Citation: Chongxing Li, Renbo Liu, Shuxian Zhang, Qingyu Li, Cong Wang, Zhiwei Zhang, Chengxiang Wang, Longwei Yin, Rutao Wang. Advanced all-solid-state lithium-selenium batteries enabled by selenium-nitrogen doped hierarchic meso-microporous carbon nanospheres composite cathode[J]. Chinese Chemical Letters, ;2023, 34(9): 108083. doi: 10.1016/j.cclet.2022.108083 shu

Advanced all-solid-state lithium-selenium batteries enabled by selenium-nitrogen doped hierarchic meso-microporous carbon nanospheres composite cathode

Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, School of Materials Science and Engineering, Shandong University, Ji'nan 250061, China

zhangzhiwei@sdu.edu.cn

rtwang@sdu.edu.cn

Received Date: 25 July 2022
Revised Date: 28 November 2022
Accepted Date: 16 December 2022
Available Online: 21 December 2022

Figures(4)

Selenium, an element belonging to the same group in the periodic table as sulfur, has a high electronic conductivity (1 × 10⁻⁵ S/cm) and a high volumetric energy density (3253 mAh/cm³), which is a prospective cathode material for high-energy all-solid-state rechargeable batteries. However, its wide use is hindered by large volume expansion and low utilization rate. In this work, Se-infused nitrogen-doped hierarchical meso-microporous carbon composites (Se/NHPC) are prepared by a melt-diffusion process. Amorphous Se is uniformly dispersed in meso-micropores of NHPC with a high mass loading of 81%. All-solid-state Li-Se batteries fabricated by using Se/NHPC as the cathode, a Li-In alloy as the anode, and Li₆PS₅Cl as the solid-state electrolyte, deliver a highly reversible capacity of 621 mAh/g (92% of theoretical capacity), a good rate capability and a high capacity retention value of 80.9% after 100 cycles. It is found that the capacity decay of Se cathode is mainly related to the interfacial degradation and the separation of Se from the carbon substrate, as suggested by the continuous increase of interfacial resistance and the structural transformation from amorphous Se_n chains to Se₈ rings initial discharge/charge cycle and then to the trigonally crystalline Se chains structure after the long-term cycles.
- L-Se battery,
- Solid-state electrolyte,
- Carbon nanospheres,
- Li₆PS₅Cl,
- Composite
1. [1]
  X. Han, S. Wang, Y. Xu, et al., Energy Environ. Sci. 14 (2021) 5044-5056. doi: 10.1039/d1ee01494c
2. [2]
  X. Han, W. Zhou, M. Chen, et al., J. Energy Chem. 67 (2022) 727-735. doi: 10.1016/j.jechem.2021.11.021
3. [3]
  X. Han, W. Zhou, M. Chen, et al., Nano Res. 15 (2022) 6156-6167. doi: 10.1007/s12274-022-4242-5
4. [4]
  C. Zhao, G.L. Xu, Z. Yu, et al., Nat. Nanotech. 16 (2021) 166-173. doi: 10.1038/s41565-020-00797-w
5. [5]
  X. Zhao, L. Yin, T. Zhang, et al., Nano Energy 49 (2018) 137-146. doi: 10.1016/j.nanoen.2018.04.045
6. [6]
  F. Zhang, X. Guo, P. Xiong, et al., Adv. Energy Mater. 10 (2020) 2000446. doi: 10.1002/aenm.202000446
7. [7]
  J. He, W. Lv, Y. Chen, et al., J. Power Sources 363 (2017) 103-109. doi: 10.1016/j.jpowsour.2017.07.065
8. [8]
  A. Abouimrane, D. Dambournet, K.W. Chapman, et al., J. Am. Chem. Soc. 134 (2012) 4505-4508. doi: 10.1021/ja211766q
9. [9]
  J. Sun, Z. Du, Y. Liu, et al., Adv. Mater. 33 (2021) e2003845. doi: 10.1002/adma.202003845
10. [10]
  Y. Zhou, Z. Li, Y.C. Lu, Nano Energy 39 (2017) 554-561. doi: 10.1016/j.nanoen.2017.07.038
11. [11]
  X. Li, X. Li, J. Liang, et al., Energy Environ. Sci. 11 (2018) 2828-2832. doi: 10.1039/c8ee01621f
12. [12]
  Q. Zhang, L. Cai, G. Liu, et al., ACS Appl. Mater. Interfaces 12 (2020) 16541-16547. doi: 10.1021/acsami.0c01996
13. [13]
  X. Gao, X. Yang, S. Wang, et al., J. Mater. Chem. A 8 (2020) 278-286. doi: 10.1039/c9ta10623e
14. [14]
  Q. Feng, S. Zhao, Q. Xu, et al., Adv. Mater. 31 (2019) 1901024. doi: 10.1002/adma.201901024
15. [15]
  T. Li, J. Zhang, C. Li, et al., Sci. China Mater. 65 (2022) 2363-2372. doi: 10.1007/s40843-021-2047-x
16. [16]
  C. Luo, Y. Xu, Y. Zhu, et al., ACS Nano 7 (2013) 8003-8010. doi: 10.1021/nn403108w
17. [17]
  R. Lukács, M. Veres, K. Shimakawa, S. Kugler, J. Appl. Phy. 107 (2010) 073517. doi: 10.1063/1.3371813
18. [18]
  S. Huang, Z. Li, B. Wang, et al., Adv. Funct. Mater. 28 (2018) 1706294. doi: 10.1002/adfm.201706294
19. [19]
  Z. Li, L. Yuan, Z. Yi, Y. Liu, Y. Huang, Nano Energy 9 (2014) 229-236. doi: 10.1016/j.nanoen.2014.07.012
20. [20]
  T.K. Schwietert, V.A. Arszelewska, C. Wang, et al., Nat. Mater. 19 (2020) 428-435. doi: 10.1038/s41563-019-0576-0
21. [21]
  C. Yu, S. Ganapathy, E.R.H. Van Eck, et al., J. Mater. Chem. A 5 (2017) 21178-21188. doi: 10.1039/C7TA05031C
22. [22]
  C. Yu, S. Ganapathy, E.R.H.V. Eck, H. Wang, et al., Nat. Commun. 8 (2017) 1086. doi: 10.1038/s41467-017-01187-y
23. [23]
  T.T. Zuo, R. Rueß, R. Pan, et al., Nat. Commun. 12 (2021) 6669. doi: 10.1038/s41467-021-26895-4
24. [24]
  R. Prasada Rao, S. Adams, J. Mater. Sci. 51 (2016) 5556-5564. doi: 10.1007/s10853-016-9860-4
25. [25]
  H.T. Bui, H. Jang, D. Ahn, et al., Electrochim. Acta 368 (2021) 137556. doi: 10.1016/j.electacta.2020.137556
26. [26]
  B.R. Shin, Y.J. Nam, D.Y. Oh, et al., Electrochim. Acta 146 (2014) 395-402. doi: 10.1016/j.electacta.2014.08.139
27. [27]
  Y.G. Lee, S. Fujiki, C. Jung, et al., Nat. Energy 5 (2020) 299-308. doi: 10.1038/s41560-020-0575-z
28. [28]
  B. Guo, Z. Wang, J. Chen, et al., ACS Nano 16 (2022) 16, 17414-17423. doi: 10.1021/acsnano.2c08558
29. [29]
  Y. Dong, P. Lu, Y. Ding, et al., SusMat 1 (2021) 393-412. doi: 10.1002/sus2.26
30. [30]
  C. Lu, A. Li, G. Li, et al., Adv. Mater. 33 (2021) 1-13.
31. [31]
  C.P. Yang, S. Xin, Y.X. Yin, et al., Angew. Chem. Int. Ed. 52 (2013) 8363-8367. doi: 10.1002/anie.201303147
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9. [9]
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10. [10]
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11. [11]
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12. [12]
  Dong Sui , Jiayi Liu . Constriction-susceptible lithium support for fast cycling of solid-state lithium metal battery. Chinese Chemical Letters, 2025, 36(2): 110417-. doi: 10.1016/j.cclet.2024.110417
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