Citation: Ao Yu, Wangtao Long, Longtao Zhu, Yinan Zhao, Ping Peng, Fang-Fang Li. Transformation of postsynthesized F-MOF to Fe/N/F-tridoped carbon nanotubes as oxygen reduction catalysts for high power density Zn-air batteries[J]. Chinese Chemical Letters, ;2023, 34(5): 107860. doi: 10.1016/j.cclet.2022.107860 shu

Transformation of postsynthesized F-MOF to Fe/N/F-tridoped carbon nanotubes as oxygen reduction catalysts for high power density Zn-air batteries

State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

ppeng@hust.edu.cn

ffli@hust.edu.cn

Received Date: 10 July 2022
Revised Date: 11 August 2022
Accepted Date: 26 September 2022
Available Online: 29 September 2022

Figures(5)

The oxygen reduction reaction (ORR), an important process in Zn-air batteries (ZABs), shows sluggish reaction kinetics, which significantly impairs the further improvement of battery performance. Thus, rationally designing cathodic catalysts for ZABs has drawn sufficient attention. We herein synthesize and characterize Fe/N/F-tridoped CNTs (FeNFCs) by annealing the postsynthesized trifluoroacetic anhydride-modified Fe-MIL-88B-NH₂ nanocrystals with melamine at high temperature in a N₂ atmosphere. Benefiting from the Fe/N/F element doping, high specific surface area, and CNT structure, the FeNFC800 catalyst prepared at 800 ℃ exhibits a preferable half-wave potential of 0.829 V vs. RHE. The Zn-air battery equipped with FeNFC800 shows a high open-circuit voltage of 1.47 V, a gratifying peak power density of 196 mW/cm², and extraordinary long-term stability, outperforming the benchmark 20% Pt/C.
- Self-catalyzed process,
- Fe/N/F-tridoped carbon nanotube,
- Electrocatalyst,
- Oxygen reduction reaction,
- Zn-air battery
1. [1]
  X. Zheng, N. Mohammadi, A.M. Zuria, M. Mohamedi, ACS Appl. Mater. Interfaces 13 (2021) 61374–61385. doi: 10.1021/acsami.1c22371
2. [2]
  Z. Wang, J. Ang, J. Liu, et al., Appl. Catal. B 263 (2020) 118344. doi: 10.1016/j.apcatb.2019.118344
3. [3]
  S. Zhao, L. Ban, J. Zhang, et al., Chem. Eng. J. 409 (2021) 128171. doi: 10.1016/j.cej.2020.128171
4. [4]
  F. Fan, H. Zhou, R. Yan, et al., ACS Appl. Mater. Interfaces 13 (2021) 41609–41618. doi: 10.1021/acsami.1c10510
5. [5]
  V. Jose, J.M.V. Nsanzimana, H. Hu, et al., Adv. Energy Mater. 11 (2021) 2100157. doi: 10.1002/aenm.202100157
6. [6]
  P. Wei, X. Li, Z. He, et al., Chem. Eng. J. 422 (2021) 130134. doi: 10.1016/j.cej.2021.130134
7. [7]
  L. Jiang, B. van Dijk, L. Wu, et al., ACS Catal. (2021) 173–182.
8. [8]
  S. Bhattacharyya, B. Konkena, K. Jayaramulu, W. Schuhmann, T.K. Maji, J. Mater. Chem. A 5 (2017) 13573–13580. doi: 10.1039/C7TA00281E
9. [9]
  X. Zhang, S. Yao, P. Chen, et al., J. Catal. 389 (2020) 677–689. doi: 10.1016/j.jcat.2020.07.003
10. [10]
  K. Meng, Q. Liu, Y. Huang, Y. Wang, J. Mater. Chem. A 3 (2015) 6873–6877. doi: 10.1039/C4TA06500J
11. [11]
  X. Feng, Y. Bai, M. Liu, et al., Energy Environ. Sci. 14 (2021) 2036–2089. doi: 10.1039/d1ee00166c
12. [12]
  R.A. Nistor, D.M. Newns, G.J. Martyna, ACS Nano 5 (2011) 3096–3103. doi: 10.1021/nn200225f
13. [13]
  D.S. Su, J. Zhang, B. Frank, et al., ChemSusChem 3 (2010) 169–180. doi: 10.1002/cssc.200900180
14. [14]
  L. Zhao, R. He, K.T. Rim, et al., Science 333 (2011) 999–1003. doi: 10.1126/science.1208759
15. [15]
  D. Guo, R. Shibuya, C. Akiba, et al., Science 351 (2016) 361–365. doi: 10.1126/science.aad0832
16. [16]
  D. Gu, Y. Zhou, R. Ma, et al., Nano-Micro Lett. 10 (2017) 29.
17. [17]
  R. Xing, T. Zhou, Y. Zhou, et al., Nano-Micro Lett. 10 (2017) 3. doi: 10.7844/kirr.2017.26.1.3
18. [18]
  H. Wu, P.H.L. Sit, Comput. Theor. Chem. 1201 (2021) 113292. doi: 10.1016/j.comptc.2021.113292
19. [19]
  T. Gong, R. Qi, X. Liu, H. Li, Y. Zhang, Nano-Micro Lett. 11 (2019) 9. doi: 10.1007/s40820-019-0240-x
20. [20]
  G. Panomsuwan, N. Saito, T. Ishizaki, J. Mater. Chem. A 3 (2015) 9972–9981. doi: 10.1039/C5TA00244C
21. [21]
  H. Zhou, Y. Peng, H.B. Wu, et al., Nano Energy 21 (2016) 80–89. doi: 10.1016/j.nanoen.2015.12.016
22. [22]
  H.J. Zhang, X. Zhang, S. Yao, et al., J. Electrochem. Soc. 164 (2017) H1081–H1085. doi: 10.1149/2.0901714jes
23. [23]
  M. Wu, Y. Wang, Z. Wei, et al., J. Mater. Chem. A 6 (2018) 10918–10925. doi: 10.1039/C8TA02416B
24. [24]
  Y. Zhao, Y. Liu, Y. Chen, et al., J. Mater. Chem. A 9 (2021) 18251–18259. doi: 10.1039/d1ta05485f
25. [25]
  M. Zhou, H.L. Wang, S. Guo, Chem. Soc. Rev. 45 (2016) 1273–1307. doi: 10.1039/C5CS00414D
26. [26]
  H. Jiang, Y. Yao, Y. Zhu, et al., ACS Appl. Mater. Interfaces 7 (2015) 21511–21520. doi: 10.1021/acsami.5b06708
27. [27]
  A. Kong, X. Zhu, Z. Han, et al., ACS Catal. 4 (2014) 1793–1800. doi: 10.1021/cs401257j
28. [28]
  X. Cui, L. Gao, S. Lei, et al., Adv. Funct. Mater. 31 (2021) 2170064. doi: 10.1002/adfm.202170064
29. [29]
  C. Li, Q. Hu, Y. Li, et al., Sci. Rep. 6 (2016) 25556. doi: 10.1038/srep25556
30. [30]
  Y. Zhang, R. Jiang, Z. Wang, et al., J. Colloid Interface Sci. 579 (2020) 391–400. doi: 10.1016/j.jcis.2020.06.057
31. [31]
  J.C. Li, P.X. Hou, C. Liu, Small 13 (2017) 1702002. doi: 10.1002/smll.201702002
32. [32]
  Q. Chen, S. Chen, L. Zhao, et al., Chem. Eng. J. 431 (2022) 133961. doi: 10.1016/j.cej.2021.133961
33. [33]
  M. Liu, Y. He, J. Zhang, Mater. Chem. Front. 5 (2021) 6559–6567. doi: 10.1039/d1qm00707f
34. [34]
  L. Song, T. Wang, Y. Wang, et al., ACS Appl. Mater. Interfaces 9 (2017) 3713–3722. doi: 10.1021/acsami.6b14754
35. [35]
  Y. Ou, L. Yao, Y. Li, et al., J. Colloid Interface Sci. 570 (2020) 163–172. doi: 10.1016/j.jcis.2020.02.116
36. [36]
  A. Liu, M. Ma, X. Zhang, et al., J. Electroanal. Chem. 824 (2018) 60–66. doi: 10.1016/j.jelechem.2018.07.039
37. [37]
  K. Niu, M. Li, X. Chen, et al., Int. J. Electrochem. Sci. 16 (2021) 210762.
38. [38]
  Z. He, J.L. Maurice, A. Gohier, et al., Chem. Mater. 23 (2011) 5379–5387. doi: 10.1021/cm202315j
39. [39]
  J. Meng, C. Niu, L. Xu, et al., J. Am. Chem. Soc. 139 (2017) 8212–8221. doi: 10.1021/jacs.7b01942
40. [40]
  A.J. Page, Y. Ohta, S. Irle, K. Morokuma, Acc. Chem. Res. 43 (2010) 1375–1385. doi: 10.1021/ar100064g
41. [41]
  S. Hofmann, R. Sharma, C. Ducati, et al., Nano Lett. 7 (2007) 602–608. doi: 10.1021/nl0624824
42. [42]
  A. Yu, G. Ma, L. Zhu, et al., Nanoscale 13 (2021) 15973–15980. doi: 10.1039/d1nr04176b
43. [43]
  A. Yu, G. Ma, L. Zhu, et al., Appl. Catal. B 307 (2022) 121161. doi: 10.1016/j.apcatb.2022.121161
44. [44]
  A. Yu, G. Ma, J. Jiang, et al., Chem. Eur. J. 27 (2021) 10405–10412. doi: 10.1002/chem.202100998
45. [45]
  S. Shang, C. Guo, K. Lan, et al., BioRes. 15 (2020) 4294–4313. doi: 10.15376/biores.15.2.4294-4313
46. [46]
  Y. Mi, L. Wen, Z. Wang, et al., Nano Energy 30 (2016) 109–117. doi: 10.1016/j.nanoen.2016.10.001
47. [47]
  J.S. Li, S.L. Li, Y.J. Tang, et al., Chem. Commun. 51 (2015) 2710–2713. doi: 10.1039/C4CC09062D
48. [48]
  W. Sun, A.S. Saleemi, Z. Luo, et al., J. Appl. Phys. 122 (2017) 165101. doi: 10.1063/1.4998996
49. [49]
  H. Zhu, Z. Zhu, J. Hao, et al., Chem. Eng. J. (2021) 133251.
50. [50]
  J.R. Pels, F. Kapteijn, J.A. Moulijn, Q. Zhu, K.M. Thomas, Carbon 33 (1995) 1641–1653. doi: 10.1016/0008-6223(95)00154-6
51. [51]
  X. Cui, Z. Pan, L. Zhang, H. Peng, G. Zheng, Adv. Energy Mater. 7 (2017) 1701456. doi: 10.1002/aenm.201701456
52. [52]
  R. Liu, H. Zhang, X. Zhang, et al., RSC Adv. 7 (2017) 19181–19188. doi: 10.1039/C7RA01798G
53. [53]
  M. Sun, X. Wu, X. Deng, et al., Mater. Lett. 220 (2018) 313–316. doi: 10.1016/j.matlet.2018.03.050
54. [54]
  J. Zhang, Q. Li, H. Wu, et al., J. Mater. Chem. A 3 (2015) 10851–10857. doi: 10.1039/C5TA00547G
55. [55]
  I. Palchan, M. Crespin, H. Estrade-Szwarckopf, B. Rousseau, Chem. Phys. Lett. 157 (1989) 321–327. doi: 10.1016/0009-2614(89)87255-0
56. [56]
  S. Jiang, Y. Sun, H. Dai, et al., Nanoscale 7 (2015) 10584–10589. doi: 10.1039/C5NR01793A
57. [57]
  S.K. Singh, K. Takeyasu, J. Nakamura, Adv. Mater. 31 (2019) 1804297. doi: 10.1002/adma.201804297
58. [58]
  W.J. Jiang, L. Gu, L. Li, et al., J. Am. Chem. Soc. 138 (2016) 3570–3578. doi: 10.1021/jacs.6b00757
59. [59]
  K. Gong, F. Du, Z. Xia, M. Durstock, L. Dai, Science 323 (2009) 760–764. doi: 10.1126/science.1168049
60. [60]
  Z. Li, Z. Gong, X. Wu, et al., Chin. Chem. Lett. 33 (2022) 3936–3940. doi: 10.1016/j.cclet.2021.11.015
61. [61]
  K. Wu, F. Ning, J. Yi, et al., J. Energy Chem. 69 (2022) 237–243. doi: 10.1016/j.jechem.2022.01.037
62. [62]
  X. Liu, Y. Fang, P. Liang, et al., Chin. Chem. Lett. 32 (2021) 2899–2903. doi: 10.1016/j.cclet.2021.02.055
63. [63]
  X. Deng, S. Imhanria, Y. Sun, et al., J. Environ. Chem. Eng. 10 (2022) 108052. doi: 10.1016/j.jece.2022.108052
64. [64]
  C. Han, X. Zhang, Q. Sun, et al., Inorg. Chem. Front. 9 (2022) 2557–2567. doi: 10.1039/d2qi00394e
65. [65]
  C. Li, Y. Wu, M. Fu, et al., ACS Appl. Energy Mater. 5 (2022) 4340–4350. doi: 10.1021/acsaem.1c03956
66. [66]
  Q. Li, T. Zhao, C. He, et al., Electrochim. Acta 410 (2022) 139975. doi: 10.1016/j.electacta.2022.139975
67. [67]
  K. Qin, Z. Zhu, F.X. Ma, J. Zhang, J. Electroanal. Chem. 906 (2022) 116021. doi: 10.1016/j.jelechem.2022.116021
68. [68]
  Q. Sun, K. Zhu, X. Ji, et al., Sci. China Mater. 65 (2022) 1453–1462. doi: 10.1007/s40843-021-1933-4
69. [69]
  B. Wang, J. Tang, X. Zhang, et al., Chem. Eng. J. 437 (2022) 135295. doi: 10.1016/j.cej.2022.135295
70. [70]
  H. Wang, S. Su, T. Yu, et al., Appl. Surf. Sci. 596 (2022) 153522. doi: 10.1016/j.apsusc.2022.153522
71. [71]
  L. Wang, S.Q. Guo, Z. Hu, B. Shen, W. Zhou, ChemCatChem 14 (2022) e202200063.
72. [72]
  S. Wu, D. Deng, E. Zhang, H. Li, L. Xu, Carbon 196 (2022) 347–353. doi: 10.1016/j.carbon.2022.04.043
73. [73]
  Y. Xie, S.J. Li, J.P. Huang, et al., J. Alloys Compd. (2022) 166076.
74. [74]
  J. Zhang, Y. Chen, Y. Liu, X. Liu, S. Gao, Sci. China Mater. 65 (2022) 653–662. doi: 10.1007/s40843-021-1775-2
75. [75]
  X. Zhang, J. Wang, C. Dai, et al., J. Power Sources 538 (2022) 231563. doi: 10.1016/j.jpowsour.2022.231563
76. [76]
  X. Zhang, J. Xu, L. Wu, Mater. Today Sustain. (2022) 100180.
77. [77]
  K. Chen, S. Ci, Q. Xu, et al., Chin. J. Catal. 41 (2020) 858–867. doi: 10.1016/S1872-2067(19)63507-2
78. [78]
  S.J. Li, Y. Xie, B.L. Lai, et al., Chin. J. Catal. 43 (2022) 1502–1510. doi: 10.1016/S1872-2067(21)63932-3
79. [79]
  Y.R. Lv, X.J. Zhai, S. Wang, et al., Chin. J. Catal. 42 (2021) 490–500. doi: 10.1016/S1872-2067(20)63667-1
80. [80]
  F. Shi, X. Zhu, W. Yang, Chin. J. Catal. 41 (2020) 390–403. doi: 10.1016/S1872-2067(19)63514-X
81. [81]
  H.L. Wei, A.D. Tan, S.Z. Hu, J.H. Piao, Z.Y. Fu, Chin. J. Catal. 42 (2021) 1451–1458. doi: 10.1016/S1872-2067(20)63752-4
82. [82]
  L. Zong, X. Chen, S. Dou, et al., Chin. Chem. Lett. 32 (2021) 1121–1126. doi: 10.1016/j.cclet.2020.08.029
83. [83]
  X. Deng, Z. Jiang, Y. Chen, et al., Chin. Chem. Lett. 34 (2023) 107389. doi: 10.1016/j.cclet.2022.03.112
84. [84]
  Y. Jia, F. Zhang, Q. Liu, et al., Chin. Chem. Lett. 33 (2022) 1070–1073. doi: 10.1016/j.cclet.2021.05.052
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