Citation: Yang Luo, Wei Zhang, Jie Zhao, Mao-Xia Yang, Qian Ren, Carl Redshaw, Zhu Tao, Xin Xiao. A novel pillar[5]arene-cucurbit[10]uril based host-guest complex: Synthesis, characterization and detection of paraquat[J]. Chinese Chemical Letters, ;2023, 34(3): 107780. doi: 10.1016/j.cclet.2022.107780 shu

A novel pillar[5]arene-cucurbit[10]uril based host-guest complex: Synthesis, characterization and detection of paraquat

Yang Luo ^a ,
Wei Zhang ^a ,
Jie Zhao ^a ,
Mao-Xia Yang ^a ,
Qian Ren ^a ,
Carl Redshaw ^b ,
Zhu Tao ^a ,
Xin Xiao ^{a, *,}

a.
Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Institute of Applied Chemistry, Guizhou University, Guiyang 550025, China
b.
Department of Chemistry, University of Hull, Hull HU6 7RX, United Kingdom

gyhxxiaoxin@163.com

Received Date: 26 May 2022
Revised Date: 19 August 2022
Accepted Date: 23 August 2022
Available Online: 25 August 2022

Figures(6)

The macrocyclic family comprising pillar[n]arenes and cucurbit[n]urils have received much attention recently. However, studies on the construction of supramolecular complexes formed directly with derivatized pillar[n]arenes and cucurbit[n]urils are scant. Given the interest in such systems, herein we have synthesized a new type of naphthalene-derivatized pillar[n]arene NTP5 and selected Q[10] as the host molecule. The 4-[2-(1-naphthalenyl)ethenyl]pyridine of NTP5 is encapsulated by Q[10] and formed a host-guest complex in water-acetic acid (1:1) solution accompanied by enhanced fluorescence, which changed the morphology of NTP5 from a sphere to a porous form. In addition, the fluorescence of Q[10]-NTP5 can be quenched by the addition of the highly toxic pesticide paraquat (PQ), and the mechanism was shown to be the formation of a new charge transfer ternary system of Q[10]-NTP5-PQ. This work provides new ideas for the contribution of supramolecular assemblies based on derivatized pillar[n]arenes and their combination with cucurbit[n]urils and reveals their potential applications.
- Pillar[n]arene,
- Cucurbit[n]uril,
- Paraquat,
- Supramolecular assembly,
- Detection
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