Citation: Kaiyue Zhang, Feng Chu, Yezi Hu, Xiubing Huang, Guixia Zhao, Ge Wang. Ce-doped MIL-125-NH₂ coupled Ce⁴⁺/Ce³⁺ and Ti⁴⁺/Ti³⁺ redox mediators for thermo-enhanced photocatalytic oxidative desulfurization[J]. Chinese Chemical Letters, ;2023, 34(5): 107766. doi: 10.1016/j.cclet.2022.107766 shu

Ce-doped MIL-125-NH₂ coupled Ce⁴⁺/Ce³⁺ and Ti⁴⁺/Ti³⁺ redox mediators for thermo-enhanced photocatalytic oxidative desulfurization

Kaiyue Zhang ^a ,
Feng Chu ^a ,
Yezi Hu ^b ,
Xiubing Huang ^{a, *,} ,
Guixia Zhao ^{b, *,} ,
Ge Wang ^{a, *,}

a.
Beijing Key Laboratory of Function Materials for Molecule & Structure Construction, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
b.
College of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, China

xiubinghuang@ustb.edu.cn

guixiazhao@ncepu.edu.cn

gewang@ustb.edu.cn

Received Date: 10 May 2022
Revised Date: 10 August 2022
Accepted Date: 20 August 2022
Available Online: 22 August 2022

Figures(5)

Photocatalytic oxidative desulfurization (PODS) over efficient earth-abundant catalysts to obtain clean fuel oil is of great importance for the environmental protection. In this work, a series of Ce-doped MIL-125-NH₂ photocatalysts were successfully prepared via a simple in-situ doping method and exhibited superior PODS performance of dibenzothiophene (DBT) under mild reaction conditions. The 1.0 mol% Ce/MIL-125-NH₂ catalyst achieved 100% sulfur removal within 22 min at 30 ℃ under visible light illumination, which is mainly attributed to the high surface area and the formation of Ce-Ti-oxo clusters due to electronic coupling. The valence transformation of Ce⁴⁺/Ce³⁺ and Ti⁴⁺/Ti³⁺ redox mediators could not only expose abundant Lewis acid sites, but also promote the separation and transfer of photogenerated charges. In addition, increasing the reaction temperature has been demonstrated to be effective in promoting the PODS performance. Additionally, a thermo-enhanced PODS mechanism was proposed over Ce/MIL-125-NH₂, demonstrating the great potential of thermal energy to promote the desulfurization activity.
1. [1]
  A. Rajendran, T. Cui, H. Fan, et al., J. Mater. Chem. A 8 (2020) 2246–2285. doi: 10.1039/C9TA12555H
2. [2]
  X. Zhou, X. Li, R. Prins, et al., J. Catal. 394 (2021) 167–180. doi: 10.1016/j.jcat.2020.08.030
3. [3]
  J. Ye, J. Wen, D. Zhao, et al., Chin. Chem. Lett. 31 (2020) 2819–2824. doi: 10.1016/j.cclet.2020.08.004
4. [4]
  Z. Wu, Y. Li, C. Zhang, et al., Chem. Catal. 2 (2022) 1009–1045. doi: 10.1016/j.checat.2022.02.010
5. [5]
  G. Lu, F. Chu, X. Huang, et al., Coord. Chem. Rev. 450 (2022) 214240. doi: 10.1016/j.ccr.2021.214240
6. [6]
  X. Guan, Y. Wang, W. Cai, Chin. Chem. Lett. 30 (2019) 1310–1314. doi: 10.1016/j.cclet.2019.02.029
7. [7]
  M. Chi, T. Su, L. Sun, et al., Appl. Catal. B: Environ. 275 (2020) 119134. doi: 10.1016/j.apcatb.2020.119134
8. [8]
  Y. Chen, C. Shen, J. Wang, G. Xiao, G. Luo, ACS Sustain. Chem. Eng. 6 (2018) 13276–13286. doi: 10.1021/acssuschemeng.8b02860
9. [9]
  B. Li, H. Song, F. Han, L. Wei, Appl. Catal. B: Environ. 269 (2020) 118845. doi: 10.1016/j.apcatb.2020.118845
10. [10]
  G. Zhao, S. Hao, J. Guo, et al., Chin. J. Catal. 42 (2021) 501–509. doi: 10.1016/S1872-2067(20)63670-1
11. [11]
  X. Li, Z. Zhang, C. Yao, et al., Appl. Surf. Sci. 364 (2016) 589–596. doi: 10.1016/j.apsusc.2015.12.196
12. [12]
  J. Li, Z. Yang, S. Li, et al., J. Ind. Eng. Chem. 82 (2020) 1–16. doi: 10.1016/j.jiec.2019.10.020
13. [13]
  G. Zhao, X. Xu, Nanoscale 13 (2021) 10649–10667. doi: 10.1039/D1NR02464G
14. [14]
  Y. Xue, G. Zhao, R. Yang, et al., Nanoscale 13 (2021) 3911–3936. doi: 10.1039/D0NR09064F
15. [15]
  H. Zhang, Y. Yang, C. Li, et al., J. Mater. Chem. A 9 (2021) 16743–16750. doi: 10.1039/D1TA04493A
16. [16]
  I. Ahmed, S.H. Jhung, J. Hazard. Mater. 301 (2016) 259–276. doi: 10.1016/j.jhazmat.2015.08.045
17. [17]
  B.N. Bhadra, S.H. Jhung, Appl. Catal. B: Environ. 259 (2019) 118021. doi: 10.1016/j.apcatb.2019.118021
18. [18]
  X. Zhang, Z. Zhang, B. Zhang, et al., Appl. Catal. B: Environ. 256 (2019) 117804. doi: 10.1016/j.apcatb.2019.117804
19. [19]
  Y. Zhang, G. Li, L. Kong, H. Lu, Fuel 219 (2018) 103–110. doi: 10.1016/j.fuel.2018.01.050
20. [20]
  N. Li, Z. Zhang, J. Zhang, et al., Dalton Trans. 50 (2021) 6506–6511. doi: 10.1039/D1DT00774B
21. [21]
  M. Bagheri, M.Y. Masoomi, A. Morsali, ACS Catal. 7 (2017) 6949–6956. doi: 10.1021/acscatal.7b02581
22. [22]
  Y. Xing, X. Wang, S. Hao, et al., Chin. Chem. Lett. 32 (2021) 13–20. doi: 10.1016/j.cclet.2020.11.011
23. [23]
  G. Zhao, Y. Xing, S. Hao, et al., Chin. Chem. Lett. 32 (2021) 277–281. doi: 10.1016/j.cclet.2020.11.033
24. [24]
  G. Mo, L. Wang, J. Luo, Sep. Purif. Technol. 277 (2021) 119643. doi: 10.1016/j.seppur.2021.119643
25. [25]
  G. Zhao, W. Ma, X. Wang, et al., Adv. Powder Mater. 1 (2022) 100008. doi: 10.1016/j.apmate.2021.09.008
26. [26]
  A.M. Ebrahim, T.J. Bandosz, ACS Appl. Mater. Interfaces 5 (2013) 10565–10573. doi: 10.1021/am402305u
27. [27]
  X. Yang, S. Deng, F. Peng, T. Luo, Dalton Trans. 46 (2017) 1996–2006. doi: 10.1039/C6DT03934K
28. [28]
  Y. Zhang, H. Chen, Y. Pan, et al., Chem. Comm. 55 (2019) 13959–13962. doi: 10.1039/C9CC06562H
29. [29]
  P. Parnicka, W. Lisowski, T. Klimczuk, A. Mikolajczyk, A. Zaleska-Medynska, Appl. Catal. B: Environ. 310 (2022) 121349. doi: 10.1016/j.apcatb.2022.121349
30. [30]
  Z. Wu, X. Huang, H. Zheng, et al., Appl. Catal. B: Environ. 224 (2018) 479–487. doi: 10.1016/j.apcatb.2017.10.034
31. [31]
  G. Ye, Y. Gu, W. Zhou, W. Xu, Y. Sun, ACS Catal. 10 (2020) 2384–2394. doi: 10.1021/acscatal.9b04937
32. [32]
  G. Lu, X. Huang, Y. Li, et al., J. Energy Chem. 43 (2020) 8–15. doi: 10.1016/j.jechem.2019.07.014
33. [33]
  J. He, Y. Xu, W. Wang, et al., Chem. Eng. J. 379 (2020) 122431. doi: 10.1016/j.cej.2019.122431
34. [34]
  X. Dong, Y. Lin, G. Ren, Y. Ma, L. Zhao, Colloid Surf. A 608 (2021) 125578. doi: 10.1016/j.colsurfa.2020.125578
35. [35]
  Y. Zou, Y. Hu, A. Uhrich, et al., Appl. Catal. B: Environ. 298 (2021) 120584. doi: 10.1016/j.apcatb.2021.120584
36. [36]
  X. Li, K. Zhang, X. Huang, et al., Nanoscale 13 (2021) 19671–19681. doi: 10.1039/D1NR05441D
37. [37]
  K. Zhang, G. Lu, F. Chu, X. Huang, Catal. Sci. Technol. 11 (2021) 7060–7071. doi: 10.1039/D1CY01333E
38. [38]
  A. Najafidoust, S. Allahyari, N. Rahemi, M. Tasbihi, Ceram. Int. 46 (2020) 4707–4719. doi: 10.1016/j.ceramint.2019.10.202
39. [39]
  J. Guo, L. Chu, L. Wang, et al., Appl. Surf. Sci. 579 (2022) 152251. doi: 10.1016/j.apsusc.2021.152251
40. [40]
  Y. Zhang, R. Wang, Appl. Catal. B: Environ. 234 (2018) 247–259. doi: 10.1016/j.apcatb.2018.04.031
41. [41]
  F. Abedini, S. Allahyari, N. Rahemi, Appl. Surf. Sci. 569 (2021) 151086. doi: 10.1016/j.apsusc.2021.151086
42. [42]
  Q. Huo, G. Liu, H. Sun, et al., Chem. Eng. J. 422 (2021) 130036. doi: 10.1016/j.cej.2021.130036
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Ce-doped MIL-125-NH2 coupled Ce4+/Ce3+ and Ti4+/Ti3+ redox mediators for thermo-enhanced photocatalytic oxidative desulfurization

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通讯作者: 陈斌, bchen63@163.com

Ce-doped MIL-125-NH₂ coupled Ce⁴⁺/Ce³⁺ and Ti⁴⁺/Ti³⁺ redox mediators for thermo-enhanced photocatalytic oxidative desulfurization