Citation: Chang-Feng Wang, Na Wang, Lang Liu, Le-Ping Miao, Heng-Yun Ye, Yi Zhang, Chao Shi. Enantiomeric hybrid high-temperature multiaxial ferroelectrics with a narrow bandgap and high piezoelectricity[J]. Chinese Chemical Letters, ;2023, 34(8): 108051. doi: 10.1016/j.cclet.2022.108051 shu

Enantiomeric hybrid high-temperature multiaxial ferroelectrics with a narrow bandgap and high piezoelectricity

Chaotic Matter Science Research Center, Department of Materials, Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China

amn716@163.com

shic@jxust.edu.cn

Received Date: 27 August 2022
Revised Date: 10 November 2022
Accepted Date: 6 December 2022
Available Online: 8 December 2022

Figures(4)

Ferroelectric semiconductors have sparked growing attention in the field of optoelectronics, due to their unique ferroelectric photovoltaic effect. Recently, substantial efforts have been devoted to the development of ferroelectric semiconductors, including inorganic oxides, organic-inorganic hybrids, and metal-free perovskites. Nevertheless, reports of ferroelectric semiconductors with a bandgap of less than 2 eV have been scarce. Here, in combination with the incorporation of triiodide (I₃⁻) and the introduction of chiral cations, we successfully constructed a pair of enantiomeric organic-inorganic hybrid ferroelectric semiconductors, (S-1,2-DAP·I)₄·I₃·BiI₆ and (R-1,2-DAP·I)₄·I₃·BiI₆ (R/S-1,2-DAP = (R/S)-(–)-1,2-diaminopropane), which possess high-temperature multiaxial ferroelectric phase transition with an Aizu notation of 422F2(s) at 405 K, a narrow bandgap of 1.56 eV comparable to that of CH₃NH₃PbI₃ (~1.5 eV), and an impressive piezoelectric response (piezoelectric coefficient, d₂₂ of 35 pC/N) on par with PVDF (polyvinylidene fluoride, 30 pC/N). With intriguing attributes, (S-1,2-DAP·I)₄·I₃·BiI₆ and (R-1,2-DAP·I)₄·I₃·BiI₆ exhibit great potential for application of self-power polarized-light detection and piezoelectric sensors.
- Chirality,
- Hybrid materials,
- Multiaxial ferroelectrics,
- Semiconductors,
- Piezoelectricity
1. [1]
  Y.Y. Tang, P.F. Li, W.Q. Liao, et al., J. Am. Chem. Soc. 140 (2018) 8051–8059. doi: 10.1021/jacs.8b04600
2. [2]
  Z. Wu, W. Zhang, H. Ye, et al., J. Am. Chem. Soc. 143 (2021) 7593–7598. doi: 10.1021/jacs.1c00459
3. [3]
  I. Grinberg, D.V. West, M. Torres, et al., Nature 503 (2013) 509–512. doi: 10.1038/nature12622
4. [4]
  S. Han, M. Li, Y. Liu, et al., Nat. Commun, 12 (2021) 284. doi: 10.1038/s41467-020-20530-4
5. [5]
  X. Li, J.M. Hoffman, M.G. Kanatzidis, Chem. Rev. 121 (2021) 2230–2291. doi: 10.1021/acs.chemrev.0c01006
6. [6]
  S. Liu, L. He, Y. Wang, et al., Chin. Chem. Lett. 33 (2022) 1032–1036. doi: 10.1016/j.cclet.2021.07.039
7. [7]
  Q. Jia, T. Shao, L. Tong, et al., Chin. Chem. Lett. 34 (2023) 107539. doi: 10.1016/j.cclet.2022.05.053
8. [8]
  C. Su, Z. Zhang, J. Yao, et al., Chin. Chem. Lett. 34 (2023) 107442. doi: 10.1016/j.cclet.2022.04.040
9. [9]
  C.F. Wang, H. Li, Q. Ji, et al., Adv. Funct. Mater. 32 (2022) 2205918. doi: 10.1002/adfm.202205918
10. [10]
  L. Mao, C.C. Stoumpos, M.G. Kanatzidis, J. Am. Chem. Soc. 141 (2018) 1171–1190. doi: 10.1007/s40195-018-0755-z
11. [11]
  C. Ji, D. Dey, Y. Peng, et al., Angew. Chem. Int. Ed. 59 (2020) 18933–18937. doi: 10.1002/anie.202005092
12. [12]
  L. Li, X. Liu, C. He, et al., J. Am. Chem. Soc. 142 (2020) 1159–1163. doi: 10.1021/jacs.9b11341
13. [13]
  W. Zhang, M. Hong, J. Luo, J. Am. Chem. Soc. 143 (2021) 16758–16767. doi: 10.1021/jacs.1c08281
14. [14]
  H.Y. Zhang, Z.X. Zhang, X.G. Chen, et al., J. Am. Chem. Soc. 143 (2021) 1664–1672. doi: 10.1021/jacs.0c12907
15. [15]
  Y.L. Zeng, X.Q. Huang, C.R. Huang, et al., Angew. Chem. Int. Ed. 60 (2021) 10730–10735. doi: 10.1002/anie.202102195
16. [16]
  G. Liu, L. Kong, J. Gong, et al., Adv. Funct. Mater. 27 (2016) 1604208.
17. [17]
  Y.Y. Chen, C.H. Gao, T. Yang, et al., Chin. J. Struct. Chem. 41 (2022) 2204001–22040011.
18. [18]
  H.Y. Ye, W.Q. Liao, C.L. Hu, et al., Adv. Mater. 28 (2016) 2579–2586. doi: 10.1002/adma.201505224
19. [19]
  L. Li, X. Liu, Y. Li, et al., J. Am. Chem. Soc. 141 (2019) 2623–2629. doi: 10.1021/jacs.8b12948
20. [20]
  L. Li, Z. Sun, P. Wang, et al., Angew. Chem. Int. Ed. 56 (2017) 12150–12154. doi: 10.1002/anie.201705836
21. [21]
  A. Starkholm, L. Kloo, P.H. Svensson, ACS Appl. Energy Mater. 2 (2018) 477–485.
22. [22]
  B. Kou, W. Zhang, C. Ji, et al., Chem. Commun. 55 (2019) 14174–14177. doi: 10.1039/c9cc05365d
23. [23]
  W. Zhang, B. Kou, Y. Peng, et al., J. Mater. Chem. C 6 (2018) 12170–12174. doi: 10.1039/c8tc04372h
24. [24]
  W. Zhang, X. Liu, L. Li, et al., Chem. Mater. 30 (2018) 4081–4088. doi: 10.1021/acs.chemmater.8b01200
25. [25]
  W.S. Yang, B.W. Park, E.H. Jung, et al., Science 356 (2017) 1376–1379. doi: 10.1126/science.aan2301
26. [26]
  H.Y. Zhang, Y.Y. Tang, P.P. Shi, et al., Acc. Chem. Res. 52 (2019) 1928–1938. doi: 10.1021/acs.accounts.8b00677
27. [27]
  V. Mujica, Nat. Chem. 7 (2015) 543–544. doi: 10.1038/nchem.2294
28. [28]
  G. Long, R. Sabatini, M.I. Saidaminov, et al., Nat. Rev. Mater. 5 (2020) 423–439. doi: 10.1038/s41578-020-0181-5
29. [29]
  C.F. Wang, C. Shi, A. Zheng, et al., Mater. Horiz. 9 (2022) 2450–2459. doi: 10.1039/d2mh00698g
30. [30]
  C. Shi, J.J. Ma, J.Y. Jiang, et al., J. Am. Chem. Soc. 142 (2020) 9634–9641.
31. [31]
  K. Aizu, Phys. Rev. 146 (1966) 423–429. doi: 10.1103/PhysRev.146.423
32. [32]
  D.A. Kleinman, Phys. Rev. 126 (1962) 1977–1979. doi: 10.1103/PhysRev.126.1977
33. [33]
  Y. Xue, Z. Zhang, P. Shi, et al., Chin. Chem. Lett. 32 (2021) 539–542. doi: 10.1016/j.cclet.2020.02.005
34. [34]
  W.P. Zhao, C. Shi, A. Stroppa, et al., Inorg. Chem. 55 (2016) 10337–10342. doi: 10.1021/acs.inorgchem.6b01545
35. [35]
  M.E. Kamminga, A. Stroppa, S. Picozzi, et al., Inorg. Chem. 56 (2017) 33–41. doi: 10.1021/acs.inorgchem.6b01699
36. [36]
  Y.M. You, W.Q. Liao, D. Zhao, et al., Science 357 (2017) 306–309. doi: 10.1126/science.aai8535
37. [37]
  T.T. Sha, Y.A. Xiong, Q. Pan, et al., Adv. Mater. 31 (2019) 1901843. doi: 10.1002/adma.201901843
38. [38]
  H.Y. Zhang, X.J. Song, X.G. Chen, et al., J. Am. Chem. Soc. 142 (2020) 4925–4931. doi: 10.1021/jacs.0c00371
39. [39]
  I.H. Park, Q. Zhang, K.C. Kwon, et al., J. Am. Chem. Soc. 141 (2019) 15972–15976. doi: 10.1021/jacs.9b07776
40. [40]
  Y.Y. Tang, Y. Ai, W.Q. Liao, et al., Adv. Mater. 31 (2019) 1902163. doi: 10.1002/adma.201902163
41. [41]
  M. Li, Y. Xu, S. Han, et al., Adv. Mater. 32 (2020) 2002972. doi: 10.1002/adma.202002972
42. [42]
  Z. Wu, C. Ji, L. Li, et al., Angew. Chem. Int. Ed. 57 (2018) 8140–8143. doi: 10.1002/anie.201803716
43. [43]
  C. Ji, S. Wang, L. Li, et al., Adv. Funct. Mater. 29 (2019) 1805038. doi: 10.1002/adfm.201805038
44. [44]
  H. Lu, T. Li, S. Poddar, et al., Adv. Mater. 27 (2015) 7832–7838. doi: 10.1002/adma.201504019
45. [45]
  X.G. Chen, X.J. Song, Z.X. Zhang, et al., J. Am. Chem. Soc. 142 (2020) 10212–10218. doi: 10.1021/jacs.0c03710
46. [46]
  H.Y. Ye, Y.Y. Tang, P.F. Li, et al., Science 361 (2018) 151–155. doi: 10.1126/science.aas9330
47. [47]
  Q. Pan, Y.A. Xiong, T.T. Sha, et al., Mater. Chem. Front. 5 (2021) 44–59. doi: 10.1039/d0qm00288g
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