Citation: Hua Guo, Wenyu Hu, Zekun Zhang, Duowen Yang, Siyuan Guo, Xiaosheng Jing, Hao Xu, Wei Yan. Quick fabrication of evenly porous PbO₂ through potential linear increase electrodeposition[J]. Chinese Chemical Letters, ;2023, 34(7): 108030. doi: 10.1016/j.cclet.2022.108030 shu

Quick fabrication of evenly porous PbO₂ through potential linear increase electrodeposition

Hua Guo ^{a, b} ,
Wenyu Hu ^a ,
Zekun Zhang ^a ,
Duowen Yang ^a ,
Siyuan Guo ^a ,
Xiaosheng Jing ^a ,
Hao Xu ^{a, b, *,} ,
Wei Yan ^{a, b}

a.
Department of Environmental Science and Engineering, Xi'an Jiaotong University, Xi'an 710049, China
b.
Research Institute of Xi'an Jiaotong University, Hangzhou 311200, China

xuhao@xjtu.edu.cn

Received Date: 8 September 2022
Revised Date: 14 November 2022
Accepted Date: 28 November 2022
Available Online: 30 November 2022

Figures(3)

Anodic oxidation electrodeposition is the primary way to prepare lead dioxide anode. The regulation of the external circuit for the reaction is a unique advantage of electrocatalytic reaction, which can regulate crystallization and accelerate the reaction process. In this study, lead dioxide coatings with uniform pore size distribution were quickly prepared on three different substrates by potential linear increase electrodeposition (PLIED). Morphology and structure analysis shows that the prepared electrodes have uniform porous morphology, and Ti/SnO₂/PLIED has the smallest grain size. Three electrodes all display well degradation performance to azophloxine and diclofenac sodium. Ti/PLIED, and Ti/SnO₂/PLIED are appreciated for degrading organics with a simple structure in low concentrations. At the same time, Ti/SnO₂/PLIED is more suitable for complex organics in high concentrations. Electrochemical activity tests indicate the different mechanisms of the PLIED electrodes that build the other degradation performance. Three PLIED electrodes show excellent electrical and electrochemical stability during the cycle degradation process. The results provide a reference for the subsequent anodic oxidation electrodeposition research and the regulating effect of the external circuit on coating properties.
- Lead dioxide,
- Bubble template,
- Porous electrode,
- Adsorption electrochemical porosity
1. [1]
  Q. Zhou, X. Zhou, R. Zheng, Z. Liu, J. Wang, Sci. Total Environ. 806 (2022) 150088. doi: 10.1016/j.scitotenv.2021.150088
2. [2]
  B.H. Yu, R.D. Xu, X.B. Wang, W.B. Wang, S.Y. Feng, Renew. Energy 159 (2020) 885–892. doi: 10.1016/j.renene.2020.03.159
3. [3]
  X. Fu, Y. Han, H. Xu, Z. Su, L. Liu, J. Hazard. Mater. 422 (2022) 126890. doi: 10.1016/j.jhazmat.2021.126890
4. [4]
  D. Shao, Z. Wang, C. Zhang, et al., Chin. Chem. Lett. 33 (2022) 1288–1292. doi: 10.1016/j.cclet.2021.07.061
5. [5]
  H. Guo, W. Hu, Z. Xu, et al., Process Saf. Environ. Prot. 164 (2022) 189–207. doi: 10.1016/j.psep.2022.06.012
6. [6]
  H. Guo, Z.C. Xu, D. Qiao, et al., Chemosphere 261 (10) (2020) 128157.
7. [7]
  M. Xu, Y.L. Mao, W.L. Song, et al., J. Electroanal. Chem. 823 (2018) 193–202. doi: 10.1016/j.jelechem.2018.06.007
8. [8]
  N. Comisso, S. Cattarin, P. Guerriero, et al., Electrochem. Commun. 60 (2015) 144–147. doi: 10.1016/j.elecom.2015.08.026
9. [9]
  Y.W. Yao, C.J. Huang, Y. Yang, M.Y. Li, B.L. Ren, Chem. Eng. J. 350 (2018) 960–970. doi: 10.1016/j.cej.2018.06.036
10. [10]
  X. Li, D. Pletcher, F.C. Walsh, Chem. Soc. Rev. 40 (2011) 3879–3894. doi: 10.1039/c0cs00213e
11. [11]
  H. Guo, Z. Xu, D. Qiao, et al., Water Environ. Res. 93 (2021) 42–50. doi: 10.1002/wer.1339
12. [12]
  Y.W. Yao, X. Chen, N.C. Yu, H.S. Dong, H.R. Wang, J. Electrochem. Soc. 164 (2017) E48–E52. doi: 10.1149/2.0711704jes
13. [13]
  Y. Zhou, Z. Li, C. Hao, et al., Electrochim. Acta 333 (2020) 135535. doi: 10.1016/j.electacta.2019.135535
14. [14]
  M. Yuan, N.M. Salman, H. Guo, et al., Catalysts 9 (2019) 875. doi: 10.3390/catal9110875
15. [15]
  J. Lei, Z. Xu, H. Xu, et al., J. Environ. Chem. Eng. 8 (2020) 103773. doi: 10.1016/j.jece.2020.103773
16. [16]
  Y. Ren, W. Zheng, X. Duan, N. Goswami, Y. Liu, Environ. Funct. Mater. 1 (2022) 10–20.
17. [17]
  H. Li, S. Sun, H. Ji, W. Liu, Z. Shen, Appl. Catal. B: Environ. 272 (2020) 118966. doi: 10.1016/j.apcatb.2020.118966
18. [18]
  Q. Liu, H. Li, H. Zhang, Z. Shen, H. Ji, Chin. Chem. Lett. 33 (2022) 4756–4760. doi: 10.1016/j.cclet.2021.12.089
19. [19]
  F. Han, X. Ye, Q. Chen, H. Long, Y. Rao, Sep. Purif. Technol. 232 (2020) 115967. doi: 10.1016/j.seppur.2019.115967
20. [20]
  H. Guo, Z. Xu, D. Wang, et al., Chemosphere 286 (2022) 131580. doi: 10.1016/j.chemosphere.2021.131580
21. [21]
  D. Guo, S. You, F. Li, Y. Liu, Chin. Chem. Lett. 33 (2022) 1–10. doi: 10.1016/j.cclet.2021.06.027
22. [22]
  H. Lin, J.F. Niu, S.T. Liang, et al., Chem. Eng. J. 354 (2018) 1058–1067. doi: 10.1016/j.cej.2018.07.210
23. [23]
  D. Guo, Y. Liu, H. Ji, et al., Environ. Sci. Technol. 55 (2021) 4045–4053. doi: 10.1021/acs.est.1c00349
1. [1]
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2. [2]
  Wei-Jia Wang , Kaihong Chen . Molecular-based porous polymers with precise sites for photoreduction of carbon dioxide. Chinese Chemical Letters, 2025, 36(1): 109998-. doi: 10.1016/j.cclet.2024.109998
3. [3]
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4. [4]
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10. [10]
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11. [11]
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12. [12]
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13. [13]
  Daheng Wen , Weiwei Fang , Yongmei Liu , Tao Tu . Valorization of carbon dioxide with alcohols. Chinese Chemical Letters, 2024, 35(7): 109394-. doi: 10.1016/j.cclet.2023.109394
14. [14]
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15. [15]
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16. [16]
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17. [17]
  Minjun Yin , Yuhui Lin , Manli Zhuang , Wei Xiao , Jie Wu . Photoredox-catalyzed synthesis of α,α-difluoromethyl-β-alkoxysulfones from sulfur dioxide. Chinese Chemical Letters, 2025, 36(3): 109926-. doi: 10.1016/j.cclet.2024.109926
18. [18]
  Pengfei Zhang , Qingxue Ma , Zhiwei Jiang , Xiaohua Xu , Zhong Jin . Transition-metal-catalyzed remote meta-C—H alkylation and alkynylation of aryl sulfonic acids enabled by an indolyl template. Chinese Chemical Letters, 2024, 35(8): 109361-. doi: 10.1016/j.cclet.2023.109361
19. [19]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
20. [20]
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Quick fabrication of evenly porous PbO2 through potential linear increase electrodeposition

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通讯作者: 陈斌, bchen63@163.com

Quick fabrication of evenly porous PbO₂ through potential linear increase electrodeposition