Citation: Zirong Song, Jie Li, Hongxin Xu, Yu Li, Yaxiong Zeng, Baohong Guan. Heterogeneous catalytic ozonation by amorphous boron for degradation of atrazine in water[J]. Chinese Chemical Letters, ;2023, 34(5): 107876. doi: 10.1016/j.cclet.2022.107876 shu

Heterogeneous catalytic ozonation by amorphous boron for degradation of atrazine in water

Zirong Song ^a ,
Jie Li ^a ,
Hongxin Xu ^b ,
Yu Li ^a ,
Yaxiong Zeng ^{c, *,} ,
Baohong Guan ^{a, *,}

a.
College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 320058, China
b.
Yiwu Water Construction Group Co., Ltd., Yiwu 322000, China
c.
College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 320013, China

zengyaxiong@zju.edu.cn

guanbaohong@zju.edu.cn

Received Date: 4 July 2022
Revised Date: 15 September 2022
Accepted Date: 30 September 2022
Available Online: 4 October 2022

Figures(4)

As one of the most promising and practical advanced oxidation processes (AOPs), the catalytic ozonation is triggered by the active components of catalyst, which are usually derived from metals or metal oxides. To avoid the metal pollution from catalyst, here the amorphous boron (A-boron) is used as a metal-free catalyst for catalytic ozonation to produce free radicals for effective degradation of atrazine (ATZ), the world-widely used herbicide and also a widespread pollutant in environment. A-boron exhibits an outstanding performance for catalytic ozonation to remove ATZ from water. As A-boron is introduced into ozonation, the degradation efficiency in 10 min is promoted to 97.1%, much higher than that of 15.1% under ozonation. The mechanism is that the B–B bonds and internal suboxide B in A-boron serve as the main active sites to donate electrons to accelerate ozone decomposition to produce reactive oxygen species (ROS), including ^•O₂⁻ and ¹O₂, and further enhance ATZ degradation via ROS reactions. Moreover, the A-boron is still highly active with a degradation efficiency of ATZ over 95% in 10 min even after four successive cycles. This work shows A-boron could be an alternative for the active components of metal or metal oxide in catalytic ozonation.
- Amorphous boron,
- Catalytic ozonation,
- Reactive oxygen species,
- Atrazine,
- Advanced oxidation processes
1. [1]
  A.A. Esquerdo, I.S. Gadea, P.J.V. Galvan, D.P. Rico, Sci. Total. Environ. 764 (2021) 144301. doi: 10.1016/j.scitotenv.2020.144301
2. [2]
  J. Gomes, R. Costa, R.M.Q. Ferreira, R.C. Martins, Sci. Total. Environ. 586 (2017) 265–283. doi: 10.1016/j.scitotenv.2017.01.216
3. [3]
  C.B. Breckenridge, P.S. Coder, M.O. Tisdel, et al., Birth. Defects. Res. B 104 (2015) 204–217. doi: 10.1002/bdrb.21154
4. [4]
  S.A. Abdulelah, K.G. Crile, A. Almouseli, et al., Chemosphere 239 (2020) 124786. doi: 10.1016/j.chemosphere.2019.124786
5. [5]
  A.N. Kabra, M.K. Ji, J. Choi, et al., Environ. Sci. Pollut. Res. Int. 21 (2014) 12270–12278. doi: 10.1007/s11356-014-3157-4
6. [6]
  J. Ge, J. Cong, Y. Sun, et al., Bull. Environ. Contam. Toxicol. 84 (2010) 401–405. doi: 10.1007/s00128-010-9958-3
7. [7]
  A.S. Sousa, W.C. Duavi, R.M. Cavalcante, M.A. Milhome, R.F.D. Nascimento, Bull. Environ. Contam. Toxicol. 96 (2016) 90–95. doi: 10.1007/s00128-015-1686-2
8. [8]
  S. Singh, V. Kumar, A. Chauhan, et al., Environ. Chem. Lett. 16 (2017) 211–237. doi: 10.1504/IJMOR.2017.081926
9. [9]
  J. Lharidon, M. Fernandez, V. Ferrier, J. Bellan, Water Res. 27 (1993) 855–862. doi: 10.1016/0043-1354(93)90150-G
10. [10]
  M.J.M. Bueno, A. Aguera, M.J. Gomez, et al., Anal. Chem. 79 (2007) 9372–9384. doi: 10.1021/ac0715672
11. [11]
  Y. Liu, S. Wang, L. Shi, W. Lu, P. Li, Environ. Sci. Water Res. Technol. 6 (2020) 1681–1687. doi: 10.1039/d0ew00227e
12. [12]
  X. Kong, J. Jiang, J. Ma, et al., Water Res. 90 (2016) 15–23. doi: 10.1504/IJRIS.2016.080059
13. [13]
  Y. Ji, C. Dong, D. Kong, J. Lu, J. Hazard. Mater. 285 (2015) 491–500. doi: 10.1016/j.jhazmat.2014.12.026
14. [14]
  H. Li, B. Zhou, J. Environ. Sci. Heal. B 54 (2019) 432–440. doi: 10.1080/03601234.2019.1574175
15. [15]
  J. Li, Y. Li, Z. Xiong, G. Yao, B. Lai, Chin. Chem. Lett. 30 (2019) 2139–2146. doi: 10.1016/j.cclet.2019.04.057
16. [16]
  J. Wang, Z. Bai, Chem. Eng. J. 312 (2017) 79–98. doi: 10.1504/IJEHV.2017.085336
17. [17]
  J.L. Acero, K. Stemmler, U.V. Gunten, Environ. Sci. Technol. 34 (2000) 591–597. doi: 10.1021/es990724e
18. [18]
  R.H. Huang, J. Liu, L.S. Li, et al., Chin. Chem. Lett. 22 (2011) 683–686. doi: 10.1016/j.cclet.2010.11.037
19. [19]
  Z. Xiong, B. Lai, Y. Yuan, et al., Chem. Eng. J. 302 (2016) 137–145. doi: 10.1016/j.cej.2016.05.052
20. [20]
  S.Q. Tian, J.Y. Qi, Y.P. Wang, et al., Water Res. 193 (2021) 116860. doi: 10.1016/j.watres.2021.116860
21. [21]
  X. Tan, Y. Wan, Y. Huang, et al., J. Hazard. Mater. 321 (2017) 162–172. doi: 10.1016/j.jhazmat.2016.09.013
22. [22]
  T. Shen, Q. Wang, S. Tong, Ind. Eng. Chem. Res. 56 (2017) 10965–10971. doi: 10.1021/acs.iecr.7b02469
23. [23]
  Y. Xie, Y. Liu, Y. Yao, et al., Chin. Chem. Lett. 33 (2022) 1298–1302. doi: 10.1016/j.cclet.2021.07.055
24. [24]
  J. Restivo, C.A. Orge, A.S.G.G. Santos, O.S.G.P. Soares, M.F.R. Pereira, Catal. Today 384 (2022) 187–196.
25. [25]
  J. Wang, S. Chen, X. Quan, H. Yu, Chemosphere 190 (2018) 135–143. doi: 10.1016/j.chemosphere.2017.09.119
26. [26]
  J. Xu, Y. Li, M. Qian, et al., Appl. Catal. B: Environ. 256 (2019) 117797. doi: 10.1016/j.apcatb.2019.117797
27. [27]
  A.S.G.G. Santos, C.A. Orge, O.S.G.P. Soares, M.F.R. Pereira, J. Water Process. Eng. 38 (2020) 101573. doi: 10.1016/j.jwpe.2020.101573
28. [28]
  A.J. Mannix, X.F. Zhou, B. Kiraly, et al., Science 350 (2015) 1513–1516. doi: 10.1126/science.aad1080
29. [29]
  P. Shao, X. Duan, J. Xu, et al., J. Hazard. Mater. 322 (2017) 532–539. doi: 10.1016/j.jhazmat.2016.10.020
30. [30]
  P. Zhou, W. Ren, G. Nie, et al., Angew. Chem. Int. Ed. Engl. 59 (2020) 16517–16526. doi: 10.1002/anie.202007046
31. [31]
  L. Ge, S. Lei, A.H.C. Hart, et al., Nanotechnology 25 (2014) 335701. doi: 10.1088/0957-4484/25/33/335701
32. [32]
  U.V. Gunten, Water Res. 37 (2003) 1443–1467. doi: 10.1016/S0043-1354(02)00457-8
33. [33]
  G. Yu, Y. Wang, H. Cao, H. Zhao, Y. Xie, Environ. Sci. Technol. 54 (2020) 5931–5946. doi: 10.1021/acs.est.0c00575
34. [34]
  X. Luo, T. Su, X. Xie, Z. Qin, H. Ji, Chemistryselect 5 (2020) 15092–15116. doi: 10.1002/slct.202003805
35. [35]
  B. Feng, J. Zhang, Q. Zhong, et al., Nat. Chem. 8 (2016) 564–569. doi: 10.3390/ma9070564
36. [36]
  X.D. Wu, Z.X. Wang, L.Q. Chen, X.J. Huang, Solid State Ionics 170 (2004) 117–121. doi: 10.1016/j.ssi.2004.02.011
37. [37]
  P. Zhou, W. Ren, G. Nie, et al., Angew. Chem. Int. Ed. 59 (2020) 16517–16526. doi: 10.1002/anie.202007046
38. [38]
  P. Wang, S. Orimo, K. Tanabe, H. Fujii, J. Alloys Compd. 350 (2003) 218–221. doi: 10.1016/S0925-8388(02)00927-1
39. [39]
  K.E. Egili, E.F.E. Agammy, M.A. Zaibani, M. Jaremko, A.H. Emwas, Appl. Phys. A 127 (2021) 1–10. doi: 10.1007/s00339-020-04132-x
40. [40]
  G.L. Richmond, Chem. Rev. 102 (2002) 2693–2724. doi: 10.1021/cr0006876
41. [41]
  B. Huang, Z. Xiong, P. Zhou, et al., J. Hazard. Mater. 424 (2022) 127641. doi: 10.1016/j.jhazmat.2021.127641
42. [42]
  Y. Qi, J. Li, Y. Zhang, et al., Appl. Catal. B: Environ. 286 (2021) 119910. doi: 10.1016/j.apcatb.2021.119910
43. [43]
  G. Ye, P. Luo, Y. Zhao, et al., Chemosphere 253 (2020) 126767. doi: 10.1016/j.chemosphere.2020.126767
44. [44]
  G.V. Buxton, C.L. Greenstock, W.P. Helman, A.B. Ross, J. Phys. Chem. Ref. Data 17 (1988) 513–886. doi: 10.1063/1.555805
45. [45]
  F.E. Scully, J. Hoigne, Chemosphere 16 (1987) 681–694. doi: 10.1016/0045-6535(87)90004-X
46. [46]
  Y.M. Dong, G.L. Wang, P.P. Jiang, et al., Chin. Chem. Lett. 22 (2011) 209–212. doi: 10.1016/j.cclet.2010.10.010
47. [47]
  Y. Ren, Q. Dong, J. Feng, et al., J. Colloid Interface Sci. 382 (2012) 90–96. doi: 10.1016/j.jcis.2012.05.053
48. [48]
  W. Li, Z. Qiang, T. Zhang, F. Cao, Appl. Catal. B: Environ. 113 (2012) 290–295.
49. [49]
  S.M. Zhu, B.Z. Dong, Y.H. Yu, et al., Chem. Eng. J. 328 (2017) 527–535. doi: 10.1016/j.cej.2017.07.083
50. [50]
  A. Ranithri, Z. Sitian, W.Z. Yang, L.Y. Chen, LWT-Food. Sci. Technol. 158 (2022) 113162. doi: 10.1016/j.lwt.2022.113162
51. [51]
  M.C. DeRosa, R.J. Crutchley, Coord. Chem. Rev. 233 (2002) 351–371.
52. [52]
  J. Brame, M. Long, Q. Li, P. Alvarez, Water Res. 60 (2014) 259–266. doi: 10.1016/j.watres.2014.05.005
53. [53]
  L. Bu, N. Zhu, C. Li, et al., J. Hazard. Mater. 388 (2020) 121760. doi: 10.1016/j.jhazmat.2019.121760
54. [54]
  T. Zhang, C. Li, J. Ma, H. Tian, Z. Qiang, Appl. Catal. B: Environ. 82 (2008) 131–137. doi: 10.1016/j.apcatb.2008.01.008
55. [55]
  F. Qi, Z. Chen, B. Xu, et al., Appl. Catal. B: Environ. 84 (2008) 684–690. doi: 10.1016/j.apcatb.2008.05.027
56. [56]
  Guidelines for drinking-water quality: Fourth edition incorporating the first and second addenda, https://www.who.int/publications/i/item/9789240045064, June 18, 2022.
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