Citation: Ang Li, Mengke Huang, Die Hu, Zhaodi Tang, Jianhang Xu, Yang Li, Xiaowei Zhang, Xiao Chen, Ge Wang. Polydopamine-coated metal-organic framework-based composite phase change materials for photothermal conversion and storage[J]. Chinese Chemical Letters, ;2023, 34(8): 107916. doi: 10.1016/j.cclet.2022.107916 shu

Polydopamine-coated metal-organic framework-based composite phase change materials for photothermal conversion and storage

Ang Li ^{a, 1,*,} ,
Mengke Huang ^{b, 1} ,
Die Hu ^b ,
Zhaodi Tang ^b ,
Jianhang Xu ^b ,
Yang Li ^c ,
Xiaowei Zhang ^c ,
Xiao Chen ^{c, d, *,} ,
Ge Wang ^{b, e, *,}

a.
School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China
b.
Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory of Function Materials for Molecule & Structure Construction, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
c.
Institute of Advanced Materials, Beijing Normal University, Beijing 100875, China
d.
Key Laboratory of Low-grade Energy Utilization Technologies and Systems (Chongqing University), Ministry of Education of China, Chongqing University, Chongqing 400044, China
e.
Shunde Graduate School, University of Science and Technology Beijing, Shunde 528399, China

angli@usts.edu.cn

xiaochen@bnu.edu.cn

gewang@ustb.edu.cn

Received Date: 29 August 2022
Revised Date: 8 October 2022
Accepted Date: 17 October 2022
Available Online: 19 October 2022

Figures(4)

The liquid leakage and weak solar absorption capacity of organic phase change materials (PCMs) seriously hinder the efficient utilization of solar energy and thermal energy storage. To address these issues, we prepared nanoporous metal organic framework (Ni-MOF) for the vacuum infiltration of paraffin wax (PW), followed by the coating of solar-absorbing functional polydopamine (PDA) on the surface of PW@MOF for photothermal conversion and storage. As an efficient photon harvester, PDA coating endows PW@MOF/PDA composite PCMs with excellent photothermal conversion and storage properties due to the robust broadband solar absorption capability in the UV–vis region. Resultantly, our prepared PW@MOF/PDA composite PCMs exhibit a high photothermal conversion and storage efficiency of 91.2%, while that of PW@MOF composite PCMs is only zero. In addition, PW@MOF/PDA composite PCMs also exhibit excellent thermal stability, shape stability, energy storage stability, and photothermal conversion stability. More importantly, this coating strategy is universal by integrating different MOFs and solar absorbers, showing the potential to accelerate the major breakthroughs of high-efficiency MOF-based photothermal composite PCMs in solar energy utilization.
- Phase change materials,
- Metal organic frameworks,
- Photothermal conversion,
- Thermal energy storage,
- Photon harvester
1. [1]
  X. Chen, H. Yu, Y. Gao, et al., EnergyChem (2022) 100071.
2. [2]
  X. Chen, H. Gao, Z. Tang, et al., Energy Environ. Sci. 13 (2020) 4498–4535. doi: 10.1039/D0EE01355B
3. [3]
  A. Allahbakhsh, M. Arjmand, Carbon 148 (2019) 441–480. doi: 10.1016/j.carbon.2019.04.009
4. [4]
  P. Cheng, X. Chen, H. Gao, et al., Nano Energy 85 (2021) 105948. doi: 10.1016/j.nanoen.2021.105948
5. [5]
  D.G. Atinafu, B.Y. Yun, S. Yang, et al., Energy Storage Mater. 42 (2021) 164–184. doi: 10.1016/j.ensm.2021.07.022
6. [6]
  X. Chen, P. Cheng, Z. Tang, et al., Adv. Sci. 8 (2021) 2001274. doi: 10.1002/advs.202001274
7. [7]
  K. Yuan, J. Liu, X. Fang, Z. Zhang, Sol. Energy Mater. Sol. Cells 218 (2020) 110759. doi: 10.1016/j.solmat.2020.110759
8. [8]
  D. Yan, B. Tang, S. Zhang, Sol. Energy Mater. Sol. Cells 215 (2020) 110657. doi: 10.1016/j.solmat.2020.110657
9. [9]
  C. Wang, W. Dong, A. Li, et al., Chem. Eng. J. 428 (2022) 130605. doi: 10.1016/j.cej.2021.130605
10. [10]
  X. Du, J. Qiu, S. Deng, et al., ACS Sustain. Chem. Eng. 8 (2020) 5799–5806. doi: 10.1021/acssuschemeng.0c01582
11. [11]
  Z. Tao, M. Yang, L. Wu, et al., Chem. Eng. J. 423 (2021) 130180. doi: 10.1016/j.cej.2021.130180
12. [12]
  A.M. Pornea, H. Kim, Energy Convers. Manag. 232 (2021) 113801. doi: 10.1016/j.enconman.2020.113801
13. [13]
  Y. Cao, Y. Meng, Y. Jiang, et al., Chem. Eng. J. 433 (2022) 134549. doi: 10.1016/j.cej.2022.134549
14. [14]
  H.Y. Wu, R.T. Chen, Y.W. Shao, et al., ACS Sustain. Chem. Eng. 7 (2019) 13532–13542. doi: 10.1021/acssuschemeng.9b03169
15. [15]
  X.S. Du, J.H. Qu, S. Deng, et al., ACS Sustain. Chem. Eng. 8 (2020) 5799–5806. doi: 10.1021/acssuschemeng.0c01582
16. [16]
  X. Xiao, L. Zou, H. Pang, Q. Xu, Chem. Soc. Rev. 49 (2020) 301–331. doi: 10.1039/C7CS00614D
17. [17]
  R.B. Lin, S. Xiang, W. Zhou, B. Chen, Chem. 6 (2020) 337–363. doi: 10.1016/j.chempr.2019.10.012
18. [18]
  R. Zhao, Z. Liang, R. Zou, Q. Xu, Joule 2 (2018) 2235–2259. doi: 10.1016/j.joule.2018.09.019
19. [19]
  L.S. Xie, G. Skorupskii, M. Dincă, Chem. Rev. 120 (2020) 8536–8580. doi: 10.1021/acs.chemrev.9b00766
20. [20]
  X. Chen, H. Gao, Z. Tang, G. Wang, Cell Rep. 1 (2020) 100218.
21. [21]
  M. Maleki, H. Karimian, M. Shokouhimehr, et al., Chem. Eng. J. 362 (2019) 469–481.
1. [1]
  Jian-Rong Li , Jieying Hu , Lai-Hon Chung , Jilong Zhou , Parijat Borah , Zhiqing Lin , Yuan-Hui Zhong , Hua-Qun Zhou , Xianghua Yang , Zhengtao Xu , Jun He . Insight into stable, concentrated radicals from sulfur-functionalized alkyne-rich crystalline frameworks and application in solar-to-vapor conversion. Chinese Journal of Structural Chemistry, 2024, 43(8): 100380-100380. doi: 10.1016/j.cjsc.2024.100380
2. [2]
  Jieqiong Xu , Wenbin Chen , Shengkai Li , Qian Chen , Tao Wang , Yadong Shi , Shengyong Deng , Mingde Li , Peifa Wei , Zhuo Chen . Organic stoichiometric cocrystals with a subtle balance of charge-transfer degree and molecular stacking towards high-efficiency NIR photothermal conversion. Chinese Chemical Letters, 2024, 35(10): 109808-. doi: 10.1016/j.cclet.2024.109808
3. [3]
  Tianwen Chen , Chunqiang Cai , Li Chen , Yanlin Chen , Lichun Dong , Luxi Tan , Zitong Liu . Novel vinylene-bridged covalent organic framework based on diketopyrrolopyrrole with exceptional photothermal properties. Chinese Chemical Letters, 2025, 36(7): 111028-. doi: 10.1016/j.cclet.2025.111028
4. [4]
  Cheng Cheng , Nasir Ali , Ji Liu , Juan Qiao , Ming Wang , Li Qi . Construction of degradable liposome-templated microporous metal-organic frameworks with commodious space for enzymes. Chinese Chemical Letters, 2024, 35(11): 109812-. doi: 10.1016/j.cclet.2024.109812
5. [5]
  Jingjing Zhang , Fei Yang , Liying Zhang , Ran Li , Guo Wang , Yanqing Xu , Wei Wei . Stable radicals in bacteria composites hybridized by a doubly-strapped perylene diimide for near-infrared photothermal conversion. Chinese Chemical Letters, 2025, 36(7): 110627-. doi: 10.1016/j.cclet.2024.110627
6. [6]
  Ying Zhao , Yao He , Jian-Xin Yang , Wen-Jie Liu , Dan Tian , Francisco Aznarez , Le-Le Gong , Li-Long Dang , Lu-Fang Ma . Controllable self-assembly and photothermal conversion of metalla[2]catenanes induced by synergistic effect of free radicals and stacking interactions. Chinese Chemical Letters, 2025, 36(12): 111460-. doi: 10.1016/j.cclet.2025.111460
7. [7]
  Xinbao Tong , Jiaying Liu , Yanqi Zhao , Jingjun Li , Ye Tian , Qingyi Liu , Shuiying Gao , Rong Cao . Metal-organic framework supported carbon quantum dots as white light-emitting phosphor. Chinese Chemical Letters, 2025, 36(7): 111058-. doi: 10.1016/j.cclet.2025.111058
8. [8]
  Zikang Hu , Hengjie Zhang , Zhengqiu Li , Tianbao Zhao , Zhipeng Gu , Qijuan Yuan , Baoshu Chen . Multifunctional photothermal hydrogels: Design principles, various functions, and promising biological applications. Chinese Chemical Letters, 2024, 35(10): 109527-. doi: 10.1016/j.cclet.2024.109527
9. [9]
  Pin Cui , Ying Tang , Jie Yu , Zhen Yang , Shouhua Yang , Boqin Li , Gang Wang , Huan Pang , Feng Yu . Bimetallic ZnFe–NC prepared using microchannel reactor for oxygen reduction reaction and mechanism research. Chinese Chemical Letters, 2025, 36(9): 110303-. doi: 10.1016/j.cclet.2024.110303
10. [10]
  Qing Li , Fangyu Fu , Mengyun Zhao , Yeqin Feng , Manzhou Chi , Zichen Zhao , Hongjin Lv , Guo-Yu Yang . Asymmetrically anchoring silver alkynyl cluster to the cobalt-containing polyoxometalate. Chinese Chemical Letters, 2025, 36(7): 110090-. doi: 10.1016/j.cclet.2024.110090
11. [11]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282
12. [12]
  Chong-Chen Wang , Xiaohang Xu . Metal-organic frameworks helping resource and energy recovery from sludge. Chinese Chemical Letters, 2025, 36(10): 111287-. doi: 10.1016/j.cclet.2025.111287
13. [13]
  Genlin Sun , Yachun Luo , Zhihong Yan , Hongdeng Qiu , Weiyang Tang . Chiral metal-organic frameworks-based materials for chromatographic enantioseparation. Chinese Chemical Letters, 2024, 35(12): 109787-. doi: 10.1016/j.cclet.2024.109787
14. [14]
  Xinyu Wu , Jianfeng Lu , Zihao Zhu , Suijun Liu , Herui Wen . Recent advances of metal-organic frameworks and MOF-derived materials based on p-block metal for the electrochemical reduction of carbon dioxide. Chinese Chemical Letters, 2025, 36(7): 110151-. doi: 10.1016/j.cclet.2024.110151
15. [15]
  Zehao Zhang , Zheng Wang , Haibo Li . Preparation of 2D V₂O₃@Pourous Carbon Nanosheets Derived from V₂CF_x MXene for Capacitive Desalination. Acta Physico-Chimica Sinica, 2024, 40(8): 2308020-0. doi: 10.3866/PKU.WHXB202308020
16. [16]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . Hierarchical MoS₂/Ti₃C₂T_x heterostructure with excellent photothermal conversion performance for solar-driven vapor generation. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-0. doi: 10.1016/j.actphy.2025.100053
17. [17]
  Tao LIU , Yuting TIAN , Ke GAO , Xuwei HAN , Ru'nan MIN , Wenjing ZHAO , Xueyi SUN , Caixia YIN . A photothermal agent with high photothermal conversion efficiency and high stability for tumor therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1622-1632. doi: 10.11862/CJIC.20240107
18. [18]
  Chen Gu , Huacao Ji , Keyu Xu , Jianmei Chen , Kang Chen , Junan Pan , Ning Sun , Longlu Wang . The recent progress of transition metal dichalcogenides-based photothermal materials for solar water generation. Chinese Chemical Letters, 2025, 36(8): 110565-. doi: 10.1016/j.cclet.2024.110565
19. [19]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
20. [20]
  Xiao-Fang Lv , Xiao-Yun Ran , Yu Zhao , Rui-Rui Zhang , Li-Na Zhang , Jing Shi , Ji-Xuan Xu , Qing-Quan Kong , Xiao-Qi Yu , Kun Li . Combing NIR-Ⅱ molecular dye with magnetic nanoparticles for enhanced photothermal theranostics with a 95.6% photothermal conversion efficiency. Chinese Chemical Letters, 2025, 36(4): 110027-. doi: 10.1016/j.cclet.2024.110027

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(993)
HTML views(51)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142