Citation: Ya-Liang Lai, Hao-Jie Zhang, Juan Su, Xue-Zhi Wang, Dong Luo, Jia-Xing Liu, Xiao-Ping Zhou, Dan Li. Self-assembly of a quadrangular prismatic covalent cage templated by zinc ions: A selective fluorescent sensor for palladium ions[J]. Chinese Chemical Letters, ;2023, 34(6): 107686. doi: 10.1016/j.cclet.2022.07.029 shu

Self-assembly of a quadrangular prismatic covalent cage templated by zinc ions: A selective fluorescent sensor for palladium ions

College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, China

zhouxp@jnu.edu.cn

Received Date: 21 May 2022
Revised Date: 13 June 2022
Accepted Date: 15 July 2022
Available Online: 17 July 2022

Figures(6)

Herein we report a covalent cage TPE-Zn₄ based on a tetraphenylethylene molecule via subcomponent self-assembly, which is templated by zinc ions. TPE-Zn₄ features a quadrangular prismatic cage structure, which is characterized by NMR, mass spectrum, and single-crystal X-ray diffractions. TPE-Zn₄ emitted orange fluorescence (λ_em = 620 nm) in DMSO solution under the irradiation of UV light (λ_ex = 395 nm) and can be applied as a fluorescence sensor for selectively detecting Pd²⁺. The fluorescence of TPE-Zn₄ was quenched by Pd²⁺ in DMSO solution, and a very low detection limit of 62.3 nM was achieved. Mechanism studies reveal that the Pd²⁺ can replace the Zn²⁺, and the heavy atom effect and chelation-enhanced quenching effect between the Pd²⁺ and the cage probably cause the fluorescence quenching.
- Subcomponent self-assembly,
- Covalent cage,
- Fluorescence sensor,
- Detection of palladium ions,
- Photoluminescence
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