Citation: Shengxian Zhai, Shuxian Qiu, Shuangtao Yang, Xingyuan Gao, Xinyu Feng, Chenzhe Yun, Ning Han, Yongsheng Niu, Jing Wang, Hongbin Zhai. Facile access to β-hydroxyl ketones via a cobalt-catalyzed ring-opening/hydroxylation cascade of cyclopropanols[J]. Chinese Chemical Letters, ;2023, 34(3): 107657. doi: 10.1016/j.cclet.2022.06.080 shu

Facile access to β-hydroxyl ketones via a cobalt-catalyzed ring-opening/hydroxylation cascade of cyclopropanols

Shengxian Zhai ^{a, 1} ,
Shuxian Qiu ^{b, 1} ,
Shuangtao Yang ^a ,
Xingyuan Gao ^{b, *,} ,
Xinyu Feng ^a ,
Chenzhe Yun ^a ,
Ning Han ^a ,
Yongsheng Niu ^a ,
Jing Wang ^a ,
Hongbin Zhai ^{c, d, e, *,}

a.
College of Chemistry & Environmental Engineering, Anyang Institute of Technology, Anyang 455000, China
b.
Department of Chemistry and Material Science, Engineering Technology Development Center of Advanced Materials & Energy Saving and Emission Reduction in Guangdong Colleges and Universities, Guangdong University of Education, Guangzhou 510303, China
c.
State Key Laboratory of Chemical Oncogenomics and Key Laboratory of Chemical Genomics, Shenzhen Engineering Laboratory of Nano Drug Slow-Release, Shenzhen Graduate School of Peking University, Shenzhen 518055, China
d.
Shenzhen Bay Laboratory, Shenzhen 518055, China
e.
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300071, China

gaoxingyuan@gdei.edu.cn

zhaihb@pku.edu.cn

Received Date: 4 May 2022
Revised Date: 26 June 2022
Accepted Date: 30 June 2022
Available Online: 3 July 2022

Figures(6)

A cobalt-catalyzed ring-opening/hydroxylation cascade of highly strained cyclopropanols has been developed for the first time. The reaction was conducted under open-air atmosphere to afford a broad series of structurally diverse β-hydroxy ketones in moderate to good yields with high regioselectivity. The protocol features mild reaction conditions, simple operation, high-functional-group tolerance, facile scalability, and heterocycle compatibility.
- Cobalt catalysis,
- Ring-opening,
- Cyclopropanol,
- β-Hydroxy ketone,
- Cascade reaction
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