Citation: Jin Wang, Zhaoyang Li, Shengxin Bai, Qinghua Zhou, Tengteng Wu, Zhongyan Hu, Xianxiu Xu. [4 + 3] Cycloaddition of ketenimines with furocarbenoids: Divergent and efficient synthesis of fused cycloheptatriene and tropone scaffolds[J]. Chinese Chemical Letters, ;2023, 34(5): 107823. doi: 10.1016/j.cclet.2022.107823 shu

[4 + 3] Cycloaddition of ketenimines with furocarbenoids: Divergent and efficient synthesis of fused cycloheptatriene and tropone scaffolds

Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, College of Chemistry, Ministry of Education, Institute of Molecular and Nano Science, Shandong Normal University, Ji'nan 250014, China

huzy@sdnu.edu.cn

xuxx677@sdnu.edu.cn

Received Date: 12 June 2022
Revised Date: 8 September 2022
Accepted Date: 13 September 2022
Available Online: 15 September 2022

Figures(8)

An unprecedent [4 + 3] cycloaddition of furoketenimines with furocarbenoids has been disclosed for the divergent and efficient synthesis of cycloheptafuran and cycloheptapyrrole scaffolds. Zinc chloride acted as promoters for both the formation of these two transient intermediates from isocyanides and ene-yne-ketones, and the subsequent construction of seven-membered ring. Three rings and five bonds were constructed successively in this three-component one-pot domino reaction.
- Domino reactions,
- Isocyanides,
- Ene-yne-ketones,
- Cycloheptafuran scaffolds,
- [4+3] cycloaddition
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