Citation: Ruowen Tang, Yanpeng Ye, Shajun Zhu, Yang Wang, Bing Lu, Yong Yao. Pillar[6]arenes: From preparation, host-guest property to self-assembly and applications[J]. Chinese Chemical Letters, ;2023, 34(3): 107734. doi: 10.1016/j.cclet.2022.08.014 shu

Pillar[6]arenes: From preparation, host-guest property to self-assembly and applications

Ruowen Tang ^a ,
Yanpeng Ye ^a ,
Shajun Zhu ^b ,
Yang Wang ^a ,
Bing Lu ^{a, *,} ,
Yong Yao ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China
b.
Department of Hepatobiliary and Pancreatic Surgery, Affiliated Hospital of Nantong University, Nantong 226001, China

2020028lubing@ntu.edu.cn

yaoyong1986@ntu.edu.cn

Received Date: 5 June 2022
Revised Date: 2 August 2022
Accepted Date: 5 August 2022
Available Online: 10 August 2022

Figures(29)

Pillar[n]arenes primarily comprise pillar[5]arenes and pillar[6]arenes, which belong to the new class of supramolecular macrocyclic hosts. Pillar[n]arenes have aroused wide attention because of their highly rigid and symmetrical architectures, controllable cavity size, and wide applications in a wide variety of areas. Although pillar[6]arene is difficult to synthesize, numerous studies have been conducted on it. In this review, the strategies to synthesize and functionalize pillar[6]arenes are investigated systematically. In addition, their host-guest properties in organic solvents and in aqueous solution are described. Moreover, pillar[6]arenes applied in different fields (e.g., molecular recognition, drug release, cancer therapy, and gas separation) are clarified. Hopefully, this study is capable of arousing more attention from increasing scientists to study large-cavity pillar[n]arenes.
- Pillar[6]arenes,
- Host-guest interactions,
- Drug release,
- Cancer therapy,
- Supramolecular chemistry
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沈阳化工大学材料科学与工程学院沈阳 110142