Citation: Ziyong Li, Xinyu Gao, Haining Zhang, Xiaoxie Ma, Yifang Liu, Hui Guo, Jun Yin. Efficient blue light-responsed dithienylethenes with exceptional photochromic performance[J]. Chinese Chemical Letters, ;2023, 34(3): 107645. doi: 10.1016/j.cclet.2022.06.068 shu

Efficient blue light-responsed dithienylethenes with exceptional photochromic performance

Ziyong Li ^a ,
Xinyu Gao ^a ,
Haining Zhang ^a ,
Xiaoxie Ma ^b ,
Yifang Liu ^a ,
Hui Guo ^{a, *,} ,
Jun Yin ^{b, *,}

a.
College of Food and Drug, College of Chemistry and Chemical Engineering, Luoyang Key Laboratory of Organic Functional Molecules, Luoyang Normal University, Luoyang 471934, China
b.
College of Chemistry, Key Laboratory of Pesticide and Chemical Biology, Ministry of Education; Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis; International Joint Research Center for Intelligent Biosensing Technology and Health, Central China Normal University, Wuhan 430079, China

guohui@lynu.edu.cn

yinj@mail.ccnu.edu.cn

Received Date: 22 March 2022
Revised Date: 25 June 2022
Accepted Date: 27 June 2022
Available Online: 1 July 2022

Figures(4)

Three novel dithienylethenes modified by bifluoroboron β-diketonate fragments have been successfully developed. Upon blue light irradiation, they reached photostationary state within 2–5 s, as well as 100% conversion ratio and photocyclization quantum yield of > 0.70. Such fascinating photochromism were endowed by collaborative role of electron-withdrawing effect of BF₂bdk group to reduce HOMO-LUMO electronic gap for the open isomer, together with intramolecular hydrogen bonds and CH-π interactions favoring antiparallel conformation fixation. Moreover, they displayed specific discrimination and photoswitchable bacterial imaging for S. aureus.
- Dithienylethene,
- Photochromism,
- Fluorescent switching behavior,
- Visible light,
- Bifluoroboron β-diketonate (BF₂bdk),
- Bacterial imaging
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