Citation: Qiangying Zhang, Xin Tan, Tao Yu. Effectively arsenic(Ⅴ) and fluoride removal in geothermal water using magnetic Fe₃O₄@MgO nanoparticles[J]. Chinese Chemical Letters, ;2023, 34(5): 107748. doi: 10.1016/j.cclet.2022.107748 shu

Effectively arsenic(Ⅴ) and fluoride removal in geothermal water using magnetic Fe₃O₄@MgO nanoparticles

Qiangying Zhang ^a ,
Xin Tan ^{a, b} ,
Tao Yu ^{c, *,}

a.
School of Science, Tibet University, Lhasa 850000, China
b.
School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, China
c.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China

yutao@tju.edu.cn

Received Date: 4 June 2022
Revised Date: 25 July 2022
Accepted Date: 12 August 2022
Available Online: 17 August 2022

Figures(5)

High residual concentration of arsenic and fluoride is a tricky problem to be solved in the process of reinjection after geothermal water utilization. We develop a method to simultaneously remove As(Ⅴ) and F⁻ from geothermal water using magnetic Fe₃O₄@MgO adsorbent, fabricated via a one-step method. The effects of pH, contact time, adsorbent dose and temperature on the removal efficiency were investigated systematically. The results show that the Fe₃O₄@MgO composite has a wide range of pH (2–11), ultrafast removal dynamics (As(Ⅴ): 2 min; F⁻: 30 min), and high removal efficiency (As(Ⅴ): 99.9%; F⁻: 96.6%). The adsorption kinetics follows the pseudo-second-order kinetics model, and the adsorption isotherm model fits Freundlich. The adsorption capacity of As(Ⅴ) and F⁻ can reach 123 and 98.4 mg/g, respectively. The exchange of As(Ⅴ) and F⁻ with Mg-hydroxyl groups hydrolysis by MgO was determined the adsorption mechanism. The Fe₃O₄@MgO adsorbent was capable of achieving the adsorption efficiency as high as 99.9% for As(Ⅴ) and 97.3% for F⁻ in real geothermal water, respectively. Hence, the proposed Fe₃O₄@MgO composite exhibited as an excellent adsorbent for the remediation of As- and F-contaminated geothermal water.
- Fe₃O₄@MgO adsorbent,
- Geothermal water,
- Arsenic(Ⅴ),
- Fluoride,
- Removal
1. [1]
  Q.H. Guo, Appl. Geochem. 27 (2012) 1887–1898. doi: 10.1016/j.apgeochem.2012.07.006
2. [2]
  Q.H. Guo, Y.W. Cao, J.X. Li, X.B. Zhang, Y.X. Wang, Appl. Geochem. 62 (2015) 164–170. doi: 10.1016/j.apgeochem.2015.01.017
3. [3]
  Z. Jiang, P. Li, J. Tu, et al., Int. Biodeterior. Biodegrad. 128 (2018) 28–35. doi: 10.1016/j.ibiod.2016.05.013
4. [4]
  J. Bundschuh, J.P. Maity, B. Nath, et al., J. Hazard Mater. 262 (2013) 951–959. doi: 10.1016/j.jhazmat.2013.01.039
5. [5]
  Q.H. Guo, Y. Wang, W. Liu, J. Volcanol, Geoth. Res. 166 (2007) 255–268. doi: 10.1016/j.jvolgeores.2007.08.004
6. [6]
  D. Mohan, C.U. Pittman, J. Hazard Mater. 142 (2007) 1–53. doi: 10.1016/j.jhazmat.2007.01.006
7. [7]
  S.R. Kanel, J.M. Grenèche, H. Choi, Environ. Sci. Technol. 40 (2006) 2045–2050. doi: 10.1021/es0520924
8. [8]
  A. Ghosh, K. Mukherjee, S.K. Ghosh, B. Saha, Res. Chem. Intermed. 39 (2012) 2881–2915.
9. [9]
  L.S. Thakur, P. Mondal, J. Environ. Manag. 190 (2017) 102–112. doi: 10.1016/j.jenvman.2016.12.053
10. [10]
  B. An, Q. Liang, D. Zhao, Water Res. 45 (2011) 1961–1972. doi: 10.1016/j.watres.2011.01.004
11. [11]
  A.P. Padilla, H. Saitua, Desalination 257 (2010) 16–21. doi: 10.1016/j.desal.2010.03.022
12. [12]
  P.P. Gao, X.K. Tian, C. Yang, et al., Environ. Sci. : Nano 3 (2016) 1416–1424. doi: 10.1039/C6EN00400H
13. [13]
  C. Jing, J. Cui, Y. Huang, A. Li, ACS Appl. Mater. Interfaces 4 (2012) 714–720. doi: 10.1021/am2013322
14. [14]
  S.M. Prabhu, P. Koilraj, K. Sasaki, Chem. Eng. J. 325 (2017) 1–13. doi: 10.1016/j.cej.2017.05.052
15. [15]
  X. Zhang, M. Wu, H. Dong, H. Li, B. Pan, Environ. Sci. Technol. 51 (2017) 6326–6334. doi: 10.1021/acs.est.7b00724
16. [16]
  D. Kang, X. Yu, S. Tong, et al., Chem. Eng. J. 228 (2013) 731–740. doi: 10.1016/j.cej.2013.05.041
17. [17]
  T. Yu, Y.L. Chen, Y.Z. Zhang, et al., Chin. Chem. Lett. 32 (2021) 3410–3415. doi: 10.1016/j.cclet.2021.04.057
18. [18]
  W. Li, C.Y. Cao, L.Y. Wu, M.F. Ge, W.G. Song, J. Hazard Mater. 198 (2011) 143–150. doi: 10.1016/j.jhazmat.2011.10.025
19. [19]
  L. Yan, H. Tu, T. Chan, C. Jing, Chem. Eng. J. 313 (2017) 983–992. doi: 10.1016/j.cej.2016.10.142
20. [20]
  V. Kumar, N. Talreja, D. Deva, et al., Desalination 282 (2011) 27–38. doi: 10.1016/j.desal.2011.05.013
21. [21]
  Y. Meng, J. N Wang, C. Cheng, X. Yang, A.M. Li, Chin. Chem. Lett. 23 (2012) 863–866. doi: 10.1016/j.cclet.2012.03.033
22. [22]
  S. Bibi, A. Farooqi, K. Hussain, N. Haider, J. Clean. Prod. 87 (2015) 882–896. doi: 10.1016/j.jclepro.2014.09.030
23. [23]
  C. García-Gómez, M.L. Rivera-Huerta, F. Almazán-García, et al., Water, Air, Soil Pollut. 227 (2016) 1–16. doi: 10.1007/s11270-015-2689-7
24. [24]
  Z. Jin, Y. Jia, K.S. Zhang, et al., J. Alloys Compd. 675 (2016) 292–300. doi: 10.1016/j.jallcom.2016.03.118
25. [25]
  L.X. Li, D. Xu, X.Q. Li, W.C. Liu, Y. Jia, New J. Chem. 38 (2014) 5445–5452. doi: 10.1039/C4NJ01361A
26. [26]
  Z. Jin, Y. Jia, T. Luo, et al., Appl. Surf. Sci. 357 (2015) 1080–1088. doi: 10.1016/j.apsusc.2015.09.127
27. [27]
  A. Dhillon, S.K. Soni, D. Kumar, J. Fluorine Chem. 199 (2017) 67–76. doi: 10.1016/j.jfluchem.2017.05.002
28. [28]
  G. Zhang D. Tang, Chem. Eng. J. 283 (2016) 721–729. doi: 10.1016/j.cej.2015.08.019
29. [29]
  L. Chai, Y. Wang, N. Zhao, W. Yang, X. You, Water Res. 47 (2013) 4040–4049. doi: 10.1016/j.watres.2013.02.057
30. [30]
  T.F. Lin, J.K. Wu, Water Res. 35 (2001) 2049–2057. doi: 10.1016/S0043-1354(00)00467-X
31. [31]
  V. Chandra, J. Park, Y. Chun, et al., ACS Nano 4 (2010) 3979–3986. doi: 10.1021/nn1008897
32. [32]
  K. Zhang, S. Wu, X. Wang, et al., J. Colloid Interface Sci. 446 (2015) 194–202. doi: 10.1016/j.jcis.2015.01.049
33. [33]
  N.A. Oladoja, S. Chen, J.E. Drewes, B. Helmreich, Chem. Eng. J. 281 (2015) 632–643. doi: 10.1016/j.cej.2015.07.007
34. [34]
  N.A. Oladoja, S. Hu, J.E. Drewes, B. Helmreich, Sep. Purif. Technol. 162 (2016) 195–202. doi: 10.1016/j.seppur.2016.02.028
35. [35]
  Y. Wei, H. Liu, C. Liu, et al., Water Res. 150 (2019) 182–190. doi: 10.1016/j.watres.2018.11.069
36. [36]
  Q.Y. Zhang, M. He, B.B. Chen, B. Hu, ACS Omega 3 (2018) 3752–3759. doi: 10.1021/acsomega.7b01989
1. [1]
  Yi Zhang , Biao Wang , Chao Hu , Muhammad Humayun , Yaping Huang , Yulin Cao , Mosaad Negem , Yigang Ding , Chundong Wang . Fe–Ni–F electrocatalyst for enhancing reaction kinetics of water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100243-100243. doi: 10.1016/j.cjsc.2024.100243
2. [2]
  Chong Liu , Nanthi Bolan , Anushka Upamali Rajapaksha , Hailong Wang , Paramasivan Balasubramanian , Pengyan Zhang , Xuan Cuong Nguyen , Fayong Li . Critical review of biochar for the removal of emerging inorganic pollutants from wastewater. Chinese Chemical Letters, 2025, 36(2): 109960-. doi: 10.1016/j.cclet.2024.109960
3. [3]
  Chao Liu , Chao Jia , Shi-Xian Gan , Qiao-Yan Qi , Guo-Fang Jiang , Xin Zhao . A luminescent one-dimensional covalent organic framework for organic arsenic sensing in water. Chinese Chemical Letters, 2024, 35(11): 109750-. doi: 10.1016/j.cclet.2024.109750
4. [4]
  Ao Sun , Zipeng Li , Shuchun Li , Xiangbao Meng , Zhongtang Li , Zhongjun Li . Stereoselective synthesis of α-3-deoxy-D-manno-oct-2-ulosonic acid (α-Kdo) derivatives using a C3-p-tolylthio-substituted Kdo fluoride donor. Chinese Chemical Letters, 2025, 36(3): 109972-. doi: 10.1016/j.cclet.2024.109972
5. [5]
  Changle Liu , Mingyuzhi Sun , Haoran Zhang , Xiqian Cao , Yuqing Li , Yingtang Zhou . All in one doubly pillared MXene membrane for excellent oil/water separation, pollutant removal, and anti-fouling performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100355-100355. doi: 10.1016/j.cjsc.2024.100355
6. [6]
  Linjing Li , Wenlai Xu , Jianyong Ning , Yaping Zhong , Chuyue Zhang , Jiane Zuo , Zhicheng Pan . Revealing the intrinsic mechanisms for accelerating nitrogen removal efficiency in the Anammox reactor by adding Fe(II) at low temperature. Chinese Chemical Letters, 2024, 35(8): 109243-. doi: 10.1016/j.cclet.2023.109243
7. [7]
  Wantong Zhang , Zixing Xu , Guofei Dai , Zhijian Li , Chunhui Deng . Removal of Microcystin-LR in lake water sample by hydrophilic mesoporous silica composites under high-throughput MALDI-TOF MS detection platform. Chinese Chemical Letters, 2024, 35(5): 109135-. doi: 10.1016/j.cclet.2023.109135
8. [8]
  Guanyang Zeng , Xingqiang Liu , Liangqiao Wu , Zijie Meng , Debin Zeng , Changlin Yu . Novel visible-light-driven I- doped Bi2O2CO3 nano-sheets fabricated via an ion exchange route for dye and phenol removal. Chinese Journal of Structural Chemistry, 2024, 43(12): 100462-100462. doi: 10.1016/j.cjsc.2024.100462
9. [9]
  Ke Zhang , Yajing Wei , Linhua Xie , Sha Kang , Fei Li , Chuanyi Wang . Amorphous titanium carbide on N-defective g-C₃N₅ for high-efficiency photocatalytic NO removal. Chinese Chemical Letters, 2025, 36(3): 110086-. doi: 10.1016/j.cclet.2024.110086
10. [10]
  Yue Li , Minghao Fan , Conghui Wang , Yanxun Li , Xiang Yu , Jun Ding , Lei Yan , Lele Qiu , Yongcai Zhang , Longlu Wang . 3D layer-by-layer amorphous MoS_x assembled from [Mo₃S₁₃]^2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764
11. [11]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
12. [12]
  Entian Cui , Yulian Lu , Zhaoxia Li , Zhilei Chen , Chengyan Ge , Jizhou Jiang . Interfacial B-O bonding modulated S-scheme B-doped N-deficient C₃N₄/O-doped-C₃N₅ for efficient photocatalytic overall water splitting. Chinese Chemical Letters, 2025, 36(1): 110288-. doi: 10.1016/j.cclet.2024.110288
13. [13]
  Zhongsen Wang , Lijun Qiu , Yunhua Huang , Meng Zhang , Xi Cai , Fanyu Wang , Yang Lin , Yanbiao Shi , Xiao Liu . Alcohothermal synthesis of sulfidated zero-valent iron for enhanced Cr(Ⅵ) removal. Chinese Chemical Letters, 2024, 35(7): 109195-. doi: 10.1016/j.cclet.2023.109195
14. [14]
  Di An , Mingdong She , Ziyang Zhang , Ting Zhang , Miaomiao Xu , Jinjun Shao , Qian Shen , Xuna Tang . Light-responsive nanomaterials for biofilm removal in root canal treatment. Chinese Chemical Letters, 2025, 36(2): 109841-. doi: 10.1016/j.cclet.2024.109841
15. [15]
  Qinwei Lu , Jinjie Lu , Juying Lei , Xubiao Luo , Yanbo Zhou . Cyclodextrin-boosted photocatalytic oxidation for efficient bisphenol A removal. Chinese Chemical Letters, 2025, 36(3): 110017-. doi: 10.1016/j.cclet.2024.110017
16. [16]
  Yuan CONG , Yunhao WANG , Wanping LI , Zhicheng ZHANG , Shuo LIU , Huiyuan GUO , Hongyu YUAN , Zhiping ZHOU . Construction and photocatalytic properties toward rhodamine B of CdS/Fe₃O₄ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2241-2249. doi: 10.11862/CJIC.20240219
17. [17]
  Qinwen Zheng , Xin Liu , Lintao Tian , Yi Zhou , Libing Liao , Guocheng Lv . Mechanism of Fenton catalytic degradation of Rhodamine B induced by microwave and Fe₃O₄. Chinese Chemical Letters, 2025, 36(4): 109771-. doi: 10.1016/j.cclet.2024.109771
18. [18]
  Lina Wang , Hairu Wang , Qian Bu , Qiong Mei , Junbo Zhong , Bo Bai , Qizhao Wang . Al-O bridged NiFeO_x/BiVO₄ photoanode for exceptional photoelectrochemical water splitting. Chinese Chemical Letters, 2025, 36(4): 110139-. doi: 10.1016/j.cclet.2024.110139
19. [19]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
20. [20]
  Hailang Deng , Abebe Reda Woldu , Abdul Qayum , Zanling Huang , Weiwei Zhu , Xiang Peng , Paul K. Chu , Liangsheng Hu . Killing two birds with one stone: Enhancing the photoelectrochemical water splitting activity and stability of BiVO₄ by Fe ions association. Chinese Chemical Letters, 2024, 35(12): 109892-. doi: 10.1016/j.cclet.2024.109892

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(1109)
HTML views(41)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effectively arsenic(Ⅴ) and fluoride removal in geothermal water using magnetic Fe3O4@MgO nanoparticles

Metrics

通讯作者: 陈斌, bchen63@163.com

Effectively arsenic(Ⅴ) and fluoride removal in geothermal water using magnetic Fe₃O₄@MgO nanoparticles