Citation: Shuya Liu, Yuhang Lin, Dongpeng Yan. Colorful ultralong room-temperature phosphorescence in dual-ligand metal-organic framework[J]. Chinese Chemical Letters, ;2023, 34(7): 107952. doi: 10.1016/j.cclet.2022.107952 shu

Colorful ultralong room-temperature phosphorescence in dual-ligand metal-organic framework

Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Key Laboratory of Radiopharmaceuticals, Ministry of Education, Beijing Normal University, Beijing 100875, China

yandp@bnu.edu.cn

Received Date: 7 July 2022
Revised Date: 18 October 2022
Accepted Date: 23 October 2022
Available Online: 27 October 2022

Figures(4)

Long afterglow organic-inorganic hybrid materials have attracted much attention in recent years and are widely used in information security, biological imaging and many other fields. Since up-conversion long-persistence materials are promising for bio-optical imaging due to their high penetration depth and elimination of autofluorescence background, it is highly desirable to combine down-conversion and up-conversion pathways to obtain smart materials with excitation-dependent tunable room-temperature phosphorescence properties. In this work, a metal-organic framework (Zn-DCPS-BIMB), consisting of divalent zinc ions, o-bis(imidazol-1-ylmethyl)benzene and 4,4′-dicarboxydiphenylsulfone, is designed to stabilize triplet excitons, coordinate the emission of different ligands, and endow materials with tunable emission color and up-conversion properties via heavy atoms effects promoting single-triplet orbital coupling and intersystem crossing.
- Room temperature phosphorescence,
- Information encryption,
- Metal-organic framework,
- Up-conversion luminescence,
- Organic-inorganic hybrids
1. [1]
  D. Li, F. Lu, J. Wang, et al., J. Am. Chem. Soc. 140 (2018) 1916–1923. doi: 10.1021/jacs.7b12800
2. [2]
  Y. Zhang, L. Gao, X. Zheng, et al., Nat. Commun. 12 (2021) 2297. doi: 10.1038/s41467-021-22609-y
3. [3]
  L. Gu, H. Shi, L. Bian, et al., Nat. Photon. 13 (2019) 406–411. doi: 10.1038/s41566-019-0408-4
4. [4]
  S. Kuila, S.J. George, Angew. Chem. Int. Ed. 59 (2020) 9393–9397. doi: 10.1002/anie.202002555
5. [5]
  Y. Li, L. Jiang, W. Liu, et al., Adv. Mater. 33 (2021) 2101844. doi: 10.1002/adma.202101844
6. [6]
  W. Zhao, T.S. Cheung, N. Jiang, et al., Nat. Commun. 10 (2019) 1595. doi: 10.1038/s41467-019-09561-8
7. [7]
  Y. Zhang, Y. Su, H. Wu, et al., J. Am. Chem. Soc. 143 (2021) 13675–13685. doi: 10.1021/jacs.1c05213
8. [8]
  L. Ma, Q. Xu, S. Sun, et al., Angew. Chem. Int. Ed. 61 (2022) e202115748.
9. [9]
  X. Li, Y. Xie, B. Song, et al., Angew. Chem. Int. Ed. 56 (2017) 2689–2693. doi: 10.1002/anie.201700011
10. [10]
  P.R. Su, T. Wang, P.P. Zhou, et al., Natl. Sci. Rev. 9 (2022) nwab016. doi: 10.1093/nsr/nwab016
11. [11]
  Q. Dang, Y. Jiang, J. Wang, et al., Adv. Mater. 32 (2020) 2006752. doi: 10.1002/adma.202006752
12. [12]
  Q. Liao, Q. Gao, J. Wang, et al., Angew. Chem. Int. Ed. 59 (2020) 9946–9951. doi: 10.1002/anie.201916057
13. [13]
  R. Gao, M.S. Kodaimati, D. Yan, Chem. Soc. Rev. 50 (2021) 5564–5589. doi: 10.1039/D0CS01463J
14. [14]
  X. Yang, D. Yan, Chem. Sci. 7 (2016) 4519–4526. doi: 10.1039/C6SC00563B
15. [15]
  H. Gui, Z. Huang, Z. Yuan, et al., CCS Chem. 4 (2022) 173–181. doi: 10.31635/ccschem.021.202000609
16. [16]
  L. Ma, G. Wang, B. Ding, et al., CCS Chem. 4 (2022) 2080–2089. doi: 10.31635/ccschem.021.202100992
17. [17]
  Q. Xu, L. Ma, X. Lin, et al., Chin. Chem. Lett. 33 (2022) 2965–2968. doi: 10.1016/j.cclet.2021.12.097
18. [18]
  R. Liu, T. Jiang, D. Liu, et al., Sci. China Chem. 65 (2022) 1100–1104. doi: 10.1007/s11426-022-1228-0
19. [19]
  C. Xu, C. Yin, W. Wu, et al., Sci. China Chem. 65 (2022) 75–81.
20. [20]
  Z. Wang, Z. Xiong, W. Liu, et al., Anal. Chem. 94 (2022) 5406–5414. doi: 10.1021/acs.analchem.2c00219
21. [21]
  R. Gao, D. Yan, D.G. Evans, X. Duan, Nano Res. 10 (2017) 3606–3617. doi: 10.1007/s12274-017-1571-x
22. [22]
  Y. Zheng, Q. Zhou, Y. Yang, et al., Small 18 (2022) 2201223. doi: 10.1002/smll.202201223
23. [23]
  S. Cai, H. Shi, J. Li, et al., Adv. Mater. 29 (2017) 1701244. doi: 10.1002/adma.201701244
24. [24]
  H.J. Yu, Q. Zhou, X. Dai, et al., J. Am. Chem. Soc. 143 (2021) 13887–13894. doi: 10.1021/jacs.1c06741
25. [25]
  D. Zhang, H. Zheng, X. Ma, et al., Adv. Opt. Mater. 10 (2022) 2102015. doi: 10.1002/adom.202102015
26. [26]
  B. Wang, S. Lu, Matter 5 (2022) 110–149. doi: 10.1016/j.matt.2021.10.016
27. [27]
  M. Zhao, H. Liao, L. Ning, et al., Adv. Mater. 30 (2018) 1802489. doi: 10.1002/adma.201802489
28. [28]
  J. Qiao, G. Zhou, Y. Zhou, et al., Nat. Commun. 10 (2019) 5267. doi: 10.1038/s41467-019-13293-0
29. [29]
  Z. Xie, X. Zhang, H. Wang, et al., Nat. Commun. 12 (2021) 3522. doi: 10.1038/s41467-021-23742-4
30. [30]
  H. Wang, H. Shi, W. Ye, et al., Angew. Chem. Int. Ed. 58 (2019) 18776–18782. doi: 10.1002/anie.201911331
31. [31]
  L. Gu, H. Shi, L. Bian, et al., Nat. Photonics 13 (2019) 406–411. doi: 10.1038/s41566-019-0408-4
32. [32]
  J. Lee, P.W. Bisso, R.L. Srinivas, et al., Nat. Mater. 13 (2014) 524–529. doi: 10.1038/nmat3938
33. [33]
  H. Lee, J. Kim, H. Kim, J. Kim, S. Kwon, Nat. Mater. 9 (2010) 745–749. doi: 10.1038/nmat2815
34. [34]
  W. Zhao, Z. He, B.Z. Tang, Nat. Rev. Mater. 5 (2020) 869–885. doi: 10.1038/s41578-020-0223-z
35. [35]
  Y. Yang, K.Z. Wang, D. Yan, Chem. Commun. 53 (2017) 7752–7755. doi: 10.1039/C7CC04356B
36. [36]
  J. Liu, Y. Zhuang, L. Wang, et al., ACS Appl. Mater. Interfaces 10 (2018) 1802–1809. doi: 10.1021/acsami.7b13486
37. [37]
  Y. Yang, X. Yang, X. Fang, K.Z. Wang, D. Yan, Adv. Sci. 5 (2018) 1801187. doi: 10.1002/advs.201801187
38. [38]
  J. Yang, X. Gao, Z. Xie, et al., Angew. Chem. Int. Ed. 56 (2017) 15299–15303. doi: 10.1002/anie.201708119
39. [39]
  T. Wang, Z. Hu, X. Nie, et al., Nat. Commun. 12 (2021) 1364. doi: 10.1038/s41467-021-21676-5
40. [40]
  Z.W. Li, L.Y. Peng, X.F. Song, et al., J. Phys. Chem. Lett. 12 (2021) 5944–5950. doi: 10.1021/acs.jpclett.1c01558
41. [41]
  S. Wan, J. Lin, H. Su, et al., Chem. Commun. 54 (2018) 3907–3910. doi: 10.1039/C8CC00780B
42. [42]
  Q. Peng, Z. Shuai, Aggregate 2 (2021) e91.
43. [43]
  J. Yuan, J. Dong, S. Lei, W. Hu, Mater. Chem. Front. 5 (2021) 6824–6849. doi: 10.1039/D1QM00689D
44. [44]
  C.Y. Sun, W.P. To, X.L. Wang, et al., Chem. Sci. 6 (2015) 7105–7111. doi: 10.1039/C5SC02216A
45. [45]
  Z. Wang, C.Y. Zhu, J.T. Mo, et al., Angew. Chem. Int. Ed. 133 (2020) 2556–2563.
46. [46]
  P.Y. Fu, B.N. Li, Q.S. Zhang, et al., J. Am. Chem. Soc. 144 (2022) 2726–2734. doi: 10.1021/jacs.1c11874
47. [47]
  H. Liu, W. Ye, Y. Mu, et al., Adv. Mater. 34 (2022) 2107612. doi: 10.1002/adma.202107612
48. [48]
  P. Mahato, A. Monguzzi, N. Yanai, et al., Nat. Mater. 14 (2015) 924–930. doi: 10.1038/nmat4366
49. [49]
  M. Scholz, G. Croizat, J. Pšenčík, et al., Photochem. Photobiol. Sci. 20 (2021) 843–857. doi: 10.1007/s43630-021-00044-8
50. [50]
  K.T. Chan, G.S.M. Tong, W.P. To, et al., Chem. Sci. 8 (2017) 2352–2364. doi: 10.1039/C6SC03775E
51. [51]
  B. Lu, X. Fang, D. Yan, ACS Appl. Mater. Interfaces 12 (2020) 31940–31951. doi: 10.1021/acsami.0c06794
52. [52]
  Y.E. Huang, X.Z. Wang, P. Hu, et al., Nanoscale 12 (2020) 6227–6232. doi: 10.1039/D0NR00306A
53. [53]
  Z. Ye, X. Lin, N. Wang, et al., Nat. Commun. 12 (2021) 4283. doi: 10.1038/s41467-021-24560-4
54. [54]
  R. Feng, Z.Y. Li, Z.Q. Yao, et al., Sci. China Chem. 65 (2022) 128–134. doi: 10.1007/s11426-021-1123-3
1. [1]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
2. [2]
  Xu Huang , Kai-Yin Wu , Chao Su , Lei Yang , Bei-Bei Xiao . Metal-organic framework Cu-BTC for overall water splitting: A density functional theory study. Chinese Chemical Letters, 2025, 36(4): 109720-. doi: 10.1016/j.cclet.2024.109720
3. [3]
  Yuxin Wang , Zhengxuan Song , Yutao Liu , Yang Chen , Jinping Li , Libo Li , Jia Yao . Methyl functionalization of trimesic acid in copper-based metal-organic framework for ammonia colorimetric sensing at high relative humidity. Chinese Chemical Letters, 2024, 35(6): 108779-. doi: 10.1016/j.cclet.2023.108779
4. [4]
  Ning Zhang , Mengjie Qin , Jiawen Zhu , Xuejing Lou , Xiao Tian , Wende Ma , Youmei Wang , Minghua Lu , Zongwei Cai . Thickness-controllable synthesis of metal-organic framework based hollow nanoflowers with magnetic core via liquid phase epitaxy for phosphopeptides enrichment. Chinese Chemical Letters, 2025, 36(4): 110177-. doi: 10.1016/j.cclet.2024.110177
5. [5]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
6. [6]
  Xuying Yu , Jiarong Mi , Yulan Han , Cai Sun , Mingsheng Wang , Guocong Guo . A stable radiochromic semiconductive viologen-based metal–organic framework for dual-mode direct X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109233-. doi: 10.1016/j.cclet.2023.109233
7. [7]
  Zixi Zou , Jingyuan Wang , Yian Sun , Qian Wang , Da-Hui Qu . Controlling molecular assembly on time scale: Time-dependent multicolor fluorescence for information encryption. Chinese Chemical Letters, 2024, 35(7): 108972-. doi: 10.1016/j.cclet.2023.108972
8. [8]
  Wen-Jun Xia , Yong-Jiang Wang , Yun-Fei Cao , Cai Sun , Xin-Xiong Li , Yan-Qiong Sun , Shou-Tian Zheng . A luminescent folded S-shaped high-nuclearity Eu₁₉-oxo-cluster embedded polyoxoniobate for information encryption. Chinese Chemical Letters, 2025, 36(2): 110248-. doi: 10.1016/j.cclet.2024.110248
9. [9]
  Xiang Wang , Qingping Song , Zixiang He , Gong Zhang , Tengfei Miao , Xiaoxiao Cheng , Wei Zhang . Constructing diverse switchable circularly polarized luminescence via a single azobenzene polymer film. Chinese Chemical Letters, 2025, 36(1): 110047-. doi: 10.1016/j.cclet.2024.110047
10. [10]
  Jiayin Zhou , Depeng Liu , Longqiang Li , Min Qi , Guangqiang Yin , Tao Chen . Responsive organic room-temperature phosphorescence materials for spatial-time-resolved anti-counterfeiting. Chinese Chemical Letters, 2024, 35(11): 109929-. doi: 10.1016/j.cclet.2024.109929
11. [11]
  Jiayu Xu , Meng Li , Baoxia Dong , Ligang Feng . Fully fluorinated hybrid zeolite imidazole/Prussian blue analogs with combined advantages for efficient oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(6): 108798-. doi: 10.1016/j.cclet.2023.108798
12. [12]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
13. [13]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
14. [14]
  Ying Gao , Rong Zhou , Qiwen Wang , Shaolong Qi , Yuanyuan Lv , Shuang Liu , Jie Shen , Guocan Yu . Natural killer cell membrane doped supramolecular nanoplatform with immuno-modulatory functions for immuno-enhanced tumor phototherapy. Chinese Chemical Letters, 2024, 35(10): 109521-. doi: 10.1016/j.cclet.2024.109521
15. [15]
  Lei Zhu , Hai-Ruo Li , Yi-Ning Mao , Ruiying Liu , Bo Zhang , Jing Chen , Wengui Xu , Libo Zhang , Cheng-Peng Li . A four-fold interpenetrated MOF for efficient perrhenate/pertechnetate removal from alkaline nuclear effluents. Chinese Chemical Letters, 2024, 35(12): 109921-. doi: 10.1016/j.cclet.2024.109921
16. [16]
  Guizhi Zhu , Junrui Tan , Longfei Tan , Qiong Wu , Xiangling Ren , Changhui Fu , Zhihui Chen , Xianwei Meng . Growth of CeCo-MOF in dendritic mesoporous organosilica as highly efficient antioxidant for enhanced thermal stability of silicone rubber. Chinese Chemical Letters, 2025, 36(1): 109669-. doi: 10.1016/j.cclet.2024.109669
17. [17]
  Zhefei Hu , Jingwen Liao , Jiawen Zhou , Lulu Zhao , Yanjuan Liu , Yuefei Zhang , Wei Chen , Sheng Tang . A new green approach to synthesizing MIP-202@porous silica microspheres for positional isomer/enantiomer/hydrophilic separation. Chinese Chemical Letters, 2025, 36(1): 109985-. doi: 10.1016/j.cclet.2024.109985
18. [18]
  Yao-Yu Ma , Wen-Juan Shi , Gang-Ding Wang , Xin Liu , Lei Hou , Yao-Yu Wang . Enhancing ethane/ethylene separation performance through the amino-functionalization of ethane-selective MOF. Chinese Chemical Letters, 2025, 36(3): 109729-. doi: 10.1016/j.cclet.2024.109729
19. [19]
  Ziyi Zhu , Yang Cao , Jun Zhang . CO2-switched porous metal-organic framework magnets. Chinese Journal of Structural Chemistry, 2024, 43(2): 100241-100241. doi: 10.1016/j.cjsc.2024.100241
20. [20]
  Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(749)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142