Citation: Yixun Gu, Kuan Yang, Hongbin Yao, Weijian Li, Haiqing Zhan, Xianquan Ming, Guanhan Huang, Guiliang Li, Feng Zhan. Surface modification of Li₃InCl₆ provides superior electrochemical performance for LiMn₂O₄ cathode materials[J]. Chinese Chemical Letters, ;2023, 34(5): 108047. doi: 10.1016/j.cclet.2022.108047 shu

Surface modification of Li₃InCl₆ provides superior electrochemical performance for LiMn₂O₄ cathode materials

Yixun Gu ^a ,
Kuan Yang ^a ,
Hongbin Yao ^a ,
Weijian Li ^b ,
Haiqing Zhan ^b ,
Xianquan Ming ^b ,
Guanhan Huang ^b ,
Guiliang Li ^b ,
Feng Zhan ^{a, *,}

a.
School of Resources Environment and Materials, Guangxi University, Nanning 530004, China
b.
South Manganese Group Limited, Nanning 530000, China

phy_idea@outlook.com

Received Date: 25 September 2022
Revised Date: 22 October 2022
Accepted Date: 5 December 2022
Available Online: 7 December 2022

Figures(4)

LiMn₂O₄ (LMO) is the substance of choice for small and medium-sized energy storage materials in daily life. In this work, Li₃InCl₆ (LIC) is prepared on the surface of LiMn₂O₄ by hydrothermal method using InCl₃ and LiCl as raw materials. This method stabilizes the LMO crystal structure by uniformly coating the LIC on the LMO surface and effectively maintains the morphology of LMO crystals during the cycling process. SEM and EDS analysis confirm the morphology and homogeneity of the synthesized material LIC on the LMO surface. The prepared material is put into a battery, and the charge-discharge test is carried out at 0.5 C and 1 C. The results show that the LIC surface-modified samples exhibit more than 6% higher cycling performance than the unmodified samples after long cycling.
- Li-ion batteries,
- Cathode material,
- LiMn₂O₄,
- Li₃InCl₆,
- Surface modification
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Surface modification of Li₃InCl₆ provides superior electrochemical performance for LiMn₂O₄ cathode materials