Citation: Qiongjie Ke, Qingshuai Xu, Xuejun Lai, Xianfeng Yang, Huichun Gao, Zaisheng Wang, Yongcai Qiu. Ultralong-life lithium metal batteries enabled by decorating robust hybrid interphases on 3D layered framworks[J]. Chinese Chemical Letters, ;2023, 34(5): 107602. doi: 10.1016/j.cclet.2022.06.025 shu

Ultralong-life lithium metal batteries enabled by decorating robust hybrid interphases on 3D layered framworks

Qiongjie Ke ^a ,
Qingshuai Xu ^a ,
Xuejun Lai ^a ,
Xianfeng Yang ^a ,
Huichun Gao ^b ,
Zaisheng Wang ^{a, *,} ,
Yongcai Qiu ^{a, *,}

a.
School of Environment and Energy, State Key Laboratory of Luminescent Materials and Device, Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, South China University of Technology, Guangzhou 510000, China
b.
EVE Energy Co., Ltd., Huizhou 516000, China

842700923@qq.com

ycqiu@scut.edu.cn

Received Date: 9 May 2022
Revised Date: 25 May 2022
Accepted Date: 8 June 2022
Available Online: 16 June 2022

Figures(5)

Stable solid-electrolyte interphase (SEI) is crucial for advanced development of lithium metal batteries. However, the continuous collapse and reconstruction of SEI will deplete fresh Li and electrolytes upon cycling, leading to irreversible capacity loss. Herein, we addressed this issue by pre-formation of artificial robust hybrid interphase on a 3D layered graphene/lithium metal framework, in which is constructed by LiF associated with Li₂TiF₆ generated by the in-situ reaction between the surfacial lithium and titanium fluoride contained electrolytes. The as-obtained interphase can maintain the structure integrality and avoid continuous consumption of the fresh Li and electrolytes. As a consequence, the Li symmetric cells achieve high-efficiency Li deposition and stable cycling over 3600 h. When paired with LiFePO₄ cathodes, the coin cells exhibit long lifespan (> 800 cycles) with almost 88.3% retention of the initial capacity.
- Lithium metal battery,
- TiF₄,
- Artificial SEI,
- Dendrite free,
- 3D frameworks
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沈阳化工大学材料科学与工程学院沈阳 110142