Citation: Zhenjin Liang, Yuhao Peng, Xing Zhang, Kewei Cao, Wei Xiao, Dong Gu. Sulfur-doped CMK-5 with expanded lattice for high-performance lithium ion batteries[J]. Chinese Chemical Letters, ;2023, 34(7): 108054. doi: 10.1016/j.cclet.2022.108054 shu

Sulfur-doped CMK-5 with expanded lattice for high-performance lithium ion batteries

Zhenjin Liang ^{a, 1} ,
Yuhao Peng ^{a, 1} ,
Xing Zhang ^a ,
Kewei Cao ^a ,
Wei Xiao ^b ,
Dong Gu ^{a, *,}

a.
The Institute for Advanced Studies, Wuhan University, Wuhan 430072, China
b.
College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources, Wuhan University, Wuhan 430072, China

dgu@whu.edu.cn

Received Date: 29 November 2022
Accepted Date: 9 December 2022
Available Online: 11 December 2022

Figures(3)

Heteroatom-doped porous carbon materials are very attractive for lithium ion batteries (LIBs) owing to their high specific surface areas, open pore structures, and abundant active sites. However, heteroatom-doped porous carbon with very high surface area and large pore volume are highly desirable but still remain a big challenge. Herein, we reported a sulfur-doped mesoporous carbon (CMK-5-S) with nanotubes array structure, ultrahigh specific surface area (1390 m²/g), large pore volume (1.8 cm³/g), bimodal pore size distribution (2.9 and 4.6 nm), and high sulfur content (2.5 at%). The CMK-5-S used as an anode material for LIBs displays high specific capacity, excellent rate capability and highly cycling stability. The initial reversible specific capacity at 0.1 A/g is as high as 1580 mAh/g and simultaneously up to 701 mAh/g at 1 A/g even after 500 cycles. Further analysis reveals that the excellent electrochemical storage performances is attributed to its unique structures as well as the expanded lattice by sulfur-doping.
- Mesoporous material,
- CMK-5,
- Hollow structure,
- Sulfur-doping,
- Lithium ion batteries
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