Citation: Jinli Li, Junhua Wang, Feng Shui, Mao Yi, Zhiyuan Zhang, Xiongli Liu, Laiyu Zhang, Zifeng You, Rufeng Yang, Shiqi Yang, Baiyan Li, Xian-He Bu. Superhigh intrinsic proton conductivity in densely carboxylic covalent organic framework[J]. Chinese Chemical Letters, ;2023, 34(8): 107917. doi: 10.1016/j.cclet.2022.107917 shu

Superhigh intrinsic proton conductivity in densely carboxylic covalent organic framework

School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China

libaiyan@nankai.edu.cn

Received Date: 1 September 2022
Revised Date: 28 September 2022
Accepted Date: 17 October 2022
Available Online: 19 October 2022

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Herein, we developed for the first time two carboxylic acid based intrinsic proton conductors (COOH-COF-1 and COOH-COF-2) via pre-assembly approach. The obtained COOH-COF-1 and COOH-COF-2 not only show outstanding chemical and thermal stabilities, but also exhibit superhigh intrinsic proton conductive behaviors. Especially, the intrinsic proton conductivity of COOH-COF-2 is up to 2.6 × 10⁻³ S/cm at 353 K and 98% RH, which is the highest value among all the reported acid functionalized COFs. This work lights up the way for the rational design of functional COFs with remarkably intrinsic proton conducting performance and related practical applications.
- Covalent organic frameworks (COFs),
- Pre-assembly approach,
- Intrinsic proton conductivity,
- Rational design,
- Carboxylic acid
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