huang , Yuefeng Su , Hong Yuan , Ning Li , Feng Wu . Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries. Chinese Chemical Letters, 2024, 35(12): 109536-. doi: 10.1016/j.cclet.2024.109536
6. [6]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
7. [7]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
8. [8]
  Gregorio F. Ortiz . Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery. Chinese Chemical Letters, 2024, 35(10): 109391-. doi: 10.1016/j.cclet.2023.109391
9. [9]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
10. [10]
  Hengyi ZHU , Liyun JU , Haoyue ZHANG , Jiaxin DU , Yutong XIE , Li SONG , Yachao JIN , Mingdao ZHANG . Efficient regeneration of waste LiNi_0.5Co_0.2Mn_0.3O₂ cathode toward high-performance Li-ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 625-638. doi: 10.11862/CJIC.20240358
11. [11]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
12. [12]
  Yuhan Wu , Qing Zhao , Zhijie Wang . Layered vanadium oxides: Promising cathode materials for calcium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(5): 100271-100271. doi: 10.1016/j.cjsc.2024.100271
13. [13]
  Runjing Xu , Xin Gao , Ya Chen , Xiaodong Chen , Lifeng Cui . Research status and prospect of rechargeable magnesium ion batteries cathode materials. Chinese Chemical Letters, 2024, 35(11): 109852-. doi: 10.1016/j.cclet.2024.109852
14. [14]
  Shunshun Jiang , Ji Zhang , Jing Wang , Shan-Tao Zhang . Excellent energy storage properties in non-stoichiometric Bi_0.5Na_0.5TiO₃-based relaxor ferroelectric ceramics. Chinese Chemical Letters, 2024, 35(7): 108955-. doi: 10.1016/j.cclet.2023.108955
15. [15]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
16. [16]
  Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167
17. [17]
  Lingjiang Kou , Yong Wang , Jiajia Song , Taotao Ai , Wenhu Li , Mohammad Yeganeh Ghotbi , Panya Wattanapaphawong , Koji Kajiyoshi . Mini review: Strategies for enhancing stability of high-voltage cathode materials in aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 110368-. doi: 10.1016/j.cclet.2024.110368
18. [18]
  Na Li , Wenxue Wang , Peng Wang , Zhanying Sun , Xinlong Tian , Xiaodong Shi . Dual-defect engineering of catalytic cathode materials for advanced lithium-sulfur batteries. Chinese Chemical Letters, 2025, 36(3): 110731-. doi: 10.1016/j.cclet.2024.110731
19. [19]
  Yuexi Guo , Zhaoyang Li , Jingwei Dai . Charlie and the 3D Printing Chocolate Factory. University Chemistry, 2024, 39(9): 235-242. doi: 10.3866/PKU.DXHX202309067
20. [20]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(385)
HTML views(18)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

3D anchoring structured for LiFe0.5Mn0.5PO4@cornstalk-C cathode materials

Metrics

通讯作者: 陈斌, bchen63@163.com

3D anchoring structured for LiFe_0.5Mn_0.5PO₄@cornstalk-C cathode materials