Citation: Li Han, Zihao Yuan, Xusheng Shao, Xiaoyong Xu, Zhong Li. Synthesis, insecticidal activity and stability study of novel nitromethylene neonicotinoids with five-membered aromatic heterocycles[J]. Chinese Chemical Letters, ;2023, 34(6): 107868. doi: 10.1016/j.cclet.2022.107868 shu

Synthesis, insecticidal activity and stability study of novel nitromethylene neonicotinoids with five-membered aromatic heterocycles

Li Han ^a ,
Zihao Yuan ^a ,
Xusheng Shao ^a ,
Xiaoyong Xu ^a ,
Zhong Li ^{a, b, *,}

a.
Shanghai Key Laboratory of Chemical Biology, School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China
b.
Shanghai Collaborative Innovation Center for Biomanufacturing Technology, Shanghai 200237, China

lizhong@ecust.edu.cn

Received Date: 7 July 2022
Revised Date: 23 September 2022
Accepted Date: 28 September 2022
Available Online: 1 October 2022

Figures(6)

Twenty-four novel neonicotinoid analogues with nitromethylene and five-membered aromatic heterocycles were designed and synthesized. All target molecular structures have been confirmed by analytical and spectral data. Some compounds exhibited notable insecticidal activities against aphid (Aphis medicaginis) and brown planthopper (Nilaparvata lugens). The aqueous stability test confirmed that the stabilities of those compounds were superior to the leading compound, and the photostability was even better than that of imidacloprid.
- Nitromethylene,
- Neonicotinoids,
- Selective reduction,
- Stability,
- Insecticidal activity
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沈阳化工大学材料科学与工程学院沈阳 110142