Citation: Wenshan Gou, Tian Jiang, Wei Wang, Qi Fan, Yan Zhang. Calcium-organic frameworks cathode for high-stable aqueous Zn/organic batteries[J]. Chinese Chemical Letters, ;2023, 34(7): 107760. doi: 10.1016/j.cclet.2022.107760 shu

Calcium-organic frameworks cathode for high-stable aqueous Zn/organic batteries

Wenshan Gou ^a ,
Tian Jiang ^b ,
Wei Wang ^c ,
Qi Fan ^{b, *,} ,
Yan Zhang ^{a, *,}

a.
Institute of Advanced Cross-field Science, College of Life Sciences, Qingdao University, Qingdao 200671, China
b.
School of Materials Science and Engineering, Jiulonghu Campus, Southeast University, Nanjing 211189, China
c.
China State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China

fanqi1984@126.com

yzhang_iacs@qdu.edu.cn

Received Date: 31 May 2022
Revised Date: 5 July 2022
Accepted Date: 17 August 2022
Available Online: 20 August 2022

Figures(6)

Rechargeable aqueous zinc-ion batteries (AZIBs) are attracting tremendous attention because of their intrinsic merits such as high safety and low cost. Cathode plays a critical role in enhancing the electrochemical performance of AZIBs. However, it is difficult to design a robust and high-efficiency cathode material and further implement the commercialization of AZIBs. Metal-organic frameworks (MOFs) electroactive compounds are attractive to serve as the cathode of AZIBs due to their unique porosity and crystal structures, resource renewability and structural diversity. In this work, a calcium-pure terephthalates acid framework (Ca-PTA·3H₂O) was synthesized by facile hydrolysis and cationic exchange method, then explored as a novel cathode for AZIBs. The results highlight a high specific capacity of 431 mAh/g (0.51 mAh/cm²) at a current density of 50 mA/g, and excellent cycle performance with capacity retention of ~90% after 2700 cycles at 500 mA/g. The following up characterizations investigate the reversible zinc storage mechanism in detail. This experiment made a specific contribution to the exploration of the new MOF as a competitive cathode for AZIBs.
- Aqueous zinc-ion battery,
- Metal-organic frameworks,
- Cathode material,
- Excellent cycle performance,
- Zinc storage mechanism
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