Citation: Taorui Liu, Yajun Liu, Xingbang Gao, Jing Cao. Self-assembly of porphyrins on perovskite film for blade-coating stable large-area methylammonium-free solar cells[J]. Chinese Chemical Letters, ;2023, 34(8): 107883. doi: 10.1016/j.cclet.2022.107883 shu

Self-assembly of porphyrins on perovskite film for blade-coating stable large-area methylammonium-free solar cells

State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

caoj@lzu.edu.cn

Received Date: 28 July 2022
Revised Date: 5 September 2022
Accepted Date: 4 October 2022
Available Online: 10 October 2022

Figures(4)

Phase transition and phase separation of formamidinium-cesium (FA-Cs) perovskite during the fabrication and operation processes reduce the efficiency and stability of perovskite solar cells (PSCs). Here, we develop an in situ molecular self-assembly approach on perovskite surface using an amine nickel porphyrin (NiP). The NiP doped perovskite precursor solution was deposited on substrate by blade-coating under ambient condition. NiP molecules self-assemble into supramolecule bound on perovskite surface during the vacuum-assisted process. Such a modification controls the perovskite grain growth to generate the uniform perovskite film. The supramolecule can release the residual lattice strain to inhibit the phase transition of perovskite film, and promote the charge extraction and transport to suppress the phase separation of FA-Cs perovskite during long-term illumination condition. Consequently, the best efficiency of large-area NiP-based FA-Cs-PSCs with the active area of 1.0 cm² is up to 20.3% (certified as 19.2%), which is close to the record efficiency (20.37%) by blade-coating. Unencapsulated NiP-doped device reveals the remarkably improved overall stabilities. This work affords a novel way to address the phase transition and phase separation in FA-Cs perovskite.
- MA-free perovskite,
- Ni porphyrin,
- Supramolecule,
- Self-assemble,
- Phase transition,
- Phase separation
1. [1]
  Y. Zhao, F. Ma, Z. Qu, et al., Science 377 (2022) 531-534. doi: 10.1126/science.abp8873
2. [2]
  Z. Wei, Y. Zhao, J. Jiang, et al., Chin. Chem. Lett. 31 (2020) 3055-3064. doi: 10.1016/j.cclet.2020.05.016
3. [3]
  M. Worku, A. Ben-Akacha, T. Blessed Shonde, et al., Small Sci. 1 (2021) 2000072. doi: 10.1002/smsc.202000072
4. [4]
  Y. Sun, W. Chen, Z. Sun, Chin. Chem. Lett. 33 (2022) 1772-1778. doi: 10.1016/j.cclet.2021.08.055
5. [5]
  Y. Fang, L. Zhang, Y. Yu, et al., CCS Chem. 3 (2020) 2203-2210. doi: 10.31635/ccschem.020.202000430
6. [6]
  Best Research-Cell Efficiency Chart; https://www.nrel.gov/pv/cell-efficiency.html
7. [7]
  T. Bu, L.K. Ono, J. Li, et al., Nat. Energy 7 (2022) 528-536. doi: 10.1038/s41560-022-01039-0
8. [8]
  X. Jiang, K. Wang, H. Wang, et al., Small Sci. 1 (2021) 2000054. doi: 10.1002/smsc.202000054
9. [9]
  S.H. Turren-Cruz, A. Hagfeldt, M. Saliba, Science 362 (2018) 449-453. doi: 10.1126/science.aat3583
10. [10]
  W.Q. Wu, P.N. Rudd, Q. Wang, Z. Yang, J. Huang, Adv. Mater. 32 (2020) e2000995. doi: 10.1002/adma.202000995
11. [11]
  C. Ge, Z. Yang, X. Liu, et al., CCS Chem. 3 (2020) 2035-2044. doi: 10.31635/ccschem.021.202101483
12. [12]
  J. Jeong, M. Kim, J. Seo, et al., Nature 592 (2021) 381-385. doi: 10.1038/s41586-021-03406-5
13. [13]
  X. Ling, H. Zhu, W. Xu, et al., Angew. Chem. Int. Ed. 60 (2021) 27299-27306. doi: 10.1002/anie.202112555
14. [14]
  R. Li, C. Li, M. Liu, et al., CCS Chem. 4 (2021) 3084-3094. doi: 10.31635/ccschem.021.202101483
15. [15]
  H. Lu, Y. Liu, P. Ahlawat, et al., Science 370 (2020) eabb8985. doi: 10.1126/science.abb8985
16. [16]
  Q. Jia, T. Shao, L. Tong, et al., Chin. Chem. Lett. 34 (2023) 107539. doi: 10.1016/j.cclet.2022.05.053
17. [17]
  T. Du, T.J. Macdonald, R.X. Yang, et al., Adv. Mater. 34 (2022) e21078.
18. [18]
  C. Su, Z. Zhang, J. Yao, et al., Chin. Chem. Lett. 34 (2023) 107442. doi: 10.1016/j.cclet.2022.04.040
19. [19]
  X. Zheng, C. Wu, S.K. Jha, et al., ACS Energy Lett. 1 (2016) 1014-1020. doi: 10.1021/acsenergylett.6b00457
20. [20]
  G. Kim, H. Min, K.S. Lee, et al., Science 370 (2020) 108-112. doi: 10.1126/science.abc4417
21. [21]
  W. Hui, L. Chao, H. Lu, et al., Science 371 (2021) 1359-1364. doi: 10.1126/science.abf7652
22. [22]
  J. Wu, Y. Cui, B. Yu, et al., Adv. Funct. Mater. 29 (2019) 1905336. doi: 10.1002/adfm.201905336
23. [23]
  Y. Chen, Y. Lei, Y. Li, et al., Nature 577 (2020) 209-215. doi: 10.1038/s41586-019-1868-x
24. [24]
  J. Zhou, L. Ding, F. Zhao, et al., Chin. Chem. Lett. 31 (2020) 554-558. doi: 10.1016/j.cclet.2019.05.008
25. [25]
  Z. Duan, G. Na, S. Wang, et al., Small Sci. 2 (2022) 2100114. doi: 10.1002/smsc.202100114
26. [26]
  F. Wang, W. Geng, Y. Zhou, et al., Adv. Mater. 28 (2016) 9986-9992. doi: 10.1002/adma.201603062
27. [27]
  G.B. Xiao, Z.F. Yu, J. Cao, Y. Tang, CCS Chem. 2 (2020) 488-494. doi: 10.31635/ccschem.020.202000163
28. [28]
  N.J. Jeon, J.H. Noh, W.S. Yang, et al., Nature 517 (2015) 476-480. doi: 10.1038/nature14133
29. [29]
  S. Tang, Y. Deng, X. Zheng, et al., Adv. Energy Mater. 7 (2017) 1700302. doi: 10.1002/aenm.201700302
30. [30]
  G.B. Xiao, L.Y. Wang, X.J. Mu, et al., CCS Chem. 3 (2021) 25-36. doi: 10.31635/ccschem.021.202000516
31. [31]
  Z. Yang, W. Zhang, S. Wu, et al., Sci. Adv. 7 (2021) eabg3749. doi: 10.1126/sciadv.abg3749
32. [32]
  R. Chen, Y. Wang, S. Nie, et al., J. Am. Chem. Soc. 143 (2021) 10624-10632. doi: 10.1021/jacs.1c03419
33. [33]
  T. Bu, J. Li, H. Li, et al., Science 372 (2021) 1327-1332. doi: 10.1126/science.abh1035
34. [34]
  L. Chao, T. Niu, W. Gao, et al., Adv. Mater. 33 (2021) e2005410. doi: 10.1002/adma.202005410
35. [35]
  N. Li, Y. Luo, Z. Chen, et al., Joule 4 (2020) 1743-1758. doi: 10.1016/j.joule.2020.06.005
36. [36]
  Y. Deng, S. Xu, S. Chen, et al., Nat. Energy 6 (2021) 633-641. doi: 10.1038/s41560-021-00831-8
37. [37]
  C. Li, J. Yin, R. Chen, et al., J. Am. Chem. Soc. 141 (2019) 6345-6351. doi: 10.1021/jacs.9b01305
38. [38]
  Z. Fang, L. Wang, X. Mu, et al., J. Am. Chem. Soc. 143 (2021) 18989-18996. doi: 10.1021/jacs.1c07518
39. [39]
  Q. Liang, K. Liu, M. Sun, et al., Adv. Mater. 34 (2022) e2200276. doi: 10.1002/adma.202200276
40. [40]
  J.H. Zhao, X. Mu, L. Wang, et al., Angew. Chem. Int. Ed. 61 (2022) e202116308. doi: 10.1002/anie.202116308
41. [41]
  J.T.W. Wang, Z. Wang, S. Pathak, et al., Energy Environ. Sci. 9 (2016) 2892-2901. doi: 10.1039/C6EE01969B
42. [42]
  G. Kim, H. Min, S. Lee Kyoung, et al., Science 370 (2020) 108-112. doi: 10.1126/science.abc4417
43. [43]
  M. Ghasemi Hajiabadi, M. Zamanian, D. Souri, Ceram. Int. 45 (2019) 14084-14089. doi: 10.1016/j.ceramint.2019.04.107
44. [44]
  J. Cao, B. Wu, R. Chen, et al., Adv. Mater. 30 (2018) 1705596. doi: 10.1002/adma.201705596
45. [45]
  Z. Yu, L. Wang, X. Mu, et al., Angew. Chem. Int. Ed. 60 (2021) 6294-6299. doi: 10.1002/anie.202016087
46. [46]
  K. Ma, H.R. Atapattu, Q. Zhao, et al., Adv. Mater. 33 (2021) e2100791. doi: 10.1002/adma.202100791
47. [47]
  Y. Zhou, F. Wang, Y. Cao, et al., Adv. Energy Mater. 7 (2017) 1701048. doi: 10.1002/aenm.201701048
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2. [2]
  Zhi-Yuan Yue , Hua-Kai Li , Na Wang , Shan-Shan Liu , Le-Ping Miao , Heng-Yun Ye , Chao Shi . Dehydration-triggered structural phase transition-associated ferroelectricity in a hybrid perovskite-type crystal. Chinese Chemical Letters, 2024, 35(10): 109355-. doi: 10.1016/j.cclet.2023.109355
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  Ying-Yu Zhang , Jia-Qi Luo , Yan Han , Wan-Ying Zhang , Yi Zhang , Hai-Feng Lu , Da-Wei Fu . Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature. Chinese Chemical Letters, 2025, 36(1): 109530-. doi: 10.1016/j.cclet.2024.109530
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