Citation: Pin Hao, Xu Dong, Houguang Wen, Ruirui Xu, Junfeng Xie, Qian Wang, Guanwei Cui, Jian Tian, Bo Tang. In-situ assembly of 2D/3D porous nickel cobalt sulfide solid solution as superior pre-catalysts to boost multi-functional electrocatalytic oxidation[J]. Chinese Chemical Letters, ;2023, 34(5): 107843. doi: 10.1016/j.cclet.2022.107843 shu

In-situ assembly of 2D/3D porous nickel cobalt sulfide solid solution as superior pre-catalysts to boost multi-functional electrocatalytic oxidation

Pin Hao ^{a, 1, *,} ,
Xu Dong ^{a, 1} ,
Houguang Wen ^a ,
Ruirui Xu ^a ,
Junfeng Xie ^a ,
Qian Wang ^a ,
Guanwei Cui ^a ,
Jian Tian ^{b, *,} ,
Bo Tang ^a

a.
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Ji'nan 250014, China
b.
School of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China

haopin@sdnu.edu.cn

jiantian@sdust.edu.cn

Received Date: 14 June 2022
Revised Date: 4 September 2022
Accepted Date: 21 September 2022
Available Online: 24 September 2022

Figures(4)

In this work, we fabricated an efficient pre-catalyst based on (Ni, Co)S₂ solid solution with hierarchical architecture and high porosity to boost urea oxidation reaction and electrocatalytic oxidation of organic small molecules. The interaction between Ni and Co can optimize the electronic structure, resulting in the improved conductivity and accelerated charge transfer rate. The 2D/3D architecture can enrich more active species and endow the mass and electron transport to facilitate the surface oxidation and the following catalytic process. Post-structure and catalytic characterizations confirm the surface oxidation of (Ni, Co)S₂ during the stability test, and the in-situ formed Co(Ni) based (oxy)hydroxides exhibit superior catalytic activity and facilitated charge transfer ability. As a result, the optimal (Ni, Co)S₂ solid solution pre-catalyst displays facilitated catalytic behavior and good stability for multifunctional electrocatalytic oxidation, in which a high conversion of benzyl alcohol (97.50%), a good selectivity to benzoic acid (93.78%) and a satisfied faraday efficiency (91.86%) can be achieved.
- Electrocatalytic oxidation,
- (Ni, Co)S₂ solid solution,
- Pre-catalyst,
- Urea oxidation reaction,
- 2D/3D architecture
1. [1]
  X. Wang, L. Yu, B.Y. Guan, S. Song, X.W. Lou, Adv. Mater. 30 (2018) 1801211. doi: 10.1002/adma.201801211
2. [2]
  L. Wang, Y. Zhu, Y. Wen, et al., Angew. Chem. Int. Ed. 60 (2021) 10577–10582. doi: 10.1002/anie.202100610
3. [3]
  P. Hao, W. Zhu, L. Li, et al., Electrochim. Acta 338 (2020) 135883. doi: 10.1016/j.electacta.2020.135883
4. [4]
  Z. Li, J. Zhang, X. Jing, et al., J. Mater. Chem. A 9 (2021) 6152–6159. doi: 10.1039/D0TA09421H
5. [5]
  X. Chen, X. Zhong, B. Yuan, et al., Green Chem. 21 (2019) 578–588. doi: 10.1039/C8GC03451F
6. [6]
  M. Zhou, Q. Weng, X. Zhang, et al., J. Mater. Chem. A 5 (2017) 4335–4342. doi: 10.1039/C6TA09366C
7. [7]
  A. Haeussler, S. Abanades, J. Jouannaux, et al., AIMS Mater. Sci. 6 (2019) 657–684. doi: 10.3934/matersci.2019.5.657
8. [8]
  Z. Ji, Y. Song, S. Zhao, et al., ACS Catal. 12 (2022) 569–579. doi: 10.1021/acscatal.1c05190
9. [9]
  P. Hao, Y. Xin, J. Tian, et al., Sci. Chin. Chem. 63 (2020) 1030–1039. doi: 10.1007/s11426-020-9770-5
10. [10]
  P. Hao, W. Zhu, L. Li, et al., Chem. Commun. 55 (2019) 10138–10141. doi: 10.1039/C9CC05115E
11. [11]
  K. Rui, G. Zhao, Y. Chen, et al., Adv. Funct. Mater. 28 (2018) 1801554. doi: 10.1002/adfm.201801554
12. [12]
  P. Hao, H. Wen, Q. Wang, et al., J. Mater. Chem. A 9 (2021) 8576–8585. doi: 10.1039/D1TA00043H
13. [13]
  H. Tan, Z. Liu, D. Chao, et al., Adv. Energy Mater. 8 (2018) 1800685. doi: 10.1002/aenm.201800685
14. [14]
  Y. Lu, D. Fan, Z. Chen, et al., Sci. Bull. 65 (2020) 460–466. doi: 10.1016/j.scib.2019.12.020
15. [15]
  F. Li, P. Wang, X. Huang, et al., Angew. Chem. Int. Ed. 58 (2019) 7051–7056. doi: 10.1002/anie.201902588
16. [16]
  Q. Zhang, F.M. Kazim, S. Ma, et al., Appl. Catal. B 280 (2021) 119436. doi: 10.1016/j.apcatb.2020.119436
17. [17]
  Z. Cao, T. Zhou, X. Ma, et al., ACS Sustain. Chem. Eng. 8 (2020) 11007–11015.
18. [18]
  H. Liu, S. Zhu, Z. Cui, et al., Nanoscale 13 (2021) 1759–1769. doi: 10.1039/D0NR08025J
19. [19]
  Q. Li, N. Li, J. An, H. Pang, Inorg. Chem. Front. 7 (2020) 2089–2096. doi: 10.1039/D0QI00316F
20. [20]
  W. Han, X. Li, L. Lu, et al., Chem. Commun. 56 (2020) 11038–11041. doi: 10.1039/D0CC03177A
21. [21]
  M. Yuan, X. Guo, N. Li, H. Pang, J. Colloid Interface Sci. 589 (2021) 56–64. doi: 10.1016/j.jcis.2020.12.100
22. [22]
  N. Chen, Y. Du, G. Zhang, W. Lu, F. Cao, Nano Energy 81 (2021) 105605. doi: 10.1016/j.nanoen.2020.105605
1. [1]
  Robab Abbasi , Khalil Farhadi , Sepideh Banisaeid , Nader Nowroozi Pesyan , Arezu Jamali , Fatemeh Rahmani . Electrosynthesized polytyramine-copper oxalate nanocomposite on copper electrode for electrocatalytic oxidation of methanol in alkaline medium. Chinese Journal of Catalysis, 2014, 35(7): 1098-1104. doi: 10.1016/S1872-2067(14)60049-8
2. [2]
  Seyed Naser Azizi , Shahram Ghasemi , Neda Salek Gilani . An electrode with Ni(Ⅱ) loaded analcime zeolite catalyst for the electrooxidation of methanol. Chinese Journal of Catalysis, 2014, 35(3): 383-390. doi: 10.1016/S1872-2067(14)60002-4
3. [3]
  Zepeng Zhang , Yunyun Li , Longzhang Dong , Zhonglong Yin , Ziqi Tian , Weiben Yang , Zhen Yang . MIL-101(Cr)-decorated Ti/TiO₂ anode for electrochemical oxidation of aromatic pollutants from water. Chinese Chemical Letters, 2023, 34(2): 107404-1-107404-5. doi: 10.1016/j.cclet.2022.04.002
4. [4]
  Zhu Meng , Zhang Longshuai , Liu Shanshan , Wang Dengke , Qin Yuancheng , Chen Ying , Dai Weili , Wang Yuehua , Xing Qiuju , Zou Jianping . Degradation of 4-nitrophenol by electrocatalysis and advanced oxidation processes using Co₃O₄@C anode coupled with simultaneous CO₂ reduction via SnO₂/CC cathode. Chinese Chemical Letters, 2020, 31(7): 1961-1965. doi: 10.1016/j.cclet.2020.01.017
5. [5]
  Yan Yang , Bowen He , Hualong Ma , Sen Yang , Zhouhong Ren , Tian Qin , Fagui Lu , Liwen Ren , Yixiao Zhang , Tianfu Wang , Xi Liu , Liwei Chen . PtRuAgCoNi High-Entropy Alloy Nanoparticles for High-Efficiency Electrocatalytic Oxidation of 5-Hydroxymethylfurfural. Acta Physico-Chimica Sinica, 2022, 38(12): 2201050-0. doi: 10.3866/PKU.WHXB202201050
6. [6]
  Zhang Hongmin , He Jie , Zhai Chunyang , Zhu Mingshan . 2D Bi₂WO₆/MoS₂ as a new photo-activated carrier for boosting electrocatalytic methanol oxidation with visible light illumination. Chinese Chemical Letters, 2019, 30(12): 2338-2342. doi: 10.1016/j.cclet.2019.07.021
7. [7]
  NIE Su-Lian , ZHAO Yan-Chun , FAN Jie-Wen , TIAN Jian-Niao , NING Zhen , LI Xiao-Xiao . Highly Active Pd-Co₃O₄/MWCNTs Catalysts for Methanol Electrocatalytic Oxidation. Acta Physico-Chimica Sinica, 2012, 28(04): 871-876. doi: 10.3866/PKU.WHXB201202013
8. [8]
  HE Quan-Guo , LIANG Jing , LI Guang-Li , DENG Pei-Hong , LIU Jun , LIU Xiao-Peng . Electrochemical Detection of Dopamine Based on MnO₂ Nanowires/Reduced Graphene Oxide Composites Modified Glassy Carbon Electrode. Chinese Journal of Analytical Chemistry, 2018, 46(3): 438-445. doi: 10.11895/j.issn.0253-3820.171183
9. [9]
  Jin Ma , Bin Liu , Rongyue Wang , Zhiyao Sun , Ying Zhang , Yubo Sun , Zhuang Cai , Yao Li , Jinlong Zou . Single-Cu-atoms anchored on 3D macro-porous carbon matrix as efficient catalyst for oxygen reduction and Pt co-catalyst for methanol oxidation. Chinese Chemical Letters, 2022, 33(5): 2585-2589. doi: 10.1016/j.cclet.2021.09.108
10. [10]
  Lingshuang Qin , Wei Zhang , Rui Cao . Hydrophilic MnO2 Nanowires Coating with o-Fluoroaniline for Electrocatalytic Water Oxidation. Chinese Journal of Structural Chemistry, 2023, 42(8): 100105-100105. doi: 10.1016/j.cjsc.2023.100105
11. [11]
  Wei-Juan Chen , Tian-Yu Zhang , Xue-Qian Wu , Yong-Shuang Li , Yunling Liu , Ya-Pan Wu , Zhao-Bo He , Dong-Sheng Li . A 3D Ni8-cluster-based MOF as a molecular electrocatalyst for alcohol oxidation in alkaline media. Chinese Journal of Structural Chemistry, 2023, 42(2): 100018-100018. doi: 10.1016/j.cjsc.2023.100018
12. [12]
  Yi Zhang , Chundong Wang . Yolk-shell nanostructural Ni₂P/C composites as the high performance electrocatalysts toward urea oxidation. Chinese Chemical Letters, 2021, 32(7): 2222-2228. doi: 10.1016/j.cclet.2020.11.040
13. [13]
  Taei Masoumeh , Hasanpour Foroozan , Dinari Mohammad , Sohrabi Nasrin , Sadegh Jamshidi Mohammad . Synthesis of 5-[(2-hydroxynaphthalen-1-yl) diazenyl]isophthalic acid and its application to electrocatalytic oxidation and determination of adrenaline, paracetamol, and tryptophan. Chinese Chemical Letters, 2017, 28(2): 240-247. doi: 10.1016/j.cclet.2016.07.025
14. [14]
  ZHOU Jie , JIANG Bo , LIU Sai , MA Chun , HU Jin-Song . A Novel 2D→3D Network with the Coexistence of Polythreading and Inclined Polycatenation Constructed by the Tripodal Linker. Chinese Journal of Structural Chemistry, 2015, 34(4): 536-542. doi: 10.14102/j.cnki.0254-5861.2011-0591
15. [15]
  JIN Hao , HUA Shu-Gui , FENG Ming-Bao , CHEN Lei . QSAR Modeling of Toxicity of Quaternary Ammonium Compounds to Chlorella pyrenoidosa Using 2D and 3D Descriptors. Chinese Journal of Structural Chemistry, 2015, 34(12): 1793-1802. doi: 10.14102/j.cnki.0254-5861.2011-0907
16. [16]
  QIN Ye-Yan , ZHANG Xin , SHEN Yi-Cheng , YAO Yuan-Gen . A Novel Luminescent Zinc(II) Coordination Polymer with 2D→3D Polythreaded Motif. Chinese Journal of Structural Chemistry, 2015, 34(9): 1399-1404. doi: 10.14102/j.cnki.0254-5861.2011-0687
17. [17]
  Yanshuo Li , Weishen Yang . Molecular sieve membranes: From 3D zeolites to 2D MOFs. Chinese Journal of Catalysis, 2015, 36(5): 692-697. doi: 10.1016/S1872-2067(15)60838-5
18. [18]
  Li Yunong , Wang Lei , Low Jingxiang , Wu Di , Hu Canyu , Jiang Wenbin , Ma Jun , Wang Chengming , Long Ran , Song Li , Xu Hangxun , Xiong Yujie . Integrating bimetallic AuPd nanocatalysts with a 2D aza-fused π-conjugated microporous polymer for light-driven benzyl alcohol oxidation. Chinese Chemical Letters, 2020, 31(1): 231-234. doi: 10.1016/j.cclet.2019.04.022
19. [19]
  Lu LIU , Ping-Ning JIN , Jie YANG , Li-Xing SONG , Bo ZHAO , Jin-Ke LI , Bin HUANG , Yu-Ping ZHANG , Xiao-Xun YANG . Structure and Fluorescence Properties of Three 1D/2D/3D Zn(Ⅱ)/Co(Ⅱ) Complexes Based on Flexible Tetracarboxylic Acid. Chinese Journal of Inorganic Chemistry, 2021, 37(5): 921-928. doi: 10.11862/CJIC.2021.101
20. [20]
  Rong Hu , Liyun Wei , Jinglin Xian , Guangyu Fang , Zhiao Wu , Miao Fan , Jiayue Guo , Qingxiang Li , Kaisi Liu , Huiyu Jiang , Weilin Xu , Jun Wan , Yonggang Yao . Microwave Shock Process for Rapid Synthesis of 2D Porous La_0.2Sr_0.8CoO₃ Perovskite as an Efficient Oxygen Evolution Reaction Catalyst. Acta Physico-Chimica Sinica, 2023, 39(9): 2212025-0. doi: 10.3866/PKU.WHXB202212025

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(88)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142