Citation: Qiao Zhang, Yuhang Yin, Jingfu Song, Gai Zhao, Shengyi Dong. Effect of spatial configuration on adhesion of 1,2-disubstituted cyclohexane derivatives[J]. Chinese Chemical Letters, ;2023, 34(8): 108126. doi: 10.1016/j.cclet.2022.108126 shu

Effect of spatial configuration on adhesion of 1,2-disubstituted cyclohexane derivatives

Qiao Zhang ^a ,
Yuhang Yin ^b ,
Jingfu Song ^b ,
Gai Zhao ^{b, *,} ,
Shengyi Dong ^{a, *,}

a.
College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
b.
State Key Laboratory of Mechanics and Control of Mechanical Structures, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

zhaogai@nuaa.edu.cn

dongsy@hnu.edu.cn

Received Date: 6 October 2022
Revised Date: 25 December 2022
Accepted Date: 27 December 2022
Available Online: 30 December 2022

Figures(4)

Spatial configuration has a significant effect on chemical self-assembly. However, the importance of spatial configuration in supramolecular adhesive materials has been frequently ignored. In this study, the effects of the spatial configuration on cohesion and adhesion were investigated. Owing to the diversities of the chemical structures and assembly patterns, 1,2-disubstituted cyclohexane derivatives were used in this combined experimental and theoretical investigation. The self-sorting assembly of enantiopure isomers improved cohesion but had a negative effect on adhesion. In contrast, racemic mixtures displayed stronger adhesion effects. Moreover, it was proven that the cis-configuration was more favorable for supramolecular adhesion than the trans-counterpart. In addition, the influence of the spatial configuration of 1,2-disubstituted cyclohexane derivatives could be effectively mitigated by hydrogen bond donors or acceptors. The addition of natural acids yielded three-dimensional polymeric networks, in which the spatial configuration was not the decisive factor for supramolecular adhesion.
- Spatial configuration,
- Supramolecular adhesive material,
- Assembly,
- Cohesion,
- Adhesion
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