Citation: Jurong Dong, Yufei Wang, Yu-Lin Lu, Li Zhang. Ultrathin two-dimensional porphyrinic metal-organic framework nanosheets induced by the axial aryl substituent[J]. Chinese Chemical Letters, ;2023, 34(7): 108052. doi: 10.1016/j.cclet.2022.108052 shu

Ultrathin two-dimensional porphyrinic metal-organic framework nanosheets induced by the axial aryl substituent

MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China

zhli99@mail.sysu.edu.cn

Received Date: 19 August 2022
Revised Date: 6 December 2022
Accepted Date: 6 December 2022
Available Online: 8 December 2022

Figures(6)

Ultrathin two-dimensional metal-organic framework nanosheets have emerged as a promising kind of heterogeneous catalysts. Herein, we report a new kind of 2D porphyrinic metal-organic framework nanosheets of Rh2-PCN-222, which was prepared from the self-assembly of the metalloporphyrin ligand Rh(TCPP)(DCB) (TCPP = 5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrin; DCB = 3,4-dichlorobenzene) and ZrCl₄ in the presence of two kinds of monocarboxylic acids as the modulating reagent. The thickness of Rh2-PCN-222 nanosheets was characterized by atomic force microscopy (AFM) and determined to be 5.4-9.6 nm. It was found that the axial aryl dichlorophenyl substituent, which controlled the anisotropic growth of MOFs, was essential for the formation of nanosheets. Catalytic results showed that Rh2-PCN-222 nanosheets were efficient for CO₂ transformation.
- Metalloporphyrin,
- Axial aryl substituent,
- 2D MOF nanosheets,
- CO₂ transformation,
- Heterogeneous catalysis
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